公开(公告)号：US20050020708A1

公开(公告)日：2005-01-27

申请号：US10717901

申请日：2003-11-21

申请人： Askar Karami ,  George Ng ,  Le Tang

发明人： Askar Karami ,  George Ng ,  Le Tang

IPC分类号： C08G18/40 ,  C08G18/54 ,  C08G18/00

CPC分类号： C08G18/542 ,  C08G18/4027 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0058 ,  C08G2101/0083

摘要： The invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer load building properties to an isocyanate-based foam (e.g., a polyurethane foam). Indeed, its possible to utilize the sub-group of phenolic resins to partially or fully displace copolymer polyols conventionally used to confer load building characteristics to isocyanate-based polymer foams. Further, the invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer energy absorption properties in an isocyanate-based foam.

摘要翻译： 本发明涉及令​​人惊奇和意想不到的发现，即酚醛树脂（即，基本上完全不含醚部分的那些）的亚组特别有利于赋予异氰酸酯基泡沫（例如，聚氨酯泡沫 ）。 实际上，可能利用酚醛树脂的亚组部分或完全置换常规用于赋予异构体聚合物泡沫的负荷建筑特性的共聚物多元醇。 此外，本发明涉及令​​人惊奇和意想不到的发现，即酚醛树脂的亚组（即基本上完全不含醚部分的那些）特别有利于赋予异氰酸酯基泡沫体中的能量吸收性能。

公开(公告)号：US08124663B2

公开(公告)日：2012-02-28

申请号：US11781543

申请日：2007-07-23

申请人： Askar Karami ,  George Ng ,  Le Tang

发明人： Askar Karami ,  George Ng ,  Le Tang

IPC分类号： C08G18/28

CPC分类号： C08G18/542 ,  C08G18/4027 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0058 ,  C08G2101/0083

摘要： The invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer load building properties to an isocyanate-based foam (e.g., a polyurethane foam). Indeed, its possible to utilize the sub-group of phenolic resins to partially or fully displace copolymer polyols conventionally used to confer load building characteristics to isocyanate-based polymer foams. Further, the invention relates to the surprising and unexpected discovery that a sub-group of phenolic resins (i.e., those which are substantially completely free of ether moieties) is particularly advantageous to confer energy absorption properties in an isocyanate-based foam.

摘要翻译： 本发明涉及令​​人惊奇和意想不到的发现，即酚醛树脂（即，基本上完全不含醚部分的那些）的亚组特别有利于赋予异氰酸酯基泡沫（例如，聚氨酯泡沫 ）。 实际上，可能利用酚醛树脂的亚组部分或完全置换常规用于赋予异构体聚合物泡沫的负荷建筑特性的共聚物多元醇。 此外，本发明涉及令​​人惊奇和意想不到的发现，即酚醛树脂的亚组（即基本上完全不含醚部分的那些）特别有利于赋予异氰酸酯基泡沫体中的能量吸收性能。

公开(公告)号：US20100184879A1

公开(公告)日：2010-07-22

申请号：US12529273

申请日：2008-03-03

申请人： Romeo Stanciu ,  Paul V. Farkas ,  Hamdy Khalil ,  Askar Karami

发明人： Romeo Stanciu ,  Paul V. Farkas ,  Hamdy Khalil ,  Askar Karami

IPC分类号： C08J9/00 ,  C09K3/00

CPC分类号： C08G18/36 ,  C08G18/10 ,  C08G18/6696 ,  C08G18/7607 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G2290/00 ,  C08G2350/00 ,  C08G18/66

摘要： There is described a novoel isocyanate-based polymer foam. The isocyanate-based polymer foam is derived from a reaction mixture comprising: (a) an isocyanate; (b) a mixture of active hydrogen-containing compounds; and (c) a blowing agent. The mixture of active hydrogen-containing compounds comprises: (i) a bio-based polyol having an OH functionality of greater than about 2.0, an OH number in the range of from about 90 to about 200 and a molecular weight (Mn) of at least about 1100, and (ii) a petroleum-based active hydrogen-containing compound. It has been surprisingly and unexpectedly discovered that relatively high amounts (compared to the prior art) of such a bio-based polyol may be incorporated into an isocyanate-based polymer foam while maintaining a desirable balance of properties in the foam. Use of such a bio-based polyol (as a single bio-based polyol or a mixture of bio-based polyols) allows for displacement of at least a portion of petroleum-based polyols conventionally used in the production of isocyanate-based polymer foam while maintaining a desirable balance of properties in the foam, particularly molded foam. The addition benefit is that such displacement is of a component that this non-renewable and relatively more expensive than bio-based polyols.

