公开(公告)号：US11407912B2

公开(公告)日：2022-08-09

申请号：US16500106

申请日：2018-03-01

申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH

发明人： Veronique Hall-Goulle ,  Luc Nueffer ,  Damien Schoehn ,  Olivier Brack ,  Willem Van Daal ,  Siro Dalle Nogare ,  Kurt Plattner

IPC分类号： D06P1/00 ,  C09D11/328 ,  C09B1/58 ,  C09B29/42 ,  C09B29/36 ,  C09B67/22 ,  C09D11/037 ,  D06P1/18 ,  D06P1/20 ,  D06P5/30 ,  D06P3/54 ,  D06P3/60 ,  D06P3/82

摘要： The present invention relates to a colorant mixture comprising (A) at least one blue- or black-dyeing disperse dye of formula wherein R1 denotes hydrogen or halogen, R2 and R3 are each independently of the other hydrogen; C1-C8-alkyl which is unsubstituted or substituted with hydroxy, cyano, C1-C4alkoxy or halogen; —(CH2)n—O—(CH2)mR4, wherein R4 denotes hydrogen or C1-C8-alkyl, n is a number from 2 to 6 and m is a number from 0 to 6; C5-C24aryl which is unsubstituted or substituted with hydroxy, carboxy, cyano, C1-C8alkyl, C1-C4alkoxy or halogen; or C6-C30aralkyl which is unsubstituted or substituted with hydroxy, cyano, C1-C4alkyl, C1-C8alkoxy groups or halogen; and (B) at least one yellow-, orange- or red-dyeing disperse dye, solvent dye, vat dye or pigment; and to the use thereof in dyeing or printing cellulose or cellulose blend fibre materials.

公开(公告)号：US09840622B2

公开(公告)日：2017-12-12

申请号：US15424893

申请日：2017-02-06

申请人： FUJIFILM CORPORATION

发明人： Tomohito Masaki ,  Junichi Miyadai

IPC分类号： C09B62/006 ,  C09B29/36 ,  C09B29/033 ,  C09B29/12 ,  C09B67/54

CPC分类号： C09B29/3691 ,  C09B29/0092 ,  C09B29/12 ,  C09B67/0096

摘要： Provided are an azo dye composition including an azo dye compound represented by Formula (I) and a urea compound represented by Formula (II), and a method for producing an azo dye composition. R11, R12, R13 and R14 each independently represent a hydrogen atom, a halogen atom, or an aliphatic group; R15 represents an aliphatic group; R21 and R22 each independently represent a hydrogen atom, an aliphatic group, or an aromatic group; and n represents an integer from 0 to 2.

公开(公告)号：US09556337B2

公开(公告)日：2017-01-31

申请号：US14714478

申请日：2015-05-18

申请人： Milliken & Company

发明人： Eduardo Torres ,  Xiaoyong M. Hong ,  Robert L. Mahaffey ,  Dominick J. Valenti ,  Gregory S. Miracle

IPC分类号： C09B44/04 ,  C09B44/08 ,  C09B44/16 ,  C11D3/42 ,  C09B29/36 ,  C09B69/10

CPC分类号： C09B29/3682 ,  C09B44/04 ,  C09B44/08 ,  C09B44/16 ,  C09B69/106 ,  C11D3/42

摘要： This application relates to thiophene azo dyes for use as hueing agents, laundry care compositions comprising such thiophene azo dyes, processes for making such thiophene azo dyes, and laundry care compositions and methods of using the same. The thiophene azo dyes contain a formally charged moiety and are generally comprised of at least two components: at least one chromophore component and at least one polymeric component. Suitable chromophore components generally fluoresce blue, red, violet, or purple color when exposed to ultraviolet light, or they may absorb light to reflect these same shades. These thiophene azo dyes are advantageous in providing a hueing effect, for example, a whitening effect to fabrics, while not building up over time and causing undesirable blue discoloration to the treated fabrics. The thiophene azo dyes are also generally stable to bleaching agents used in laundry care compositions.

