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    Catalyst components and their use in the polymerization of olefins
    11.
    发明申请
    Catalyst components and their use in the polymerization of olefins 审中-公开
    催化剂组分及其在烯烃聚合中的应用

    公开(公告)号：US20050148460A1

    公开(公告)日：2005-07-07

    申请号：US10751243

    申请日：2004-01-02

    Applicant: Vladimir Marin ,  Abbas Razavi

    Inventor： Vladimir Marin ,  Abbas Razavi

    IPC: C07F17/00 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  B01J31/00

    CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/52 ,  C08F4/65927 ,  C08F2500/15 ,  C08F210/16

    Abstract: Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers specific to the polymerization of propylene to produce isotactic polypropylene and copolymer, specifically an ethylene-propylene copolymer. An olefin polymerization catalyst is characterized by the formula: B(FluA)MQn wherein Flu is a fluorenyl group substituted at the 4(5) position by a bulky hydrocarbyl group having at least 3 carbon atoms, A is a substituted or unsubstituted cyclopentadienyl or indenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 such as nitrogen. R is an alkyl group or cycloalkyl group or a mononuclear aromatic group which may be substituted or unsubstituted. B is a structural bridge which imparts stereorigidity to the ligand structure. The bridge B is characterized by the formula ER′R″, in which E is a carbon, silicon or germanium atom, and R′ and R″ are each independently an alkyl group, an aromatic group or a cycloalkyl group. M is a Group 4 or Group 5 transition metal such as titanium, zirconium or hafnium. Q is chlorine, bromine, iodine, an alkyl group, an amino group or an aromatic group. n is 1 or 2. The fluorenyl group may be substituted at both of the 4 or 5 positions with a bulky hydrocarbyl group containing at least 3 carbon atoms. A may take the form of an indenyl group which is substituted or unsubstituted, or a cyclopentadienyl group which is substituted at the 3 or the 3 and 5 positions. The fluorenyl group may be mono-substituted at the 4 (or 5) position and is otherwise unsubstituted or is di-substituted at the 2,7 positions with alkyl or phenyl or substituted phenyl groups.

    Abstract translation: 催化剂组合物和烯属不饱和单体的聚合方法，用于制备丙烯聚合物特异性聚合物以产生全同立构聚丙烯和共聚物，特别是乙烯 - 丙烯共聚物。 烯烃聚合催化剂的特征在于以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> B（FluA）MQ 其中Flu是在4（5）位被具有至少3个碳原子的大体积烃基取代的芴基，A是取代或未取代的环戊二烯基 或茚基或杂有机基团XR，其中X为第15族或第16族的杂原子，例如氮。 R是可以被取代或未取代的烷基或环烷基或单核芳香基。 B是赋予配体结构立体刚性的结构桥。 桥B的特征在于式ER'R“，其中E是碳，硅或锗原子，R'和R”各自独立地是烷基，芳族基团或环烷基。 M是第4族或第5族过渡金属，例如钛，锆或铪。 Q是氯，溴，碘，烷基，氨基或芳基。 n是1或2.芴基可以在具有至少3个碳原子的庞大烃基的4或5位上被取代。 A可以是取代或未取代的茚基，或在3或3和5位被取代的环戊二烯基的形式。 芴基可以在4（或5）位上被单取代，并且是未取代的或在2,7位被二烷基或苯基或取代的苯基二取代。

    Fluorinated Impregnated Catalyst Systems and Methods of Forming the Same
    12.
    发明申请
    Fluorinated Impregnated Catalyst Systems and Methods of Forming the Same 审中-公开
    氟化浸渍催化剂体系及其形成方法

