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    Water based concentrated product forms of oil-soluble organic UV absorbers
    13.
    发明授权
    Water based concentrated product forms of oil-soluble organic UV absorbers 有权

    公开(公告)号：US11918672B2

    公开(公告)日：2024-03-05

    申请号：US16642999

    申请日：2018-08-28

    Applicant: BASF SE

    Inventor： Brigitte Lindemann ,  Stefan Busch ,  Frank Pirrung

    IPC: A61K8/49 ,  A61K8/362 ,  A61K8/37 ,  A61K8/46 ,  A61K8/60 ,  A61K8/81 ,  A61Q17/04

    CPC classification number: A61K8/4966 ,  A61K8/362 ,  A61K8/37 ,  A61K8/463 ,  A61K8/602 ,  A61K8/8147 ,  A61Q17/04

    Abstract: An aqueous polymer dispersion with an average particle size of less than 1000 nm comprising a) a polymer carrier prepared by heterophase radical polymerization of at least one ethylenically unsaturated monomer in the presence of b) an oil-soluble organic UV absorber selected from the class of p-aminobenzoic acid derivatives; salicylic acid derivatives; benzophenone derivatives; diphenyl acrylate derivatives; benzofuran derivatives; polymeric UV absorbers, comprising one or more organosilicon radicals; cinnamic acid derivatives; camphor derivatives; s-triazine derivatives; trianilino-striazine derivatives; menthyl anthranilates; and benzotriazole derivatives; wherein the weight ratio of the oil-soluble organic UV absorber (b) to polymer carrier (a) is greater than 50 parts UV absorber per 100 parts of carrier; and c) a surfactant selected from c1) a nonionic surfactant selected from c11) the condensation product of a C6 to C18 fatty alcohol or C6 to C18 fatty acid and a mono- or disaccharide; and c2) an anionic surfactant selected from c21) sulfosuccinates and sulfosuccinamates; c22) fatty alcoholates; and c23) mixtures of phosphoric acid esters and fatty alcohols having from 6 to 18, preferably from 8 to 10, carbon atoms. The aqueous polymer dispersions show unexpectedly high sunscreen effects and a positive skin feeling. They have excellent anti-pollen, anti-dust and anti-oxidant performances in sun screen compositions.

    Polymer dispersants
    16.
    发明授权
    Polymer dispersants 有权

    公开(公告)号：US09683126B2

    公开(公告)日：2017-06-20

    申请号：US15192071

    申请日：2016-06-24

    Applicant: BASF SE

    Inventor： Huiguang Kou ,  Clemens Auschra ,  Frank Pirrung

    IPC: C08F8/30 ,  C08F22/10 ,  C09D167/04 ,  C08F2/00 ,  C08G63/685 ,  C08G63/91 ,  C08G64/02 ,  C08G64/42 ,  C09D17/00 ,  C09D11/102 ,  C09D133/08 ,  C09D133/14 ,  C09D177/12 ,  C08F8/32 ,  C09D151/00 ,  C08F10/00

    CPC classification number: C09D167/04 ,  C08F2/00 ,  C08F8/32 ,  C08F10/00 ,  C08G63/6852 ,  C08G63/912 ,  C08G64/0241 ,  C08G64/42 ,  C09D11/102 ,  C09D17/00 ,  C09D133/08 ,  C09D133/14 ,  C09D151/003 ,  C09D177/12 ,  C08F220/18 ,  C08F293/005

