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公开(公告)号：US4002492A
公开(公告)日：1977-01-11
申请号：US592219
申请日：1975-07-01
申请人： Bhaskara M. L. Rao
发明人： Bhaskara M. L. Rao
摘要： A high energy density electrochemical cell comprises an anode consisting essentially between about 63% and 92% lithium, on an atomic basis, and the balance essentially aluminum, a cathode and a nonaqueous electrolyte. Advantageously, the cathode is an electrochemically active transition metal chalcogenide, such as titanium disulfide, and the nonaqueous electrolyte is an organic solvent, such as dioxolane, having at least one lithium salt, preferably lithium perchlorate, dissolved therein.
摘要翻译： 高能量密度电化学电池包括基本上在约63％至92％的锂之间的阳极，基于原子，余量基本上为铝，阴极和非水电解质。 有利地，阴极是电化学活性的过渡金属硫族化物，例如二硫化钛，非水电解质是溶解有至少一种锂盐，优选高氯酸锂的有机溶剂，例如二氧戊环。
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2.发明授权Additive for an alkaline battery employing divalent silver oxide positive active material 失效使用二氧化锡阳极活性材料的碱性电池添加剂
公开(公告)号：US3853623A
公开(公告)日：1974-12-10
申请号：US38475273
申请日：1973-08-01
申请人： ESB INC
发明人： DAVIS S
摘要： An alkaline battery having a divalent silver oxide (AgO) positive active material (cathode) in which gold ions are incorporated into the alkaline electrolyte on the positive side of the battery separator or barrier or added to the positive active material. The gold additive improves the stability of the divalent silver oxide (AgO) active material in the aqueous alkaline electrolyte without adversely affecting the electrochemical reactions during the discharge of the battery. The additive is present in the battery in amounts ranging from about 0.1 to about 10% by weight of silver in the divalent silver oxide positive active material. It is preferred that the divalent silver oxide active material contain at least 50% by weight of divalent silver oxide (AgO) with the balance of the active material comprising monovalent silver oxide (Ag2O) and metallic silver. The gold additive may be combined with other additives and has been found to be particularly effective in some batteries when combined with mercury and incorporated into either the positive active material or the electrolyte on the positive side of the separator.
摘要翻译： 具有二价氧化银（AgO）正极活性物质（阴极）的碱性电池，其中金离子被引入到电池隔板或屏障的正极侧的碱性电解质中或添加到正极活性物质中。 金添加剂改善了碱性电解液中二价氧化银（AgO）活性物质的稳定性，而不会对电池放电期间的电化学反应产生不利影响。 在二价氧化银正极活性物质中，添加剂以约0.1至约10重量％的银的量存在于电池中。 优选二价氧化银活性物质含有至少50重量％的二价氧化银（AgO），剩余的活性物质包含一价氧化银（Ag 2 O）和金属银。 金添加剂可以与其他添加剂组合，并且已经发现在与汞组合时在一些电池中特别有效并且并入正极活性材料或隔膜正极上的电解质中。
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3.发明授权Homogeneous cathode mixtures for secondary electrochemical power-producing cells 失效用于二次电化学发电电池的均质阴极混合物
公开(公告)号：US3827910A
公开(公告)日：1974-08-06
申请号：US31104872
申请日：1972-11-30
发明人： CAIRNS E , SHIMOTAKE H , SELMAN J
摘要： THIS INVENTION CONSISTS OF A SECONDARY,ELECTROCHEMICAL POWDER-PRODUCING CELL HAVING AN ANODE CONTAINING A MOLTEN ALKALI METAL OF LOW ELECTRONEGATIVITY,AN ELECTROLYTE CONTAINING ALKALI-METAL IONS, AND A NOVEL CATHODE CONTAINING A REACTANT COMPRISING A CHALCOGEN WHEREIN THE CATHODE COMPRISING A SUBSTNTIALLY HOMOGENEOUS MIXTURE OF THE RE-
ACTANT, A POROUS SUBSTRATE MATERIAL IMPREGNABLE BY THE REACTANT, ELECTROLYTE, AND AN ELECTRONICALLY-CONDUCTING MATERIAL.-
公开(公告)号：US3808052A
公开(公告)日：1974-04-30
申请号：US85331269
申请日：1969-08-27
申请人： DEY A
发明人： DEY A
摘要： Cathodic electrodes incorporating molybdenum trioxide (MoO3) active cathode material, methods of preparation thereof and organic electrolyte cells employing light metal anodes in combination therewith. A preferred preparation method is disclosed wherein an MoO3 cathode is produced by pyrolytic decomposition of a mixture incorporating a molybdenum salt, wherein the molybdenum is hexavalent. Cells exhibiting high energy density, extended shelf life, relatively constant output voltage and good current capability are also disclosed.
