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公开(公告)号：US20220356406A1
公开(公告)日：2022-11-10
申请号：US17621276
申请日：2020-07-24
申请人： SHELL OIL COMPANY
发明人： Kai Jürgen FISCHER , Sybe SIPMA
摘要： The present invention provides a process for the removal of contaminants from contaminated crude oil in a vessel. An organic solvent stream is provided to the vessel containing crude oil. After mixing, an organic solvent bottom phase is allowed to form. The bottom phase comprises at least a portion of the organic solvent stream and at least a portion of the contaminants. The bottom phase is removed from the vessel, while the remaining crude oil is retained in the vessel. An aqueous stream is provided to the vessel and mixed with the remaining crude oil, allowing an aqueous bottom phase to form. The aqueous bottom phase is removed from the vessel, while the remaining crude oil is retained in the vessel.
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公开(公告)号：US11479729B2
公开(公告)日：2022-10-25
申请号：US17211223
申请日：2021-03-24
IPC分类号： C10G9/00 , C10G9/34 , C10G53/06 , C10G21/00 , C10G67/06 , C10G49/00 , C10G21/22 , C10G29/28 , C10G9/36
摘要： A method of upgrading a petroleum feedstock, the method comprising the steps of introducing a disulfide oil, a water feed, and a petroleum feedstock to a supercritical water upgrading unit, and operating the supercritical water upgrading unit to produce a product gas stream, a product oil stream, and a used water stream.
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公开(公告)号：US20190264110A1
公开(公告)日：2019-08-29
申请号：US15905089
申请日：2018-02-26
摘要： A method of upgrading a petroleum feedstock, the method comprising the steps of introducing a disulfide oil, a water feed, and a petroleum feedstock to a supercritical water upgrading unit, and operating the supercritical water upgrading unit to produce a product gas stream, a product oil stream, and a used water stream.
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4.发明申请公开(公告)号：US20160075954A1
公开(公告)日：2016-03-17
申请号：US14814175
申请日：2015-07-30
CPC分类号： C10G53/06 , C10G21/16 , C10G21/27 , C10G2300/202
摘要： A method for removing sulfolane from hydrocarbon streams by serial separation using raffinate wash column and at least one raffinate wash drum. The separation may be particularly useful in retrofitting existing separation facilities to produce motor fuels meeting the specifications requiring lower sulfolane content. A method is provided for the purification of a hydrocarbon-containing stream having a sulfolane therein. The method includes separating a first sulfolane-depleted stream from a hydrocarbon stream in a first counter-current separation unit and then separating a second sulfolane-depleted stream from the first sulfolane-depleted stream in a second counter-current separation unit. The first and second counter-current separation units are preferably different and chosen from a raffinate wash column or at least one raffinate wash drum. An apparatus for performing the methods is also described.
摘要翻译： 一种通过使用萃余液洗涤塔和至少一个残液清洗桶通过连续分离从烃流中除去环丁砜的方法。 分离可能特别适用于改造现有的分离设备以生产符合要求较低环丁砜含量的规格的机动车燃料。 提供了在其中纯化含有环丁砜的含烃物流的方法。 该方法包括在第一逆流分离单元中从烃流中分离出第一环丁砜消耗流，然后在第二逆流分离单元中从第一环丁砜消耗流中分离出第二环丁砜消耗流。 第一和第二逆流分离单元优选地是不同的，并且从萃余液洗涤塔或至少一个萃余液洗涤滚筒中选择。 还描述了用于执行方法的装置。
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5.发明授权Solvent extraction process for removal of naphthenic acids and calcium from low asphaltic crude oil 有权从低沥青原油中除去环烷酸和钙的溶剂萃取方法公开(公告)号：US09238780B2
公开(公告)日：2016-01-19
申请号：US13767369
申请日：2013-02-14
发明人： Harender Bisht , Asit Kumar Das , Bibeka Hazarika , Biswajit Shown , D. P. S. Rana , Mahesh G. Marve , Manthan A. Malvanker , Paras N. Shah , Rohit R. Irabatti , Sukumar Mandal , Suyog S. Salgarkar
摘要： The present disclosure provides a process for obtaining extracted crude oil (ECO) which is substantially free of naphthenic acids, calcium and other impurities from low asphaltic crude oils or their residue fractions by preferential extraction of saturates using at least one solvent.
