Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole

    公开(公告)号:US4975505A

    公开(公告)日:1990-12-04

    申请号:US501112

    申请日:1990-03-29

    申请人: Edward N. Squire

    发明人: Edward N. Squire

    IPC分类号: C08F234/02 H05K1/03 H05K3/28

    摘要: Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole with at least one fluoro comonomer selected from one or more of ten defined classes having a recited minimum mole proportion of perfluoro-2,2-dimethyl-1,3-dioxole, in no event less than 65%, have high glass transition temperatures of 140.degree. C. or higher, low indices of refraction, and good physical properties, and low dielectric constants, which make them suitable for cladding optical fibers as well as for many electronics applications, including the manufacture of substrates for circuit boards. They all are soluble at room temperature in perfluoro(2-butyltetrahydrofuran), which makes it practical to apply them as coatings from solution.

    Regulation of the degree of polymerization of vinyl or vinylidene
monomers with 2,5-dihydrofurans
    98.
    发明授权
    Regulation of the degree of polymerization of vinyl or vinylidene monomers with 2,5-dihydrofurans 失效
    乙烯基或亚乙烯基单体与2,5-二氢呋喃的聚合度的调节

    公开(公告)号:US3985942A

    公开(公告)日:1976-10-12

    申请号:US541272

    申请日:1975-01-15

    IPC分类号: C08F2/00 C08F2/38 C08F234/02

    CPC分类号: C08F2/38

    摘要: A process for producing vinyl or vinylidene polymers comprising polymerizing vinyl or vinylidene monomers in the presence of 0.1 to 5.0 % by weight of at least one compound represented by the following formula based upon the total weight of monomers, wherein the degree of polymerization of the vinyl or vinylidene polymers is controlled, ##EQU1## wherein R.sub.1 is --CR.sub.5 R.sub.6).sub.n wherein R.sub.5 and R.sub.6 are hydrogen atoms or alkyl groups containing 1 to 4 carbon atoms and n is an integer of 1 or more; R.sub.2 is a hydrogen atom or an alkyl group containing 1 to 4 carbon atoms; and R.sub.3 and R.sub.4 are hydrogen atoms or alkyl groups containing 1 to 4 carbon atoms may be combined to form a ring.

    摘要翻译: 一种生产乙烯基或亚乙烯基聚合物的方法,包括在基于单体总重量的0.1至5.0重量%的至少一种由下式表示的化合物存在下聚合乙烯基或亚乙烯基单体,其中乙烯基或亚乙烯基单体的聚合度 或亚乙烯基聚合物被控制,其中R 1是-CR 5 R 6)n其中R 5和R 6是氢原子或含有1至4个碳原子的烷基,n是整数1或 更多; R2是氢原子或含有1至4个碳原子的烷基; 并且R 3和R 4是氢原子或可以组合含有1至4个碳原子的烷基以形成环。

    ETHYLENE-(METH)ACRYLATE-BASED ELASTOMER AND METHOD FOR PRODUCING THE SAME

    公开(公告)号:US20240191014A1

    公开(公告)日:2024-06-13

    申请号:US18282456

    申请日:2022-03-18

    IPC分类号: C08F234/02

    CPC分类号: C08F234/02

    摘要: An ethylene-(meth)acrylate-based elastomer having a structure in which 40 to 79.9 mol % of ethylene, 20.0 to 50.0 mol % of an alkyl (meth)acrylate containing an alkyl group having 1 to 8 carbon atoms and/or an alkoxy (meth)acrylate containing an alkoxyalkyl group having 2 to 8 carbon atoms, 0.05 to 20.0 mol % of an unsaturated dicarboxylic acid monosaturated ester, and 0 to 20.0 mol % of an unsaturated dicarboxylic anhydride are copolymerized, and having a monosaturated esterification rate of the acid anhydride of 70% or more as measured by IR. The ethylene-(meth)acrylate-based elastomer gives a vulcanizate having excellent heat resistance, and molding processability.