    公开(公告)号：US20120309914A1

    公开(公告)日：2012-12-06

    申请号：US13486732

    申请日：2012-06-01

    Applicant: Vladimir Marin

    Inventor： Vladimir Marin

    IPC: C08F10/06

    CPC classification number: C08F10/00 ,  Y10S526/943 ,  C08F4/52 ,  C08F4/02

    Abstract: Methods of forming supported catalyst systems, supported catalyst systems and polymerization processes utilizing supported catalyst systems are described. The methods include providing an inorganic support material, contacting the inorganic support material with a support solvent to form a support solution, and contacting the support solution with a fluorine containing compound (AlFpX3−pBq) to form an intermediate. X is Cl, Br or OFF, B is H2O, p is from 1 to 3 and q is 0 to 6. The methods include drying and heating the intermediate to at least about 300° C. to form an impregnated support and contacting the impregnated support with a transition metal compound ([L]mM[A]n) to form a supported catalyst system. L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to the transition metal valency.

    Abstract translation: 描述了形成负载型催化剂体系的方法，负载型催化剂体系和利用负载型催化剂体系的聚合方法。 所述方法包括提供无机载体材料，使无机载体材料与载体溶剂接触以形成载体溶液，并使载体溶液与含氟化合物（AlFpX3-pBq）接触以形成中间体。 X为Cl，Br或OFF，B为H 2 O，p为1至3，q为0至6.该方法包括将中间体干燥并加热至至少约300℃，以形成浸渍的载体并使浸渍的 用过渡金属化合物（[L] mM [A] n）负载以形成负载型催化剂体系。 L是体积大的配体，A是离去基团，M是过渡金属，m和n使得总配体的化合价对应于过渡金属的价态。

    PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLYMERIZATION OF OLEFINS
    13.
    发明申请
    PREPARATION AND USE OF TETRASUBSTITUTED FLUORENYL CATALYSTS FOR POLYMERIZATION OF OLEFINS 审中-公开
    用于聚合烯烃的四唑基氟化物催化剂的制备和使用

    公开(公告)号：US20120095175A1

    公开(公告)日：2012-04-19

    申请号：US13313059

    申请日：2011-12-07

    Applicant: Vladimir Marin ,  Abbas Razavi

    Inventor： Vladimir Marin ,  Abbas Razavi

    IPC: C08F4/76 ,  C08F2/00 ,  C08F10/06 ,  C07F17/00

    CPC classification number: C07F7/00 ,  B01J31/2282 ,  B01J2231/122 ,  B01J2531/0263 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/03

    Abstract: Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. The polymerization catalyst characterized by the formula B(FluL)MQn in which Flu is a fluorenyl group substituted at least the 2,7- and 3,6-positions by hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1 or 2.

    Abstract translation: 催化剂组合物和用于聚合烯属不饱和单体以生产聚合物的方法，包括共聚物或均聚物。 其特征在于式B（FluL）MQn的聚合催化剂，其中Flu是通过烃基取代至少2,7-和3,6位的芴基。 L是取代或未取代的环戊二烯基，茚基或芴基或杂有机基团XR，其中X是元素周期表第15或16族的杂原子，R是烷基，环烷基或芳基 B是在L和Flu之间延伸的结构桥，M是第4族或第5族过渡金属，例如钛，锆或铪，Q选自氯，溴，碘，烷基 ，氨基，芳基及其混合物，n为1或2。

    Fluorinated transition metal catalysts and formation thereof
    14.
    发明申请
    Fluorinated transition metal catalysts and formation thereof 审中-公开
    氟化过渡金属催化剂及其形成

    公开(公告)号：US20070255028A1

    公开(公告)日：2007-11-01

    申请号：US11414653

    申请日：2006-04-28

    Applicant: Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    Inventor： Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    IPC: C08F4/44

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65916 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/03 ,  C08F2500/04

    Abstract: Supported catalyst systems and methods of forming polymers are generally described herein. The polymerization processes generally include contacting an inorganic support composition with a fluorinating agent to form a fluorinated support, wherein the fluorinating agent includes an organofluorine compound having the formula R4nAlF3-n and wherein each R is independently selected from alkyls, aryls and combinations thereof and n is 1 or 2, contacting the fluorinated support with a transition metal compound to form a supported catalyst system and contacting an olefin monomer with the supported catalyst composition to form a polyolefin.

