Solvent-free binder compositions and their use in one- and two-component coating compositions
    2.
    发明授权
    Solvent-free binder compositions and their use in one- and two-component coating compositions 失效
    无溶剂粘合剂组合物及其在单组分和双组分涂料组合物中的用途

    公开(公告)号:US06410095B1

    公开(公告)日:2002-06-25

    申请号:US08706551

    申请日:1996-09-06

    CPC classification number: C08G18/7837 C09D175/04 C09K3/1021 C14C11/006

    Abstract: The present invention relates to substantially solvent-free binder compositions containing a) a polyisocyanate component containing heteroallophanate groups and having aromatically-bound isocyanate groups, i) an NCO content of 3 to 16%, ii) an average functionality of 1.8 to 4, iii) an allophanate group content (calculated as C2N2O3, MW: 101) of 5 to 35% and iv) a hydrocarbon chain content of 10 to 65%, wherein the hydrocarbon chains are attached to allophanate groups via oxygen and have an average of 2 to 23 carbon atoms and b) an isocyanate-reactive component. The present invention also relates to the use of these binder compositions in one- and two-component coating compositions.

    Abstract translation: 本发明涉及基本上无溶剂的粘合剂组合物,其含有a)含杂芳族化合物基团并具有芳香族结合的异氰酸酯基团的多异氰酸酯组分,i)NCO含量为3至16%,ii)平均官能度为1.8至4,iii) 脲基甲酸酯基含量(按C2N2O3计算,MW:101)为5〜35%,烃链含量为10〜65%,其中烃链通过氧连接在脲基甲酸酯基上,平均含有2〜23碳 原子和b)异氰酸酯反应性组分。 本发明还涉及这些粘合剂组合物在单组分和双组分涂料组合物中的用途。

    Low temperature-drying waterborne coatings
    5.
    发明授权
    Low temperature-drying waterborne coatings 失效
    低温干燥水性涂料

    公开(公告)号:US06827983B2

    公开(公告)日:2004-12-07

    申请号:US09960034

    申请日:2001-09-20

    Abstract: The present invention relates to a storage-stable, waterborne, one-component, coating composition, which can be cured at temperatures below 100° C. to provide a stone chip resistant and sandable coating, containing as the binder a polyurethane dispersion A, which after physical drying results in a coating having a pendulum hardness according to DIN 53 157 of >90 s; a polyurethane dispersion B, which after physical drying results in a coating having a pendulum hardness (DIN 53 157) of

    Abstract translation: 本发明涉及一种储存稳定的水性单组分涂料组合物,其可以在低于100℃的温度下固化,以提供耐石棉片和可打磨的涂层,其包含作为粘合剂的聚氨酯分散体A,其中 在物理干燥后,导致具有根据DIN 53 157> 90s的摆锤硬度的涂层; 在物理干燥后导致摆锤硬度(DIN 53 157)<90秒的涂层的聚氨酯分散体B; 和三聚氰胺树脂C,其优选是高反应性的。本发明还涉及用这些涂料组合物和所得基材涂布基材的方法。

    Multi-component coatings, adhesives and sealants and the use thereof
    6.
    发明授权
    Multi-component coatings, adhesives and sealants and the use thereof 失效
    多组分涂料,粘合剂和密封剂及其用途

    公开(公告)号:US06756072B2

    公开(公告)日:2004-06-29

    申请号:US10240861

    申请日:2002-10-04

    Abstract: Multicomponent coating materials, adhesives and sealing compounds comprising a (meth)acrylate (A) containing, based on (A), up to 90% by weight of hydroxyl-containing monomers in copolymerized form, of which (a1) from 20-90% by weight, based on (A), are 4-hydroxybutyl (meth)acrylate and/or 2-alkylpropane-1,3-diol mono(meth)acrylate, and (a2) from 0-40% by weight based on (A), are other hydroxyl-containing monomers; and (B) an adduct preparable from (b1) a diisocyanate, and (b2) a compound of the general formula I having an isocyanate-reactive group: wherein R1 and R2 are hydrogen or alkyl radicals, X and Y are oxygen, sulfur or >N—R6 where R6 is alkyl radical or aryl radical, R3 is alkylene radical and R4 and R5 are hydrogen, isocyanate-reactive groups or radicals R6; where R4, R5 or R6 contains an isocyanate-reactive group or R4 or R5 is an isocyanate-reactive functional group, and where R4, R5 or R6, where present, contain no isocyanate-reactive groups and the molar ratio of isocyanate groups in (b1) to the isocyanate-reactive groups in the compound I is 1.0.

