- 专利标题: Reactor for carrying out a gas-liquid two-phase high-pressure reaction with a foaming medium
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申请号: US17274135申请日: 2019-09-03
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公开(公告)号: US11884611B2公开(公告)日: 2024-01-30
- 发明人: Oliver Bey , Peter Zehner , Michael Acker , Rocco Paciello , Mathias Schelwies , Martin Haubner , Guenter Wegner , Gerd Tebben , Gunnar Heydrich , Georg Seeber
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen am Rhein
- 代理机构: Faegre Drinker Biddle & Reath LLP
- 优先权: EP 192739 2018.09.05
- 国际申请: PCT/EP2019/073477 2019.09.03
- 国际公布: WO2020/048991A 2020.03.12
- 进入国家日期: 2021-03-05
- 主分类号: C07C29/141
- IPC分类号: C07C29/141 ; B01J10/00 ; B01J3/04 ; B01J19/00 ; B01J19/24 ; B01J19/26 ; B01J19/30 ; B01J19/32 ; B01J31/20
摘要:
A reactor for performing a gas/liquid biphasic high-pressure reaction with a foaming medium, comprising an interior formed by a cylindrical, vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by internals into a backmixed zone and a zone of limited backmixing, wherein the backmixed zone and the zone of limited backmixing are consecutively traversable by the reaction mixture, wherein the backmixed zone comprises means for introducing gas and liquid and a gas outlet and also comprises at least one mixing apparatus selected from a stirrer, a jet nozzle and means for injecting the gas, and the zone of limited backmixing comprises a reaction product outlet, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a riser tube whose lower end is arranged within the backmixed zone and whose upper end opens into the zone of limited backmixing so that liquid from the backmixed zone can ascend into the zone of limited backmixing via the riser tube, wherein flow into the zone of limited backmixing enters from below. The reactor is configured such that the high-pressure reaction space is optimally utilized and contamination of workup steps or subsequent reactions arranged downstream of the high-pressure reaction with foam is substantially avoided. The invention further relates to a process for performing a continuous gas/liquid biphasic high-pressure reaction in the reactor.
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