摘要翻译： 本公开提供了通过使用至少一种溶剂优先提取饱和物而获得基本上不含有低沥青原油或其残余物馏分的环烷酸，钙和其它杂质的萃取原油（ECO）的方法。
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6.发明申请公开(公告)号：US20150353847A1
公开(公告)日：2015-12-10
申请号：US14300709
申请日：2014-06-10
IPC分类号： C10G53/06
摘要： Methods are provided for extracting heterocyclic compounds, organometallic compounds, and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock such as crude oil or a crude fraction. The heterocyclic compounds and organometallic compounds are removed from the hydrocarbon feedstock through one or more successive extractions to form a first raffinate. The extractions use a first solvent system containing an ionic liquid formed from carbon dioxide and water. The polynuclear aromatic hydrocarbons are removed from the first raffinate using a second solvent system containing an aprotic solvent such as NMP, DMSO, aromatics, or combinations thereof. The extracted compounds remain chemically intact and may be fractionated for further applications. Further methods are provided for producing a hydrocarbon raffinate having reduced levels of heterocyclic compounds, organometallic compounds, and 2-4 cycle polynuclear aromatic hydrocarbons.
摘要翻译： 提供了用于从诸如原油或粗馏分的烃原料中提取杂环化合物，有机金属化合物和多环芳烃的方法。 通过一次或多次连续提取从烃原料中除去杂环化合物和有机金属化合物以形成第一残液。 提取物使用含有由二氧化碳和水形成的离子液体的第一溶剂体系。 使用含有非质子溶剂如NMP，DMSO，芳族化合物或其组合的第二溶剂体系，从第一萃余液中除去多核芳烃。 提取的化合物保持化学完整，并且可以分馏用于进一步的应用。 提供了进一步的方法来生产具有降低水平的杂环化合物，有机金属化合物和2-4个循环多核芳烃的烃萃余液。
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公开(公告)号：US09068129B2
公开(公告)日：2015-06-30
申请号：US13623271
申请日：2012-09-20
发明人： Pavel Kriz , Katherine Lynn Sokol
CPC分类号： C10G21/20 , C08L91/06 , C08L95/00 , C10C3/00 , C10G21/00 , C10G21/16 , C10G53/06 , C10G2300/1074 , Y02A30/333 , Y02P30/20 , C08L33/10
摘要： Methods are provided for upgrading the quality of an asphalt containing wax. This can include base asphalts that naturally contain elevated levels of wax, such as base asphalts with a wax content of at least 3.0 wt %. Additionally or alternately, this can include a base asphalt containing subsequently added wax. Wax generated at a refinery can be added to an asphalt along with a pour point depressant to form an asphalt product. The additional wax can reduce the viscosity of the asphalt product at higher temperatures so that the asphalt product can be mixed and stored at a tower temperature. Additionally, the pour point depressant can unexpectedly improve the low temperature properties of the wax-containing asphalt product.
摘要翻译： 提供了用于提高含沥青的蜡质量的方法。 这可以包括天然含有升高水平的蜡的碱性沥青，例如蜡含量为至少3.0重量％的碱性沥青。 另外或替代地，这可以包括含有随后加入的蜡的基础沥青。 在炼油厂产生的蜡可以与倾点下降剂一起添加到沥青中以形成沥青产品。 另外的蜡可以在较高的温度下降低沥青产品的粘度，使得沥青产品可以在塔温下混合和储存。 此外，倾点下降剂可以意外地改善含蜡沥青产品的低温性能。
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公开(公告)号：US5178747A
公开(公告)日：1993-01-12
申请号：US708532
申请日：1991-07-22
CPC分类号： C10G53/06 , C10G21/003
摘要： Non-carcinogenic bright stock extracts and/or deasphalted oils are produced from reduced hydrocarbon feedstocks. Such non-carcinogenic products are produced by establishing a functional relationship between mutagenicity index and a physical property correlative of hydrocarbon type for the bright stock extract or deasphalted oil and determining a critical physical property level which, when achieved, results in a product having a mutagenicity index of less than about 1.0. Process conditions are established so that a product stream achieving the desired physical property level can be produced. Non-carcinogenic bright stock extracts and/or deasphalted oils are then processed utilizing the conditions so established. A bright stock extract and a deasphalted oil substantially free from mutagenic activity, as well as processes for their production are also provided herein.
