Invention Grant
- Patent Title: Catalyst for preparation of an unsaturated carboxylic acid by gas phase oxidation of an unsaturated aldehyde
- Patent Title (中): 通过不饱和醛的气相氧化制备不饱和羧酸的催化剂
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Application No.: US14487383Application Date: 2014-09-16
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Publication No.: US09238217B2Publication Date: 2016-01-19
- Inventor: Cathrin Alexandra Welker-Nieuwoudt , Cornelia Katharina Dobner , Holger Borchert , Ulrich Hammon , Josef Macht , Andrey Karpov , Christian Walsdorff
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102013218628 20130917
- Main IPC: C07C51/235
- IPC: C07C51/235 ; B01J23/888 ; B01J37/04 ; B01J37/08 ; B01J35/02 ; B01J35/10 ; B01J37/00 ; B01J35/04 ; C07C51/25 ; B01J37/02 ; B01J23/94 ; B01J35/00 ; B01J23/00 ; B01J23/887

Abstract:
What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
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