Process for imparting improved whiteness to polyolefin resins
    2.
    发明授权
    Process for imparting improved whiteness to polyolefin resins 失效
    赋予聚烯烃树脂改善白度的方法

    公开(公告)号:US06528565B1

    公开(公告)日:2003-03-04

    申请号:US09705491

    申请日:2000-11-03

    Inventor: Mark K. Russell

    CPC classification number: C08K5/17 C08L23/02

    Abstract: Hydroxyalkylamines can, in addition to imparting antistatic properties, significantly improve the color, i.e., the whiteness, of polyolefin resins produced with chromium-based catalysts and metallocene catalysts. Additionally, such compounds can impart improved whiteness at a loading significantly lower than that required to impart antistatic properties. Surprisingly, the discovered improvement in whiteness is not, however, observed in resins produced using other types of catalysts.

    Abstract translation: 除了赋予抗静电性之外,羟烷基胺可以显着改善用铬基催化剂和茂金属催化剂生产的聚烯烃树脂的颜色,即白度。 此外,这样的化合物可以在负载下赋予改善的白度,显着低于赋予抗静电性能所需的白度。 令人惊奇的是,在使用其他类型催化剂制备的树脂中,观察到白度的改善并不是观察到的。

    Process for stabilizing oxymethylene copolymer
    3.
    发明授权
    Process for stabilizing oxymethylene copolymer 有权
    稳定甲醛共聚物的方法

    公开(公告)号:US06365655B1

    公开(公告)日:2002-04-02

    申请号:US09367288

    申请日:1999-08-16

    CPC classification number: C08G2/28 C08K5/19 C08L59/04

    Abstract: Disclosed is a method for stabilizing a crude oxy-methylene copolymer having thermally unstable terminal groups, which comprises subjecting a crude oxymethylene copolymer to heat treatment in the presence of at least one quaternary ammonium compound represented by the following formula (1): [R1R2R3R4N+]nX−n  (1) wherein each of R1, R2, R3 and R4 independently represents an unsubstituted or substituted alkyl group, an aryl group, an aralkyl group which is an unsubstituted or substituted alkyl group substituted with at least one aryl group, or an alkylaryl group which is an aryl group substituted with at least one unsubstituted or substituted alkyl group; n is an integer of from 1 to 3; and X is a hydroxyl group or an acid residue. In this method, even by the addition of a very small amount of the quaternary ammonium compound, the decomposition rate of the unstable terminal groups can be remarkably increased, thereby facilitating the stabilization of the crude copolymer. Therefore, by this method, it has become possible to easily produce an excellent oxymethylene copolymer within a short period of time, which has substantially no unstable terminal groups and, therefore, has excellent thermal stability and color tone.

    Abstract translation: 本发明公开了一种稳定具有热不稳定端基的粗氧亚甲基共聚物的方法,其包括在至少一种由下式(1)表示的季铵化合物存在下使粗甲醛共聚物进行热处理:其中, R1,R2,R3和R4独立地表示未取代或取代的烷基,芳基,被至少一个芳基取代的未取代或取代的烷基的芳烷基或作为被至少一个芳基取代的芳基的烷基芳基 至少一个未取代或取代的烷基; n为1〜3的整数, X为羟基或酸残基。 在该方法中,即使加入极少量的季铵化合物,也能够显着提高不稳定末端基的分解速度,从而有助于粗共聚物的稳定化。 因此,通过该方法,可以在短时间内容易地制造优异的甲醛共聚物,其基本上不具有不稳定的端基,因此具有优异的热稳定性和色调。

    Rubber composition for tire and tire using the same
    4.
    发明授权
    Rubber composition for tire and tire using the same 失效
    用于轮胎和使用其的轮胎的橡胶组合物

    公开(公告)号:US06699921B2

    公开(公告)日:2004-03-02

    申请号:US09988754

    申请日:2001-11-20

    Applicant: Keiji Ikeda

    Inventor: Keiji Ikeda

    Abstract: There is provided a rubber composition whose run-flat durability is improved and in which precipitation of sulfur and a vulcanization accelerator on the rubber surface before vulcanization is prevented. Sulfur in an amount of 2 to 8 parts by weight and two or more vulcanization accelerators in a total amount of at least 5 parts by weight based on 100 parts by weight of a rubber component are used, at least one of the accelerators being a sulfen amide accelerator.