摘要翻译： 非致癌明亮的提取物和/或脱沥青的油是由还原的烃原料生产的。 这种非致癌产物是通过建立致突变性指数与光亮油提取物或脱沥青油的烃类型的物理性质之间的功能关系而产生的，并且确定临界物理性能水平，其在达到时导致具有致突变性的产物 指数小于约1.0。 建立工艺条件使得可以产生实现所需物理性能水平的产品流。 然后使用所建立的条件处理非致癌的亮色提取物和/或脱沥青油。 本文还提供了明亮的原料提取物和基本上不含致突变活性的脱沥青油以及它们的生产方法。
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公开(公告)号：US4810367A
公开(公告)日：1989-03-07
申请号：US50912
申请日：1987-05-15
CPC分类号： C10G21/003 , C10G53/06
摘要： A process for deasphalting a heavy hydrocarbon feedstock, comprising two stages of precipitation from the feedstock of an asphaltene fraction alone or, alternatively, of a resin fraction along with the asphaltene fraction, by means of a heavy solvent and a light solvent, respectively, is disclosed.In accordance with the process, the heavy solvent and the light solvent both contain, in different proportions, at least one hydrocarbon having 3 carbon atoms and at least one hydrocarbon having at least 5 carbon atoms, the proportion of the hydrocarbon having 3 carbon atoms being higher in the light solvent than in the heavy solvent.
摘要翻译： 重质烃原料脱沥青的方法，分别通过重溶剂和轻溶剂分别从沥青质馏分的原料单独沉淀出来，或者与沥青质馏分一起沉淀出树脂馏分。 披露 根据该方法，重溶剂和轻溶剂均以不同比例含有至少一种具有3个碳原子的烃和至少一个具有至少5个碳原子的烃，具有3个碳原子的烃的比例是 在轻溶剂中比在重溶剂中更高。
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公开(公告)号：US4169044A
公开(公告)日：1979-09-25
申请号：US946900
申请日：1978-09-28
申请人： Ralph P. Crowley
发明人： Ralph P. Crowley
IPC分类号： C10G53/06 , C10M175/00 , C10M11/00
CPC分类号： C10M175/005 , C10G2400/10
摘要： Process for re-refining used lubrication oil by contacting the used lube oil in a first extraction zone with a light hydrocarbon solvent, for example, propane, yielding a first extract and raffinate. The solvent is removed from the first extract to recover desired lubrication stock base. The first raffinate is then solvent-extracted, using the same solvent to produce a second extract and raffinate. The solvent is then removed from this second extract to yield an oil which can be further refined for separation of valuable constituents or burned as fuel oil. The second raffinate is flashed to remove any remaining solvent and leave an easily discardable solid residue.
摘要翻译： 通过使第一提取区中使用的润滑油与轻烃溶剂例如丙烷接触来再次精炼所使用的润滑油的方法，产生第一提取物和残液。 从第一提取物中除去溶剂以回收所需的润滑原料。 然后使用相同的溶剂对第一萃余液进行溶剂萃取以产生第二提取物和萃余液。 然后从该第二提取物中除去溶剂，得到油，其可进一步精制以分离有价值的组分或作为燃料油燃烧。 闪蒸第二个残液以除去任何剩余的溶剂，并留下容易丢弃的固体残留物。
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