Invention Grant
US09238217B2 Catalyst for preparation of an unsaturated carboxylic acid by gas phase oxidation of an unsaturated aldehyde 有权
通过不饱和醛的气相氧化制备不饱和羧酸的催化剂

Catalyst for preparation of an unsaturated carboxylic acid by gas phase oxidation of an unsaturated aldehyde
Abstract:
What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) ⁢ S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
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