    Abstract translation: 载体催化剂体系和形成聚合物的方法一般在此描述。 聚合方法通常包括使无机载体组合物与氟化剂接触以形成氟化载体，其中氟化剂包括具有式R 4的有机氟化合物， 其中每个R独立地选自烷基，芳基及其组合，n是1或2，使氟化支持物与过渡金属化合物接触以形成负载型催化剂体系，并使烯烃单体 与负载的催化剂组合物形成聚烯烃。

    Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components
    17.
    发明申请
    Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components 失效
    使用双亚氨基吡啶基过渡金属催化剂组分的乙烯聚合

    公开(公告)号：US20050090631A1

    公开(公告)日：2005-04-28

    申请号：US10691809

    申请日：2003-10-23

    Applicant: Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    Inventor： Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    IPC: C08F4/46 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/04 ,  C08F2500/04 ,  C08F210/14 ,  C08F4/60089 ,  C08F4/7042

    Abstract: Ethylene polymerization processes employing bis-imino pyridinyl transition metal components which exhibit C2, C2v or Cs symmetry. Catalyst components of the same or different symmetries may be employed to control polymerization characteristics and characteristics of the resulting polymer products such as polymer yield and polymer molecular weight. The transition metal catalyst component is characterized by the formula: wherein M is a Group 4-11 transition metal, n is an integer within the range of 1-3, Q is a halogen or a C1-C2 alkyl group, and PY is a pyridinyl group which is coordinated with M through the nitrogen atom of the pyridinyl group. Further, with respect to formula (I), A is a methyl group, a phenyl group, or a substituted phenyl group and B, and B2 are the same or different aromatic groups depending on the symmetry of the catalyst component. The catalyst component and an activating co-catalyst component are contacted with ethylene in a polymerization reaction zone which is free of hydrogen or contains hydrogen in an amount which is less than 5 mole % of the ethylene under polymerization conditions to produce a polymer product which can be a ethylene homopolymer or a copolymer of ethylene and C3+ alpha olefin, specifically an ethylene-propylene copolymer.

    Abstract translation: 使用显示C2，C2v或Cs对称性的双亚氨基吡啶基过渡金属组分的乙烯聚合方法。 可以使用相同或不同对称性的催化剂组分来控制所得聚合物产物的聚合特性和特性，例如聚合物产率和聚合物分子量。 过渡金属催化剂组分的特征在于下式：其中M是4-11族过渡金属，n是1〜3的整数，Q是卤素或C 1〜 C 2烷基，PY是通过吡啶基的氮原子与M配位的吡啶基。 此外，对于式（I），A是甲基，苯基或取代的苯基，B和B 2是相同或不同的芳族基团，取决于 催化剂组分。 催化剂组分和活化助催化剂组分在聚合反应区中与乙烯接触，所述聚合反应区在聚合条件下不含氢或含有小于乙烯5摩尔％的氢，以产生聚合物产物， 是乙烯均聚物或乙烯和C 3 +α烯烃的共聚物，特别是乙烯 - 丙烯共聚物。

    Process for the preparation of substituted fluorenes
    19.
    发明授权
    Process for the preparation of substituted fluorenes 失效
    制备取代芴的方法

    公开(公告)号：US07605294B2

    公开(公告)日：2009-10-20

    申请号：US12277558

    申请日：2008-11-25

    Applicant: Vladimir Marin ,  Abbas Razavi

    Inventor： Vladimir Marin ,  Abbas Razavi

    IPC: C07C2/68

    CPC classification number: C07C17/2632 ,  C07C1/26 ,  C07C1/28 ,  C07C1/321 ,  C07C1/325 ,  C07C17/12 ,  C07C17/32 ,  C07C2531/24 ,  C07C2603/18 ,  C08F110/02 ,  C08F110/06 ,  C07C13/567 ,  C07C25/18 ,  C07C25/22 ,  C07C22/04 ,  C08F2500/15 ,  C08F2500/16

