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公开(公告)号:US20200299441A1
公开(公告)日:2020-09-24
申请号:US16084681
申请日:2017-03-15
Applicant: DAIKIN INDUSTRIES, LTD. , NISSIN CHEMICAL INDUSTRY CO., LTD
Inventor: Rumi KAWABE , Masaki FUKUMORI , Ryosuke HARA , Masahiro MIYAHARA , Shinichi MINAMI , Ikuo YAMAMOTO , Yasuhiro MITTA , Akifumi MITAKE
IPC: C08F220/18 , C08F220/20 , C08F236/20 , C08F214/06 , C08F214/08 , C08F265/04 , C08F2/38 , C08L33/08 , D06M15/248 , D06M15/263
Abstract: Provided is a surface treatment agent which does not use fluorine-containing monomers, particularly fluoroalkyl group-containing monomers. Additionally, provided is a copolymer which includes a first polymer formed from first monomers, and a second polymer formed from second monomers. The copolymer does not include fluorine. The second polymer is polymerized in the presence of the first polymer. The first monomers include a long-chain acrylate ester monomer (a) represented by the formula CH2=CA11-C(═O)—O-A12 (in the formula, A11 represents hydrogen, a monovalent organic group, or a halogen, and A12 represents a C18-30 straight-chain or branched hydrocarbon group). The first monomers and the second monomers both include a halogenated olefin monomer (b).
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公开(公告)号:US20200055970A1
公开(公告)日:2020-02-20
申请号:US16345984
申请日:2017-10-31
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Shinichi MINAMI , Masaki FUKUMORI , Takashi ENOMOTO , Takuya YOSHIOKA , Ikuo YAMAMOTO , Bin ZHOU , Min ZHU
IPC: C08F214/18 , C08F220/18 , D06M15/256
Abstract: Provided is a fluorinated polymer that can impart excellent washing durability and water- and oil-repellency to fibers, said fluorinated polymer having a repeating unit derived from a fluorinated monomer (a) that comprises a first fluorinated monomer (a1) represented by the formula: CH2═C(—X1)—C(═O)—Y1—Z1—Rf1 [wherein X1 represents a halogen atom; Y1 represents —O— or —NH—; Z1 represents a direct bond or a bivalent organic group; and Rf1 represents a fluoroalkyl group having 1 to 20 carbon atoms] and a second fluorinated monomer (a2) represented by the formula: CH2═C(—X2)—C(═O)—Y2—Z2—Rf2 [wherein X2 represents a monovalent organic group or a hydrogen atom; Y2 represents —O— or —NH—; Z2 represents a direct bond or a bivalent organic group; and Rf2 represents a fluoroalkyl group having 1 to 20 carbon atoms].
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公开(公告)号:US20230050864A1
公开(公告)日:2023-02-16
申请号:US17964526
申请日:2022-10-12
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Ikuo YAMAMOTO , Shinichi MINAMI , Bin ZHOU
IPC: C08G18/28 , C08G18/80 , C08G18/48 , C09D175/08 , D06M15/564 , D06M15/277
Abstract: A urethane compound (A) including units formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO—Z(Y—R)n [wherein the R moieties are each independently —O—, —NH—, —O—C(═O)—, —NH—C(═O)—, —C(═O)—NH—, —O—C(═O)—NH—, —NH—C(═O)—O—, —NH—C(═O)—NH—, —NH—S(═O)2—, —S(═O)2—NH—, —NH—(CH2)m—NH—S(═O)2—, —NH—(CH2)m—S(═O)2—NH—, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2]. Also disclosed is a urethane mixture containing the urethane compound (A), and at least one selected from the polyisocyanate (A1), the long-chain alcohol (A2), a blocking agent (A3) and an alcohol compound (A4); an aqueous urethane composition; a method for producing the aqueous urethane composition; a method of treating a substrate; and a treated textile product.
