摘要:
Sponge iron produced by direct reduction is melted in an electric arc furnace, in which a pool of liquid metal is maintained. To ensure that liquid carbon-containing iron for forming the pool is available in adequate quantities and that the process can be carried out with the highest possible economy, the sponge iron is reacted in an electric arc furnace on a bath of liquid carbon-containing iron (hot metal), which has been produced from sponge iron or from partly reduced ore in an electric reducing furnace, and in dependence on the electric load changes which are due to the operation of the electric arc furnace the operation of the electric reducing furnace is so controlled that a virtually constant load on the electric power supply system is maintained.
摘要:
Before iron oxide-containing materials is reduced in a rotary kiln by a treatment with solid carbonaceous reducing agents below the melting point of the charge, the iron oxide containing material and carbonaceous reducing agent are preheated in a multiple-hearth furnace, in which the reducing agent is subjected to an at least partial coking or an at least partial low-temperature carbonization. To prevent a partial reduction and sintering, the iron oxide-containing material is preheated in the upper part of the multiple-hearth furnace and the solid carbonaceous reducing agent is separately preheated in the lower part of the multiple-hearth furnace. At least part of the gases produced by the low-temperature carbonization in the lower part of the multiple-furnace is caused to flow in the upper part of said furnace in a countercurrent to the iron oxide-containing material to supply the heat required in said upper part.
摘要:
In a Waelz process of volatilizing zinc and lead from iron-containing and oxide-containing material in an inclined rotary kiln, which is charged at its upper end with the material together with solid carbonaceous reducing agent having a high content of volatile combustible constituents, wherein the reduction and volatilization are effected below the softening point of the charge, metallic iron-containing material is discharged from the lower end of the rotary kiln, combustion air is sucked into the lower end of the rotary kiln, and the exhaust gases are sucked from the upper end, the improvement which comprises blowing oxygen-containing gases through tubular air nozzles into the charge disposed over said tubular air nozzles in that region of the heating-up zone which begins where ignitable particles of the solid reducing agent begin to occur and which terminates at up to 50 percent of the length of the kiln.
摘要:
A process has been developed for directly reducing iron-containing oxidic materials to sponge iron by means of a moist solid carbonaceous reducing agent having a high volatile content in a rotary kiln in which the solid charge and a gaseous atmosphere move in counter-current flow through the kiln.
摘要:
In the operation of the rotary kiln provided at its charging end with a central burner, solid reducing agents having a high content of volatile constituents are used and the charge and the gas atmosphere are conducted in cocurrent streams. To avoid a high heat load per unit of volume in the heating-up zone and yet to increase the heating-up rate, a solid carbonaceous reducing agent having a high content of volatile constituents is charged together with the iron oxide-containing material into the charging end of the rotary kiln, oxygen-containing gases are blown through nozzle blocks into the free gas space and into the charge in the heating-up zone, and oxygen-containing gases are blown through nozzle blocks into the free kiln space in the reducing zone.
摘要:
A process is disclosed for producing quicklime by a calcining treatment with a hot gas in a rotary kiln, wherein solid carbonaceous fuel for producing hot gas is fed into the charging end of the rotary kiln and an oxygen-containing gas is blown through nozzle blocks into the charge disposed over nozzle blocks in the heating-up zone beginning at the point where ignitable particles of the solid fuel first appear, the improvement wherein:(a) an oxygen-containing gas is blown through nozzle blocks into the charge disposed over nozzle blocks in that region of the heating-up zone which begins with the appearance of ignitable particles of the solid fuels and which ends where the temperature in the charge does not rise further;(b) oxygen-containing gases are blown through nozzle blocks into the charge disposed over nozzle blocks in a calcining zone which succeeds said heating-up zone and at such a rate that the temperature in the charge is held constant and for as long as the temperature remains constant,(c) oxygen-containing gases are blown into the free kiln space where the kiln atmosphere contains combustible gaseous constituents, and(d) the rates at which oxygen-containing gases are blown into the free kiln space are so controlled that the exhaust gas is virtually free from combustible gaseous constituents.
摘要:
Iron oxide-containing materials, such as iron ores, are directly reduced to produce sponge iron by a treatment with solid carbonaceous reducing agents in a rotary kiln at temperatures below the softening and melting point of the charge wherein the kiln atmosphere flows opposite to the direction of movement of the charge. At least part of the solid carbonaceous reducing agent is charged in an agglomerated form into the rotary kiln at the charging end thereof and oxygen containing gases are fed into the rotary kiln. A highly reactive, solid carbonaceous reducing agent containing 20-50% volatile constituents are charged in agglomerated form into the rotary kiln the charging end thereof and are heated up at such a rate that the reducing agent disintegrates into fine particles substantially in and before the end of the heating-up zone of the rotary kiln.
摘要:
Sponge iron is produced by a direct reduction of iron oxide containing materials in a rotary kiln, the material discharged from the rotary kiln is separated into sponge iron and material which contains surplus carbon, the carbon-containing material is burnt in a fluidized bed reactor containing a circulating fluidized bed, and the heat generated by the combustion is recovered and utilized to produce electric power. To ensure a utilization of the surplus energies of the rotary kiln process and to minimize the contents of SO.sub.2, NO.sub.X, and CaS, the dust-containing exhaust gas from the rotary kiln is supplied to the fluidized bed reactor and is afterburnt therein, at least a major part of all oxygen-containing gases supplied to the fluidized bed reactor is supplied as a fluidizing gas to the lower portion of the fluidized bed reactor, the combustion of the combustible constituents is effected with an over-stoichiometric oxygen content, and the solids entrained by the gases discharged from the fluidized bed reactor are recycled to the fluidized bed reactor in such a manner that the weight of solids circulated per hour is at least 5 times the weight of the solids contained in the fluidized bed reactor.
摘要:
A radiation sensitive polymeric material comprising a copolymer of methyl methacrylate and allyl methacrylate and at least one organosulfur compound having at least two --SH groups per molecule, said material being useful as a polymer resist sensitive to high energy radiation.
摘要:
Fine-grained material which contains iron oxide is prereduced in a fluidized bed and is subsequently completely reduced in a rotary kiln. In order to avoid agglomeration and incrustation in the rotary kiln, the prereduction is carried out to effect a metallization of 50 to 80%.