    Abstract: Methods for the preparation of fluorenyl-type ligand structures and substituted fluorenyl groups which may be employed in metallocene-type olefin polymerization catalysts. There is provided a 2,2′-dihalogen-diphenylmethylene having a methylene bridge connecting a pair of phenyl groups. Each phenyl group has a halogen on a proximal carbon atom relative to the methylene bridge. The halogenated diphenylmethylene is reacted with a coupling agent comprising a Group 2 or 12 transition metal in the presence of a nickel or palladium-based catalyst to remove the halogen atoms from the phenyl groups and couple the phenyl groups at the proximal carbon atoms to produce a fluorene ligand structure. The coupling agent may be zinc, cadmium or magnesium and the catalyst may be a monophosphene nickel complex. The halogenated diphenylmethylene may be an unsubstituted ligand structure or a monosubstituted or disubstituted ligand structure. The halogenated diphenylmethylene may be monosubstituted with a tertiary butyl group or may be a dialkyl diphenylmethylene having alkyl substituents at the directly distal positions of the phenyl groups relative to the methylene bridge.

    Abstract translation: 可用于茂金属型烯烃聚合催化剂中的芴基型配体结构和取代的芴基的制备方法。 提供了具有连接一对苯基的亚甲基桥的2,2'-二卤代 - 二苯基亚甲基。 每个苯基相对于亚甲基桥在近端碳原子上具有卤素。 卤化二苯基亚甲基与含有2或12族过渡金属的偶联剂在镍或钯基催化剂存在下反应，以从苯基除去卤素原子，并将近邻碳原子上的苯基偶联，生成 芴配体结构。 偶联剂可以是锌，镉或镁，催化剂可以是单磷酸镍络合物。 卤代二苯基亚甲基可以是未取代的配体结构或单取代或二取代的配体结构。 卤化二苯基亚甲基可以用叔丁基单取代，或者可以是在苯基相对于亚甲基桥的直接远端位置具有烷基取代基的二烷基二苯基亚甲基。

    FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS
    20.
    发明申请
    FLUORENYL CATALYST COMPOSITIONS AND OLEFIN POLYMERIZATION PROCESS 审中-公开
    氟代催化剂组合物和烯烃聚合方法

    公开(公告)号：US20090163688A1

    公开(公告)日：2009-06-25

    申请号：US12392145

    申请日：2009-02-25

    Applicant: Vladimir Marin ,  Abbas Razavi

    Inventor： Vladimir Marin ,  Abbas Razavi

    IPC: C08F110/06 ,  C08F210/06 ,  C08F210/02

    CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/20 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/12

    Abstract: An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: B(Cp)(Fl)MQ2 wherein M comprises a metal, Q comprises a halogen, an alkyl group or an aryl group or combinations thereof, Cp comprises a cyclopentadienyl group, Fl comprises a fluorenyl group, B is a bridging group that may be characterized by the general formula —YRH wherein Y comprises C or Si and R comprises an alkyl group, an aryl group, a poly-aryl group or combinations thereof.

    Abstract translation: 烯烃聚合方法包括在合适的反应条件下使反应区中的一种或多种烯烃和催化剂组分接触以形成聚烯烃，其中催化剂组分的特征在于下式： 公式“end =”lead“？> B（Cp）（F1）MQ2 <？in-line-formula description =”In-line formula“end =”tail“？>其中M包括金属，Q包括卤素， 烷基或芳基或其组合，Cp包含环戊二烯基，Fl包含芴基，B是可以由通式-YRH表征的桥连基团，其中Y包含C或Si，R包括烷基 ，芳基，聚芳基或其组合。

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