- 专利标题: Method for epoxidation to produce alkene oxide
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申请号: US16454714申请日: 2019-06-27
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公开(公告)号: US10767172B2公开(公告)日: 2020-09-08
- 发明人: Stephane C. Corgie , Xiaonan Duan , Emmanuel Giannelis , Daniel Aneshansley , Larry P. Walker
- 申请人: CORNELL UNIVERSITY
- 申请人地址: US NY Ithaca
- 专利权人: CORNELL UNIVERSITY
- 当前专利权人: CORNELL UNIVERSITY
- 当前专利权人地址: US NY Ithaca
- 代理机构: Scully, Scott, Murphy & Presser, P.C.
- 主分类号: C12N11/04
- IPC分类号: C12N11/04 ; A62D3/02 ; B01J19/12 ; B01J35/04 ; B01J37/02 ; C02F1/48 ; C02F3/00 ; C02F3/34 ; C07C1/12 ; C07G1/00 ; C08F14/00 ; C08F18/00 ; C07D301/22 ; C12N11/14 ; C12P7/22 ; C12N9/02 ; C12N9/04 ; C12N9/08 ; C12N13/00 ; C12P7/04 ; C12P17/02 ; B01J31/00 ; B01J35/00 ; B01J31/02 ; B01J8/00 ; C12N11/08 ; B01J35/10 ; C02F101/32
摘要:
A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
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