Determination of nitrate in water and catalyst therein
    91.
    发明授权
    Determination of nitrate in water and catalyst therein 失效
    水中的硝酸盐和其中的催化剂的测定

    公开(公告)号:US4526870A

    公开(公告)日:1985-07-02

    申请号:US526510

    申请日:1983-08-26

    摘要: A method and catalyst for the determination of nitrate in water which has been obtained by reduction of a solution of a salt of a transition metal or group VIII of the periodic system and a transition metal salt of the copper group in the presence of an acid. The nitrate determination is effected by determining the nitrate extinction of a sample of water as compared with a blank sample in the UV region at 210 nm, a part of the sample of water whose nitrate has been reduced in the presence of hydrogen with the use of the catalyst of the invention being employed as blank sample.

    摘要翻译: 一种用于测定水中硝酸盐的方法和催化剂,其通过在酸的存在下还原过渡金属或周期系的VIII族的盐和铜基的过渡金属盐而获得。 硝酸盐测定通过测定在210nm的UV区域中与空白样品相比的水样品的硝酸盐消光来实现,其中硝酸盐在氢气存在下已经被还原的部分水样品使用 本发明的催化剂用作空白样品。

    Destruction method for the wet combustion of organics
    92.
    发明授权
    Destruction method for the wet combustion of organics 失效
    有机物湿法燃烧的破坏方法

    公开(公告)号:US4276198A

    公开(公告)日:1981-06-30

    申请号:US88272

    申请日:1979-10-25

    申请人: Richard A. Miller

    发明人: Richard A. Miller

    CPC分类号: C02F1/725 B01J27/25 C02F11/08

    摘要: The method of oxidizing organic compounds, such as 1,3,5-trichlorobenzene, in an aqueous system of pH not more than about 4, the method comprising oxidizing the organic compound by contacting the compound with an oxidizing agent, such as air, in the aqueous system in the presence of a catalytic amount of a cocatalyst system, is improved by using as the cocatalyst system a catalytic combination of nitrate ions, at least one of either bromide ions or iodide ions, and transition metal ions of at least one transition metal having two or more oxidation states, such as vanadium ions. This cocatalyst system enhances the rate of oxidation of the organic compounds.

    摘要翻译: 在pH不大于约4的水性体系中氧化有机化合物如1,3,5-三氯苯的方法,包括通过使化合物与氧化剂如空气接触来氧化有机化合物的方法 在催化量的助催化剂体系存在下,水系统通过使用作为助催化剂体系的硝酸根离子,溴离子或碘离子中的至少一种和至少一个过渡的过渡金属离子的催化组合而得到改善 具有两种或更多种氧化态的金属,例如钒离子。 该助催化剂体系提高了有机化合物的氧化速率。

    Supported solid phase catalyst, and preparation method and use thereof

    公开(公告)号:US10434501B2

    公开(公告)日:2019-10-08

    申请号:US15548178

    申请日:2015-08-12

    摘要: The present invention belongs to the flue gas desulfuration field. Specifically, the present invention relates to a supported solid-phase catalyst for oxidizing the by-product magnesium sulfite in a magnesium desulfuration process, and to preparation method and use thereof. The catalyst uses an activated carbon particle as a support, and cobalt nitrate, manganese nitrate, copper nitrate and ferrous nitrate as catalytically active components. The preparation method is as follows: mixing the pre-treated activated carbon support with the catalytically active components, followed by oscillating, standing under microwave irradiation, filtrating, drying, baking, so as to obtain the supported solid-phase catalyst. Raw materials of the present invention are inexpensive and easily available; the preparation process is simple; the catalyst has prominent catalytic effect and can be widely used in the magnesium desulfuration process in medium-sized and small-sized boilers of 75t or more to improve the recovery rate of the desulfuration by-product and reduce energy consumption of the oxidation system; the catalyst has a low amount of catalytically active components and causes low residue in the solution and hence no secondary pollution problem, and has a high generalization value.