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公开(公告)号:US20210317246A1
公开(公告)日:2021-10-14
申请号:US17269608
申请日:2019-08-27
Applicant: NATIONAL UNIVERSITY CORPORATION NARA INSTITUTE OF SCIENCE AND TECHNOLOGY , DAIKIN INDUSTRIES, LTD
Inventor: Tsuyoshi ANDO , Kayo TERADA , Nobuo MURASE , Shota SHIBUTANI , Yoshito TANAKA , Takuma KAWABE , Ikuo YAMAMOTO
IPC: C08F255/02 , C09K3/18 , C08F265/06 , D01F11/08
Abstract: A water- and oil-repellent agent for fibers containing a bottle brush polymer having a structure represented by the following formula (1), wherein R1 is H or CH3; R2 is a divalent organic group; R3 is a polymer chain having a structure represented by the following formula (2) (wherein R4 is H or CH3; R5 is a C16-C40 monovalent hydrocarbon group; and n is an integer of 10 to 1000); and m is an integer of 10 to 5000:
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公开(公告)号:US20190077984A1
公开(公告)日:2019-03-14
申请号:US16085157
申请日:2017-03-15
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Rumi KAWABE , Masaki FUKUMORI , Ryosuke HARA , Masahiro MIYAHARA , Shinichi MINAMI , Ikuo YAMAMOTO
IPC: C09D151/06 , D06M15/248 , D06M15/263 , D06M13/165
Abstract: Provided is a surface treatment agent which does not use fluorine-containing monomers, particularly fluoroalkyl group-containing monomers. The surface treatment agent is a water-based emulsion which includes: a copolymer (1) which includes a first polymer formed from first monomers, and a second polymer formed from second monomers, wherein the second polymer is polymerized in the presence of the first polymer, the first monomers include a long-chain acrylate ester monomer (a) represented by the formula CH2═CA11-C(═O)—O-A12 (in the formula, A11 represents hydrogen, a monovalent organic group, or a halogen, and A12 represents a C18-30 straight-chain or branched hydrocarbon group), the first monomers do not include a halogenated olefin monomer (b), and the second monomers include the halogenated olefin monomer (b); a surfactant (2) including a nonionic surfactant; and a liquid medium (3) including water.
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公开(公告)号:US20180038044A1
公开(公告)日:2018-02-08
申请号:US15662437
申请日:2017-07-28
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Shinichi MINAMI , Masaki FUKUMORI , Takashi ENOMOTO , Ikuo YAMAMOTO , Min ZHU
IPC: D06M15/277 , D01F6/32 , D01F6/16 , D06M15/267
CPC classification number: D06M15/277 , D01F6/16 , D01F6/32 , D06M15/244 , D06M15/248 , D06M15/263 , D06M15/267 , D06M15/295 , D06M2101/06 , D06M2101/22 , D06M2101/32 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12
Abstract: Disclosed is a nonwoven fabric formed from (i) a nonwoven fabric substrate and (ii) a fluorine-containing polymer adhering to the nonwoven fabric substrate, wherein the fluorine-containing polymer contains:(a) repeating units formed from a fluorine-containing monomer which is alpha-chloro acrylate or alpha-chloro acrylamide containing a fluoroalkyl group, and (b) repeating units formed from a halogenated olefin monomer, and the fluorine-containing polymer is free from repeating units formed from a (meth)acrylate containing a linear or branched hydrocarbon group having at least 18 carbon atoms.
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公开(公告)号:US20170197888A1
公开(公告)日:2017-07-13
申请号:US15313594
申请日:2015-05-21
Applicant: DAIKIN INDUSTRIES, LTD.
Inventor: Kanako TAKAHASHI , Masaki FUKUMORI , Ikuo YAMAMOTO
CPC classification number: C04B41/4842 , C04B24/2688 , C04B41/009 , C04B41/48 , C04B41/63 , C04B2103/0051 , C04B2103/60 , C04B2103/65 , C04B2111/203 , C04B2111/27 , C08F220/22 , C08F220/24 , C08F220/28 , C09K3/18
Abstract: Provided is a masonry treatment composition containing a fluorine-containing polymer, which contains, as essential components, a fluorine-containing monomer having a fluoroalkyl group represented by the formula (a) CH2═C(—X)—C(═O)—Y—Z—Rf, a first hydrophilic monomer represented by formula (b) CH2═CX11C(═O)—O—RO—X12, a second hydrophilic monomer represented by formula (c) CH2═CX21C(═O)—O—(RO)n—X22 or CH2═CX31C(═O)—O—(RO)n—C(═O)CX32═CH2, and (d) repeating units derived from a monomer having an anion donor and an ethylenic unsaturated double bond. Provided is a treatment composition which can impart outstanding water repellency, oil repellency and anti-fouling properties to a masonry substrate.
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