摘要翻译： 描述了一种异氰酸酯基聚合物泡沫体。 异氰酸酯基聚合物泡沫衍生自包含以下物质的反应混合物：（a）异氰酸酯; （b）含活性氢的化合物的混合物; 和（c）发泡剂。 含活性氢的化合物的混合物包括：（i）具有大于约2.0的OH官能度，约90至约200的OH值，以及分子量（Mn）为约 至少约1100，和（ii）石油基活性氢化合物。 出人意料地发现与这种生物基多元醇相比，相对较高的量（与现有技术相比）可以引入到异氰酸酯基聚合物泡沫中，同时保持泡沫中所需的性能平衡。 使用这种基于生物的多元醇（作为单一生物基多元醇或生物基多元醇的混合物）允许至少一部分常规用于生产异氰酸酯基聚合物泡沫体的基于石油的多元醇的位移，同时 保持泡沫中特别是模塑泡沫的性能的理想平衡。 附加的好处是这种位移是这种不可再生的并且比基于生物的多元醇相对更贵的组成部分。

公开(公告)号：US5872205A

公开(公告)日：1999-02-16

申请号：US706336

申请日：1996-08-30

申请人： Stephen Thomas Balke ,  Sibichen Joseph ,  Askar Karami ,  Dennis Pao-Chang Lo ,  Mohammad Hadi Sayad

发明人： Stephen Thomas Balke ,  Sibichen Joseph ,  Askar Karami ,  Dennis Pao-Chang Lo ,  Mohammad Hadi Sayad

IPC分类号： B29B17/02 ,  C08J11/06 ,  C08F6/00

CPC分类号： C08J11/06 ,  B29B17/02 ,  B29B2017/0203 ,  B29K2023/06 ,  B29K2023/083 ,  B29K2023/12 ,  B29K2025/00 ,  B29K2031/04 ,  B29K2033/12 ,  B29K2709/08 ,  Y02W30/622 ,  Y02W30/701 ,  Y10T428/31855 ,  Y10T428/31913

摘要： The present invention provides a method enabling segregation of the various ingredients making up the polymer based products into component product streams and collection of these component streams so as to form individual product streams. Thus, according to this invention there is provided a process for purposefully segregating polymer-polymer and polymer-additive mixtures. The process for segregating the various combinations of components may be advantageously used on the one hand for the production of separate product streams from a mixture of polymers or polymer-additives in, for example, recycling of waste plastic based products, or on the other hand, in the production of polymer-polymer or polymer-additive layered structures exhibiting preselected spatial segregation of the various components. In its simplest form, the polymer segregation part of the process consists of a tube added to an extruder. During segregation, polymer layers containing different blend compositions are formed. Operating conditions are selected to enhance differences in viscosity between polymer components. This includes addition of low viscosity grades of one of the polymer components present to encourage migration of that component to the high shear region of the flow. Segregation may occur in either the extruder or in a tube added onto the end of the extruder, or in both. Preferential segregation of additives into one or more of the polymer layers can also be effected. Addition of components which attract the additives to be segregated provide a method of segregating a wide variety of additives.

摘要翻译： 本发明提供了一种能够将构成基于聚合物的产品的各种成分分离成组分产物流并收集这些组分流以形成单独的产物流的方法。 因此，根据本发明，提供了一种用于有目的地分离聚合物 - 聚合物和聚合物 - 添加剂混合物的方法。 分离各种组分组合的方法一方面可以有利地用于在例如废塑料基产品的再循环中从聚合物或聚合物添加剂的混合物生产分离的产物流，或者另一方面 在生产聚合物 - 聚合物或聚合物 - 添加剂层状结构时，表现出各种组分的预先选择的空间偏析。 在其最简单的形式中，该方法的聚合物偏析部分由加入到挤出机中的管组成。 在分离期间，形成含有不同共混组成的聚合物层。 选择操作条件以增强聚合物组分之间的粘度差异。 这包括添加存在的聚合物组分之一的低粘度级别以促进该组分迁移到流动的高剪切区域。 在挤出机中或在加入挤出机末端的管中或两者中都可能发生分离。 也可以将添加剂优先偏析成一个或多个聚合物层。 吸引要分离的添加剂的组分的添加提供了分离各种添加剂的方法。