    Abstract translation: 提供一种橡胶组合物,其耐久性得到改善,并且在硫化之前防止硫和硫化促进剂在橡胶表面上析出。 使用2〜8重量份的硫和相对于100重量份的橡胶成分为5重量份以上的2种以上的硫化促进剂,至少一种促进剂为亚硫酸盐 酰胺加速剂。

    Diaryl-p-phenylenediamine disulfides
    5.
    发明授权
    Diaryl-p-phenylenediamine disulfides 失效
    二芳基对苯二胺二硫化物

    公开(公告)号:US06627686B1

    公开(公告)日:2003-09-30

    申请号:US09655684

    申请日:2000-09-06

    CPC classification number: C07C323/37 C08K5/3725 C08L21/00

    Abstract: The present invention relates to mixed diaryl-p-phenylenediamine disulfides and its use in compounds. The mixed diaryl-p-phenylenediamine are of the formula and mixtures thereof wherein R1 and R2 are each independently selected from the group consisting of hydrogen and alkyls having from 1 to 8 carbon atoms.

    Abstract translation: 本发明涉及混合二芳基对苯二胺二硫化物及其在化合物中的用途。 混合的二芳基对苯二胺具有下式及其混合物,其中R 1和R 2各自独立地选自氢和具有1至8个碳原子的烷基。

    Rubber vulcanizates having improved ageing properties

    公开(公告)号:US06444759B1

    公开(公告)日:2002-09-03

    申请号:US09808817

    申请日:2001-03-14

    Abstract: The invention relates to a vulcanizable rubber composition comprising a rubber, sulfur or a sulfur donor, a vulcanization accelerator, a protective agent and 0.1 phr or more of an N,N′-disubstituted p-phenylenediamine protective agent is present in the form of a salt with an acid, and the composition does not comprise an elastomeric copolymer having glycidyl groups. The invention also relates to a vulcanization process comprising mixing and heating said rubber composition and to an article of manufacture comprising the rubber vulcanizate obtained by said process. Preferably, the acid is a C1-C24 monocarboxylic acid or a C2-C24 dicarboxylic acid, more preferably a C12-C20 fatty acid such as stearic acid. Most preferably, the protective agent is 6PPD.

    Color stable compositions containing arylate-comprising polymers

    公开(公告)号:US06410620B1

    公开(公告)日:2002-06-25

    申请号:US09815328

    申请日:2001-03-22

    Abstract: The color stability of thermoplastic polymers comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one organodicarboxylic acid is enhanced by combination with at least one photobleachable 4-aminocinnamic compound such as 4-dimethylaminocinnamaldehyde. The latter absorbs radiation in the range between about 360 nanometers and about 390 nanometers, balancing the radiation absorbed by hydroxybenzophenone moieties formed in the polymer.

    Color stable compositions containing arylate-comprising polymers

    公开(公告)号:US06414058B1

    公开(公告)日:2002-07-02

    申请号:US09815327

    申请日:2001-03-22

    Abstract: The color stability of thermoplastic polymers comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one organodicarboxylic acid is enhanced by combination with at least one photobleachable 4-aminocinnamic compound such as 4-dimethylaminocinnamaldehyde. The latter absorbs radiation in the range between about 360 nanometers and about 390 nanometers, balancing the radiation absorbed by hydroxybenzophenone moieties formed in the polymer.

    Copolymer latex for adhesive for rubber/metal adhesion and process for producing same
    10.
    发明授权
    Copolymer latex for adhesive for rubber/metal adhesion and process for producing same 有权
    用于橡胶/金属粘合剂的粘合剂用共聚物胶乳及其制造方法

    公开(公告)号:US06335391B1

    公开(公告)日:2002-01-01

    申请号:US09522005

    申请日:2000-03-09

    CPC classification number: C09J119/02 C08F236/18

    Abstract: A latex adhesive for rubber/metal adhesion, which contains a copolymer consisting of, based on the weight of the copolymer, (A) 90.0 to 97.0% by weight of 2,3-dichloro-1,3-butadiene units, (B) 1.5 to 5.0% by weight of 1,2-dichloro-1,3-butadiene units, and (C) 1.5 to 5.0% by weight of 1,3-dichloro-1,3-butadiene units. The latex adhesive is prepared by polymerizing a monomer mixture consisting of the stated amounts of the monomers (A), (B) and (C) in the presence of a free-radical initiator, preferably a redox catalyst system, by an emulsion polymerization procedure. The latex adhesive has good mechanical stability and exhibits enhanced adhesion for rubber/metal adhesion.

    Abstract translation: 一种用于橡胶/金属粘合的胶乳粘合剂,其包含基于共聚物重量的共聚物,(A)90.0至97.0重量%的2,3-二氯-1,3-丁二烯单元,(B) 1.5〜5.0重量%的1,2-二氯-1,3-丁二烯单元,(C)1.5〜5.0重量%的1,3-二氯-1,3-丁二烯单元。 胶乳粘合剂通过在自由基引发剂,优选氧化还原催化剂体系的存在下,通过乳液聚合方法聚合由所述量的单体(A),(B)和(C)组成的单体混合物来制备 。 胶乳粘合剂具有良好的机械稳定性,并且对橡胶/金属附着力具有增强的附着力。

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