摘要翻译： 包含三氧化钼（MoO 3）活性阴极材料的阴极电极，其制备方法和使用轻金属阳极的组合的有机电解质电池。 公开了一种优选的制备方法，其中通过热解分解掺入钼盐的混合物制备MoO 3阴极，其中钼是六价的。 还公开了表现出高能量密度，延长的保存期限，相对恒定的输出电压和良好的电流能力的电池。
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公开(公告)号：US3770506A
公开(公告)日：1973-11-06
申请号：US3770506D
申请日：1970-09-28
申请人： STANDARD OIL CO
发明人： RIGHTMIRE R , METCALFE J , BENAK J
CPC分类号： H01M10/399
摘要： The capacity of an electrical energy storage device containing a high surface area carbon cathode, a metallic anode, and a fused salt electrolyte in contact with the electrodes, can be greatly enhanced by the addition of a tellurium compound directly to the electrolyte or to the carbon cathode. On passage of an electric current through the system, the tellurium becomes permanently bonded to the carbon of the cathode thereby forming an ''''active'''' tellurium species that manifests itself as a characteristic plateau in the discharge profile of the cell.
摘要翻译： 通过将碲化合物直接添加到电解质或碳中，可以大大提高包含高表面积的碳阴极，金属阳极和与电极接触的熔融盐电解质的电能存储装置的容量 阴极。 当电流通过系统时，碲永久地结合到阴极的碳上，从而形成“活性”碲物质，其表现为电池放电曲线中的特征平台。
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6.发明授权Sodium-sulfur battery having aluminum sulfide or aluminum polysulfide in the electrolyte 失效在电解液中具有硫化铝或聚合物的钠 - 硫电池
公开(公告)号：US3718505A
公开(公告)日：1973-02-27
申请号：US3718505D
申请日：1971-12-07
申请人： ESB INC
发明人： WERTH J
CPC分类号： H01M10/3909
摘要： A REDUCED OPERATING TEMPERATURE FOR A SODIUM-SULFUR BATTERY IS ACHIEVED WITH A NEW ELECTROLYTE COMPRISING SODIUM POLYSULFIDE, ALUMINUM SULFIDE OR ALUMINUM POLYSULFIDES AND FREE SULFUR WHEN THE ELECTRODES ARE IN THE CHARGE CONDITION. THE ELECTROLYTE, WHICH HAS A MELTING POINT IN THE RANGE OF APPROXIMATELY 200*C., PERMITS THE BATTERY TO BE SEALED WITH POLUTETRAFLUOROETHYLENE SEALING MATERIALS. BASED ON PRESENT LIMITED DATA, IT APPEARS THAT THE REDUCED MELTING POINT TEMPERATURE OF THE ELECTROLYTE CAN BE OBTAINED WITH SOLUTIONS IN WHICH THE RATIO OF THE MOLE PERCENT OF SODIUM POLYSULFIDE TO THE MOLE PERCENT OF ALUMINUM SULFIDE OR ALUMINUM POLYSULFIDE VARIES CONSIDERABLY.
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公开(公告)号：US3706601A
公开(公告)日：1972-12-19
申请号：US3706601D
申请日：1970-01-28
发明人： STRIER MURRAY P , SMATKO JOSEPH S
CPC分类号： H01M4/26
摘要： Method for producing a battery electrode, particularly a zinc electrode, of improved strength and stability, and which has a porous cellular structure, by mixing an aqueous dispersion of electrode material such as zinc oxide, with an aqueous dispersion of a latex type polymer such as a fluorocarbon polymer, e.g., polytetrafluoroethylene, casting a film of such mixture, drying the film, sintering the dried film, and rolling such sintered film, to form a fibrous polymer structure binding the particles of electrode material. The resulting sintered and rolled film can be employed per se as an electrode, e.g., a zinc electrode, or such film can be ground and the ground particles then compacted to form an electrode.