摘要翻译： 本申请涉及用作调色剂的噻吩偶氮染料，包含这种噻吩偶氮染料的洗衣护理组合物，制备此类噻吩偶氮染料的方法，以及洗衣护理组合物及其使用方法。 噻吩偶氮染料含有正电荷的部分，通常由至少两种组分组成：至少一种发色团组分和至少一种聚合物组分。 当紫外线照射时，合适的发色团组分通常会发出蓝色，红色，紫色或紫色的颜色，或者它们可以吸收光线以反映这些相同的色调。 这些噻吩偶氮染料在提供调色效果方面是有利的，例如对织物的美白效果，而不会随着时间的推移而增加，并对经处理的织物造成不希望的蓝色变色。 噻吩偶氮染料也通常用于洗衣护理组合物中使用的漂白剂。

公开(公告)号：US20100245509A1

公开(公告)日：2010-09-30

申请号：US12161225

申请日：2007-01-19

申请人： Keiichi Tateishi

发明人： Keiichi Tateishi

IPC分类号： C09B29/36 ,  C09B29/00 ,  C09B29/42 ,  B41J2/01

CPC分类号： C09B29/36 ,  B41M5/5218 ,  C09B33/12 ,  C09D11/328

摘要： An ink includes at least one coloring matter represented by a formula (I): wherein R1 represents one of an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, an acyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an alkylsulfonyl group, an arylsulfonyl group and a sulfamoyl group, which may have a substituent; X1 represents one of —CR2═ and a nitrogen atom, R2 represents one of a hydrogen atom and a substituent, and when R2 represents a substituent, R2 may have a substituent; X2 represents one of —CR3═ and a nitrogen atom, and R3 represents an electron-withdrawing group having a σp value of 0.20 or more; when X1 represents —CR2═, a pair of R1 and R2 and/or when X2 represents —CR3═, a pair of R2 and R3 each may combine to form a 5- to 7-membered ring; the coloring matter may form one of a dimer and a trimer through R1, R2, R3 or A; and A represents a prescribed aryl group or heterocyclic group etc.

摘要翻译： 油墨包括由式（I）表示的至少一种着色剂：其中R1表示烷基，烯基，炔基，芳烷基，芳基，杂环基，酰基， 烷氧基羰基，芳氧基羰基，氨基甲酰基，烷基磺酰基，芳基磺酰基和氨磺酰基，其可以具有取代基; X1表示-CR2 =和氮原子之一，R2表示氢原子和取代基中的一个，当R2表示取代基时，R2可以具有取代基。 X2代表-CR3 =和氮原子之一，R3表示具有0.20以上p值的吸电子基团; 当X1表示-CR2 =时，一对R1和R2和/或当X2表示-CR3 =时，一对R2和R3各自可以组合形成5-至7-元环; 着色剂可以通过R1，R2，R3或A形成二聚体和三聚体之一; A表示规定的芳基或杂环基等。

公开(公告)号：US07513943B2

公开(公告)日：2009-04-07

申请号：US11976349

申请日：2007-10-24

申请人： Chien-Wen Lee ,  Shih-Hung Wang ,  Feng-Hung Lo ,  Tzu-Kwei Sun

发明人： Chien-Wen Lee ,  Shih-Hung Wang ,  Feng-Hung Lo ,  Tzu-Kwei Sun

IPC分类号： C09D11/00 ,  C09B29/36

CPC分类号： C09B29/366 ,  C09B67/0083

摘要： A yellow dye compound having a structure of following formula (I) is disclosed: wherein R1, R2, R3, and R4, is defined the same as in the specification. The yellow dye compound can be used in ink-jet ink. Also disclosed is a yellow ink composition including the yellow dye compound having the above formula (I).

摘要翻译： 公开了具有下式（I）结构的黄色染料化合物：其中R1，R2，R3和R4定义与说明书中相同。 黄色染料化合物可用于喷墨油墨。 还公开了包含具有上述式（I）的黄色染料化合物的黄色油墨组合物。

