发明授权
US4265817A Novel chiral ethers and their use in resolution of alcohols and phenols
失效
新型手性醚及其在醇和酚的拆分中的应用
- 专利标题: Novel chiral ethers and their use in resolution of alcohols and phenols
- 专利标题(中): 新型手性醚及其在醇和酚的拆分中的应用
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申请号: US21833申请日: 1979-03-19
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公开(公告)号: US4265817A公开(公告)日: 1981-05-05
- 发明人: Jacques Martel , Jean Tessier , Andre Teche
- 申请人: Jacques Martel , Jean Tessier , Andre Teche
- 申请人地址: FRX Paris
- 专利权人: Roussel Uclaf
- 当前专利权人: Roussel Uclaf
- 当前专利权人地址: FRX Paris
- 优先权: FRX7807778 19780317
- 主分类号: B01J31/02
- IPC分类号: B01J31/02 ; C07B31/00 ; C07B57/00 ; C07B61/00 ; C07C27/00 ; C07C29/10 ; C07C29/88 ; C07C37/86 ; C07C41/18 ; C07C43/295 ; C07C45/57 ; C07C51/487 ; C07C62/02 ; C07C62/04 ; C07C67/00 ; C07D307/33 ; C07D307/88 ; C07D307/93 ; C07D315/00 ; C07D307/77
摘要:
Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and an substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.
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