    Abstract: The present invention relates to novel polymer dispersants and to a liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The polymer dispersants have at least one functional moiety of the formula I, which is bound to one of the termini or to the backbone of the polymer: (I) where # indicates the point of attachment to the terminus and/or to the polymer backbone; k is 0, 1, 2, 3 or 4; m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9; A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, —O—(C2-C6 alkylene), —C(═O)—O—(C2-C6 alkylene), —NR3—(C2-C6 alkylene) and C(═O)—NR3—(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of —O—, —NH— and —S—; R1 is independently selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C20 alkyl, C1-C4 alkoxy, halogen, aryloxy, aryl, heteroaryl, where aryl, hetaryl and aryloxy are unsubstituted or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C4 alkyl, C1-C4 alkoxy and halogen; R2 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl, heteroaryl, aryl-C1-C4-alkyl and heteroaryl-C1-C4-alkyl, where aryl and hetaryl in the four last mentioned radicals are unsubstituted or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C4 alkyl, C1-C4 alkoxy and halogen; R3 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl and heteroaryl, where aryl and hetaryl are unsubstituted or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C4 alkyl, C1-C4 alkoxy and halogen; R4 is selected from the group consisting of OH, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, C1-C4 alkyl, C1-C4 alkoxy, aryl and heteroaryl,

    Polymer dispersants
    17.
    发明授权
    Polymer dispersants 有权

    公开(公告)号：US09670350B2

    公开(公告)日：2017-06-06

    申请号：US14896581

    申请日：2014-06-06

    Applicant: BASF SE

    Inventor： Huiguang Kou ,  Clemens Auschra ,  Frank Pirrung ,  Matthias Maier ,  Dario Perera-Diez

    IPC: C08F8/32 ,  C08L25/14 ,  C09D11/10 ,  C08F212/08 ,  C09D11/00 ,  C09D125/14

    CPC classification number: C08L25/14 ,  C08F8/32 ,  C08F212/08 ,  C09D11/00 ,  C09D11/10 ,  C09D125/14 ,  C08F222/08

    Abstract: The present invention relates to novel polymer dispersants in the form of comb polymers P and to a liquid composition containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The comb polymer P having at least 0.5 mol-%, e.g. 0.5 to 90 mol-%, based on the total amount of repeating units in the comb polymer, of repeating units A, selected from repeating units of the formulae la and lb: wherein R1 is selected from the group consisting of hydrogen, —S(═O)2Ra, C1-C20 alkyl, C3-C10 cycloalkyl, aryl, heteroaryl, aryl-C1-C4-alkyl and heteroaryl-C1-C4-alkyl; and X indicates a polymer group of the following formula X wherein Z indicates a polymer segment or a monovalent alkyl or alkenyl segment having from 10 to 100 carbon atoms; R1 is as defined above; k is 0, 1, 2, 3 or 4; n is 0, 1 or 2; A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, —O—(C2-C6 alkylene) or —C(═O)—O—(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of —O—, —NH— and —S—; R2 is independently selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2Ra, C1-C20 alkyl, C1-C4 alkoxy, halogen, aryloxy, aryl, heteroaryl.

    Dispersant composition
    20.
    发明授权
    Dispersant composition 有权

    公开(公告)号：US11492501B2

    公开(公告)日：2022-11-08

    申请号：US16070641

    申请日：2017-01-11

    Applicant: BASF SE

    Inventor： Frank Pirrung ,  Matthias Maier ,  Sonja Gesine Gabriel ,  Steffen Onclin

    IPC: C09D7/45 ,  C09D17/00 ,  C09B67/46 ,  C09K23/00 ,  C09K23/14 ,  C09K23/16

    Abstract: The present invention relates to a dispersant composition comprising: a) at least one oligomeric acid A, which has i) at least one acidic group selected from COOH and PO3H2, and ii) at least one polyoxyalkylene-ether radical of the formula (I): R—(O-A)xO-G-, where A is an C2-C4-alkan-1,2-diyl radical; X is an integer having a number average value in the range from 2 to 20; and R is hydrocarbon radical having from 1 to 30 carbon atoms; G is a chemical bond or a carbonyl group; and b) at least one polyamine B, which is selected from the group consisting of polyvinylamines, poly-C2-C3-alkyleneimines, modified poly-C2-C3-alkyleneimines, melamine compounds, modified melamine compounds, poly-(C2-C4-alkyleneether) amines, polyetheramine polyols, and modified polyetheramine polyols. The invention also relates to aqueous pigment compositions containing a dispersant composition as defined herein, a pigment component, selected from the group consisting of pigments and mixtures of at least one pigment and at least one filler, and an aqueous diluent.

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