公开(公告)号：US20080010756A1

公开(公告)日：2008-01-17

申请号：US11661776

申请日：2005-08-24

申请人： Véronique Hall-Goulle ,  Athanassios Tzikas

发明人： Véronique Hall-Goulle ,  Athanassios Tzikas

IPC分类号： C09B29/42 ,  C09B29/36 ,  C09B31/153 ,  C09B67/00 ,  C09B67/38 ,  G03F7/00

CPC分类号： G03F7/0007 ,  C09B29/3639 ,  C09B31/153 ,  C09B67/008 ,  G03F7/105

摘要： A composition containing (A) an alkali-soluble binder and (B) an azo dye of formula (1), wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphtholic acid imide, chromone, phthalimide or diphenylene oxide series, X and Y are each independently of the other C2-C6alkylene, n is a number from 1 to 10, Z denotes oxygen or sulphur, and R1 is —X[—O—Y]n-ZH, wherein X, Y, Z and n are as defined above, C1-C12alkyl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups or C1-C8alkoxy groups, C5-C24aryl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, C6-C30aralkyl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, or a C5-C24cycloaliphatic group which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, is useful for the production of colour filters for liquid crystal displays, flat-panel displays, colour image pickup tubes, colour-copying machines etc.

摘要翻译： 包含（A）碱溶性粘合剂和（B）式（1）的偶氮染料的组合物，其中D是苯，萘，二苯基，偶氮苯，噻吩，苯并噻唑，苯并异噻唑，噻二唑的重氮组分的基团 ，吲唑，苯并三唑，吡唑，蒽醌，萘甲酰亚胺，色酮，邻苯二甲酰亚胺或二苯醚系列，X和Y各自独立地为C 2 -C 6 -C 6亚烷基 ，n为1〜10的数，Z为氧或硫，R 1为-X [-OY] n -ZH，其中，X，Y，Z 和n如上所定义，可以是未取代的或被一个或多个卤素原子，羟基，氨基或C 1 -C 12烷基取代的C 1 -C 12烷基， C 1 -C 8烷氧基，C 5 -C 20 -C 24芳基，其可以是未取代的或被一个或多个卤素原子取代 ，羟基，氨基，C 1 -C 12烷基或C 1 -C 8烷氧基 ，C

公开(公告)号：US07217803B2

公开(公告)日：2007-05-15

申请号：US10537063

申请日：2003-11-26

申请人： Leonhard Feiler ,  Thomas Raimann ,  Thomas Eichenberger ,  Max Hügin

发明人： Leonhard Feiler ,  Thomas Raimann ,  Thomas Eichenberger ,  Max Hügin

IPC分类号： C09B31/14 ,  C09B29/36 ,  C09B69/04 ,  D06P3/60

CPC分类号： C09B69/045 ,  C09B29/3617 ,  C09B31/14 ,  Y10S8/922

摘要： The present invention relates to azo dyes of formula (1) which are soluble in organic solvents, wherein R1 is —CN, —COOR5, —CONR6R7 or a heterocyclic ring, R2 is unsubstituted or substituted alkyl, unsubstituted or substituted aryl, —CF3, —COOR5, —CONR6R7 or —COR5, R3 is hydrogen, —SO3M, alkyl, alkoxy, alkylcarbonyl, —NO2 or halogen, R4 is substituted aryl, substituted heteroaryl or an aryl-N═N-aryl radical, wherein one or both of the aryl radicals in aryl-N═N-aryl is/are unsubstituted or substituted, or a radical heteroaryl-N═N-heteroaryl, wherein one or both of the heteroaryl radicals in heteroaryl-N═N-heteroaryl is/are unsubstituted or substituted, R5 is hydrogen, alkyl or unsubstituted or substituted aryl, R6 is hydrogen, alkyl or unsubstituted or substituted aryl, R7 is hydrogen, alkyl or unsubstituted or substituted aryl, M+ is a cation, n is a number 1, 2 or 3 and m is a number 1, 2 or 3, to a process for the preparation thereof and to the use thereof in the production of colored plastics or polymeric color particles, and as printing inks, printing dyes, coating compositions and wood stains

摘要翻译： 本发明涉及可溶于有机溶剂的式（1）的偶氮染料，其中R 1是-CN，-COOR 5，-CONR 6 R 7或杂环R 2是未取代或取代的烷基，未取代或取代的芳基，-CF 3 - ， - COOR 5，-CONR 6 R 7或-COR 5，R 3， 是氢，-SO 3 M，烷基，烷氧基，烷基羰基，-NO 2或卤素，R 4是取代的芳基，取代的杂芳基或 芳基-NH-芳基，其中芳基-NH-芳基中的一个或两个芳基是未被取代或取代的，或者是杂芳基-NH-杂芳基，其中杂芳基-NN中的一个或两个杂芳基 - 杂芳基是未取代或取代的，R 5是氢，烷基或未取代或取代的芳基，R 6是氢，烷基或未取代或取代的芳基，R SUB > 7是氢，烷​​基或未取代的 取代或取代的芳基，M + +是一种阳离子，n是数字1,2或3，m是数字1,2或3，其制备方法及其用途 在生产有色塑料或聚合彩色颗粒时，以及作为印刷油墨，印刷染料，涂料组合物和木材污渍