    Abstract translation: 包含基于(A)至多90重量%的共聚形式的含羟基单体的(甲基)丙烯酸酯(A)的多组分涂料,粘合剂和密封化合物,其中(a1)为20-90% (甲基)丙烯酸4-羟基丁酯和/或2-烷基丙烷-1,3-二醇单(甲基)丙烯酸酯,和(a2)基于(A)为0-40重量% )是其它含羟基的单体; 和(B)可由(b1)二异氰酸酯制备的加合物,和(b2)具有异氰酸酯反应性基团的通式I化合物:其中R 1和R 2是氢或烷基,X和 Y是氧,硫或> NR 6,其中R 6是烷基或芳基,R 3是亚烷基,R 4和R 5是氢,异氰酸酯反应性基团或基团R <6>; 其中R 4,R 5或R 6含有异氰酸酯反应性基团,或者R 4或R 5是异氰酸酯反应性官能团,其中R 4,R 5, 或R 6不存在异氰酸酯反应性基团,并且(b1)中的异氰酸酯基与化合物I中的异氰酸酯反应性基团的摩尔比为1.0。

    Oligomeric epoxy/isocyanate systems
    8.
    发明授权
    Oligomeric epoxy/isocyanate systems 失效
    低聚环氧/异氰酸酯体系

    公开(公告)号:US06426148B1

    公开(公告)日:2002-07-30

    申请号:US09462968

    申请日:2000-01-14

    Abstract: A curable coating composition comprising, in an organic solvent, a binder of (i) a non-isocyanate oligomer or blend of oligomers containing at least two functional groups with at least one being an epoxy group, the remaining being epoxy or hydroxyl; (ii) optionally a polyester, oligoester, or acrylic polymer with at least two hydroxyl groups; and (iii) an oligomeric crosslinker or blend of crosslinkers which contain at least two isocyanate groups.

    Abstract translation: 一种可固化涂料组合物,其在有机溶剂中包含(i)非异氰酸酯低聚物或含有至少两个官能团的低聚物共混物的粘合剂,至少一个为环氧基,其余为环氧基或羟基; (ii)任选具有至少两个羟基的聚酯,低聚酯或丙烯酸聚合物; 和(iii)含有至少两个异氰酸酯基的交联剂或交联剂的混合物。

    Polyurethane coatings, based on polyisocyanates containing uretdione and/or oxadiazinetrione groups
    10.
    发明授权
    Polyurethane coatings, based on polyisocyanates containing uretdione and/or oxadiazinetrione groups 失效
    聚氨酯涂料,基于含有脲二酮和/或恶二嗪四酮基团的多异氰酸酯

    公开(公告)号:US06806340B2

    公开(公告)日:2004-10-19

    申请号:US10204978

    申请日:2002-08-27

    Abstract: Polyurethane coatings which are the reaction product of A) an aliphatic, isocyanate-containing prepolymer having an isocyanate content of 1-8 wt. % and a free monomeric diisocyanate content of less than 2 wt. %, and containing 0.1 to 1.5 moles of per 1000 g of prepolymer of aliphatically bound uretdione and oxadiazinetrione groups, and B) a polyol component B) comprising at least 50 equivalent % of a compound corresponding to the formula HO—X—Y—X—OH where Y represents methylene, ethylene, —C≡C—, cyclohexylene-1,4, -1,3, -1,2, or phenylene-1,4, -1,3, -1,2 and X represents methylene, —OCH2CH2— (the oxygen being bound to the Y), or cyclohexylene-1,4, -1,3, -1,2, and where the equivalent ratio of the free NCO groups to isocyanate-reactive groups is 0.90 to 1.5. The coatings are applied to flexible substrates such as textile or leather by the casting or knife coating process by means of reactive compositions.

    Abstract translation: 聚氨酯涂料,其是A)具有异氰酸酯含量为1-8重量%的脂族异氰酸酯的预聚物的反应产物。 %和游离的单体二异氰酸酯含量小于2wt。 并且含有0.1-1.5摩尔的每1000克脂族酯结合的脲二酮和恶二嗪二酮基团的预聚物,和B)包含至少50当量%的对应于所述甲基的化合物的多元醇组分B)代表亚甲基,亚乙基,-C = C-,亚环己基-1,4,-1,3,...,1,2-或亚苯基-1,4,-1,3,-1,2-,X表示亚甲基,-OCH 2 CH 2 - (氧与 Y)或亚环己基-1,4,1,3 -1,2,其中游离NCO基团与异氰酸酯反应性基团的当量比为0.90至1.5。 通过使用反应性组合物的铸造或刮刀涂布将涂层施加到柔性基材如纺织品或皮革上。

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