摘要翻译： 通过将电极材料如氧化锌的水性分散体与胶乳型聚合物的水分散体混合，制备具有改善的强度和稳定性并具有多孔多孔结构的电池电极，特别是锌电极的方法， 碳氟聚合物，例如聚四氟乙烯，浇铸这种混合物的膜，干燥膜，烧结干燥的膜，以及轧制这种烧结膜，形成结合电极材料颗粒的纤维聚合物结构。 所得到的烧结和轧制膜本身可以用作电极，例如锌电极，或者可以研磨这种膜，然后将研磨的颗粒压实以形成电极。
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8.发明授权Accumulator electrode with capacity for storing hydrogen and method of manufacturing said electrode 失效具有储存氢能力的蓄电池电极及制造电极的方法
公开(公告)号：US3669745A
公开(公告)日：1972-06-13
申请号：US3669745D
申请日：1970-04-24
发明人： BECCU KLAUS
CPC分类号： H01M4/242 , H01M4/86 , Y02E60/327
摘要： AN ACCUMULATOR ELECTRODE WITH CAPACITY FOR STORING HYDROGEN, HAVING AN ACTIVE COMPONENT CONSTITUTING AT LEAST 40% BY WEIGHT OF THE ELECTRODE AND CONSISTING OF A HYDRIDE OF A METAL BELONGING TO THE THIRD, FOURTH OR FIFTH GROUP OF TRANSITION ELEMENTS. THE ELECTRODE FURTHER CONTAINS NICKEL, COPPER, SILVER, IRON OR CHROME-NICKEL STEEL ALLOYED WITH THE ACTIVE COMPONENT AND COMPRISES A METALLIC SUPPORTING STRUCTURE. A METHOD OF MANUFACTURING THIS ELECTRODE, COMPRISES PREPARING A METAL POWDER CONTAINING THE ACTIVE COMPONENT AND SAID OTHER METAL AND SINTERING SAID POWDER IN HYDROGEN AT 700 TO 1000*C.
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公开(公告)号：US3666560A
公开(公告)日：1972-05-30
申请号：US3666560D
申请日：1970-09-21
CPC分类号： H01M4/745 , H01M10/399
摘要： AN ELECTROCHEMICAL POWER-PRODUCING CELL INCLUDING A MOLTEN LITHIUM METAL ANODE, A MOLTEN SELENIUM METAL CATHODE, A PASTE ELECTROLYTE SEPARATING THE ANODE FROM THE CATHODE, AN ANODE CURRENT COLLECTOR AND A SINGLE LAYER OF NIOBIUM EXPANDED METAL FORMED IN CORRUGATED SHAPE AS CATHODE CURRENT COLLECTOR. IN ADDITION MEANS ARE PROVIDED FOR SEALING THE ANODE AND THE CTHODE FROM LOSS OF LITHIUM AND SELENIUM RESPECTIVELY AND AN INSULATOR IS PROVIDED BETWEEN THE ANODE HOUSING AND THE PASTE ELECTROLYTE DISK.
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10.发明授权
公开(公告)号：US3558356A
公开(公告)日：1971-01-26
申请号：US3558356D
申请日：1967-02-28
发明人： JOST ERNEST M
CPC分类号： H01M10/30
摘要： A SEALED NICKEL-ZINC BATTERY SYSTEM IS SHOWN IN WHICH THE CHARGE CAPACITY OF THE POSITIVE NICKEL ELECTRODE SOMEWHAT EXCEEDS THE CHARGE CAPACITY OF THE NEGATIVE ZINC ELECTRODE FOR PREVENTING THE EVOLUTION OF OXYGEN AT THE POSITIVE ELECTRODE DURING CHARGING OF THE BATTERY SYSTEM, THE BATTERY SYSTEM BEING CHARACFTERIZED BY A SHARP CHANGE IN NEGATIVE ELECTRODE POTENTIAL AND SLIGHT EVOLUTION OF HYDROGEN AT THE NEGATIVE ELECTRODE WHEN THE NEGATIVE ELECTRODE IS FULLY CHARGED AND BY SUPPORTING MEMBRANE MEANS FOR VENTING HYDROGEN GAS FROM WITHIN THE BATTERY SYSTEM.
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