公开(公告)号：US20050175908A1

公开(公告)日：2005-08-11

申请号：US11043991

申请日：2005-01-28

申请人： Nobuo Seto ,  Nobuo Suziki

发明人： Nobuo Seto ,  Nobuo Suziki

IPC分类号： C09B29/01 ,  C09B29/033 ,  C09B29/36 ,  G02B5/22 ,  G03F7/00 ,  G03F7/022 ,  G03F7/027 ,  G03F7/038 ,  A61C3/00

CPC分类号： C09B29/3604 ,  C09B67/0033 ,  C09B67/0046 ,  G03F7/0007 ,  G03F7/0226 ,  G03F7/027

摘要： A dye represented by the following formula (1-1), a colored curable composition using the same, and a colored curable composition including a dye represented by the following formula (1) and at least one dye represented by the following formula (2) or (3): wherein Ra1 is an aliphatic group, an aryl group, a heterocyclic group, an acyl group or the like; Xa1 is —CRa3═ or N; Ra2 and Ra3 are each H or a substituent; B is a coupler residue; A is a residue of a 5-membered heterocyclic diazo component A-NH2; B1 and B2 is —CR1═, —CR2═ or N; R5 and R6 is H, an aliphatic group, an aromatic group, a heterocyclic group or the like; G, R1 and R2 is H, halogen, an aliphatic group, an aromatic group, a heterocyclic group, a cyano group, a carboxyl group, a carbamoyl group, an alkoxycarbonyl group or the like; Rd1 to Rd4 is H or an aliphatic group; Rd5 is a sulfo group or a sulfamoyl group; Rd6 to Rd10 is a substituent; m, n, p and q=0 to 3; r=0 to 4

摘要翻译： 由下式（1-1）表示的染料，使用该染料的着色固化性组合物和由下式（1）表示的染料和由下式（2）表示的至少一种染料的着色固化性组合物， 或（3）其中R a1是脂族基，芳基，杂环基，酰基等; X 1是N 3 - 或N; R a2和R a3各自为H或取代基; B是成色剂残基; A是5元杂环重氮组分A-NH 2的残基; B 1和B 2是-CR 1 - ， - CR 2 - 或N; R 5和R 6是H，脂族基团，芳族基团，杂环基团等; G，R 1和R 2是H，卤素，脂族基团，芳族基团，杂环基，氰基，羧基，氨基甲酰基， 烷氧基羰基等; Rd 1至Rd 4是H或脂族基团; Rd 5是磺基或氨磺酰基; Rd＆lt; 6＆gt;至Rd＆lt; 10＆gt;是取代基; m，n，p和q = 0〜3; r = 0〜4

公开(公告)号：US20050126431A1

公开(公告)日：2005-06-16

申请号：US10732093

申请日：2003-12-10

申请人： Joan Potenza ,  Marcel Madaras ,  Hans Schmitthenner ,  David Southby ,  Mihaela Madaras

发明人： Joan Potenza ,  Marcel Madaras ,  Hans Schmitthenner ,  David Southby ,  Mihaela Madaras

