Invention Application
- Patent Title: CATALYST FOR PREPARATION OF AN UNSATURATED CARBOXYLIC ACID BY GAS PHASE OXIDATION OF AN UNSATURATED ALDEHYDE
- Patent Title (中): 用于通过气相氧化不饱和二醛制备不饱和羧酸的催化剂
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Application No.: US14487383Application Date: 2014-09-16
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Publication No.: US20150080605A1Publication Date: 2015-03-19
- Inventor: Cathrin Alexandra WELKER-NIEUWOUDT , Cornelia Katharina Dobner , Holger Borchert , Ulrich Hammon , Josef Macht , Andrey Karpov , Christian Walsdorff
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Priority: DE102013218628.2 20130917
- Main IPC: B01J23/888
- IPC: B01J23/888 ; B01J37/04 ; C07C51/25 ; B01J35/04

Abstract:
What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
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