IPC分类号： C09B29/00 ,  C09B29/36 ,  C09D11/00

CPC分类号： C09D11/328 ,  C09B29/0037 ,  C09B29/3647

摘要： The invention relates to an ink composition comprising a dye, wherein said dye comprises a structure of Formula I: wherein R1 represents a hydrogen atom, a cyano group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group, an alkylthio group, an arylthio group an acyl group, a substituted acyl group, a carboxyl group, a carbamoyl group, or a heterocyclic group; Za represents one of —N═, —NH— or —C(R8)═; and Zb and Zc each independently represents one of —N═or —C(R8)═; R8 represents a hydrogen, a substituted or unsubstituted alkyl or a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group or a heterocyclic group; R2 represents a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a halogen, a cyano group, a carboxyl or substituted carboxyl group, an acyl group, a substituted acyl group, a carbamoyl group, a nitro group, an alkyl or aryl sulfone, a sulfonic acid, a substituted or unsubstituted primary or secondary alkyl sulfonamide, a substituted or unsubstituted aryl sulfonamide or a heteroaryl group; R3 may be hydrogen or any non-metallic group; R4, R5, R6 may be H or any non-metallic group with the proviso that at least one of R4 or R6 represents any ionizable group which is capable of imparting water solubility to the dye; R5 may be present in any other position on the aromatic ring that is not occupied by R4 or R6.

摘要翻译： 本发明涉及包含染料的油墨组合物，其中所述染料包括式I的结构：其中R 1表示氢原子，氰基，取代或未取代的烷基，取代或未取代的烷基， 未取代的环烷基，取代或未取代的烯基，取代或未取代的芳烷基，烷硫基，芳硫基，酰基，取代酰基，羧基，氨基甲酰基或杂环基。 Za代表-N-，-NH-或-C（R 8 N） - 之一。 Zb和Zc各自独立地表示-N或-C（R 8） - 之一。 R 8表示氢，取代或未取代的烷基或取代或未取代的烯基，取代或未取代的炔基或杂环基; R 2表示氢，取代或未取代的烷基，取代或未取代的芳基，卤素，氰基，羧基或取代的羧基，酰基，取代的酰基， 氨基甲酰基，硝基，烷基或芳基砜，磺酸，取代或未取代的伯或仲烷基磺酰胺，取代或未取代的芳基磺酰胺或杂芳基; R 3可以是氢或任何非金属基团; R 4，R 5，R 6可以是H或任何非金属基团，条件是R“ 4或R 6表示能赋予染料水溶性的任何可电离基团; R 5可以存在于不被R 4或R 6 X占据的芳环上的任何其它位置。

公开(公告)号：US20050057629A1

公开(公告)日：2005-03-17

申请号：US10502388

申请日：2003-01-23

申请人： Toshiki Taguchi ,  Manabu Ogawa ,  Takashi Ozawa

发明人： Toshiki Taguchi ,  Manabu Ogawa ,  Takashi Ozawa

IPC分类号： B41M5/00 ,  B41M5/52 ,  C09B29/033 ,  C09B29/36 ,  C09D11/00 ,  G01D11/00

CPC分类号： C09D11/00 ,  B41M5/52 ,  C09B29/0025 ,  C09B29/3604 ,  C09D11/32 ,  C09D11/328

摘要： An object of the present invention is to provide a magenta ink for ink jet recording excellent in weathering resistance. An additional object of the present invention is to provide a magenta ink for ink jet recording which is preferably provided with a hue as magenta ink, exhibits a high stability in ejection and causes no defects in water resistance and image quality in addition to the aforesaid requirement. The objects of the present invention are accomplished with an ink for ink jet recording comprising a magenta dye selected from azo dyes dissolved or dispersed in an aqueous medium, characterized in that said magenta dye is a dye having a absorption maximum in a spectral range of from 500 to 580 nm in said aqueous medium and a more positive oxidation potential than 1.0V (vs SCE), particularly with the aforesaid ink for ink jet recording wherein the azo dye has a specific structure having a 5-membered heterocyclic ring and a 4-amino-6-membered heterocyclic ring connected to the azo group.

摘要翻译： 本发明的目的是提供耐候性优良的用于喷墨记录的品红色油墨。 本发明的另一个目的是提供一种用于喷墨记录的品红色油墨，其优选地具有品红色油墨的色调，在喷射中表现出高稳定性，并且除了上述要求之外，不会产生耐水性和图像质量的缺陷 。 本发明的目的是通过一种用于喷墨记录的油墨来实现的，其包括选自溶于或分散在水性介质中的偶氮染料的品红色染料，其特征在于所述品红染料是在光谱范围内具有最大吸收的染料 在所述水性介质中为500〜580nm，比1.0V（与SCE）相比具有更高的氧化电位，特别是与上述喷墨记录用油墨相比，偶氮染料具有5元杂环的特殊结构， 连接到偶氮基的氨基-6-元杂环。