摘要:
Thermoplastic resin compositions prepared by blending graftpolymers formed of rubbery copolymers obtained by copolymerizing a vinyl monomer with at least one compound selected from the group consisting of acrylic and methacrylic esters of tetrahydrofulfuryl alcohol, ethylene glycol monomethyl ether and 3-methoxybutanol, and at least one compound selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, and mixtures of either of said types of compounds and monomers copolymerizable therewith, with polymers separately prepared from at least one compound consisting of either or combination of said aromatic vinyl compounds and vinyl cyanides.
摘要:
POLYMERS HAVING IMPROVED EXTRUSION AND COLD-STRETCHING PROPERTIES ARE PRODUCED BY MELT-BLENDING THE POLYMER PRIOR TO EXTRUSION WITH MALEIC ANHYDRIDE AND A COMPOUND HAVING THE STRUCTURE
R3-(CH(-R1)-CH2)N-R2
WHERE R1=AROMATIC RADICAL OR SUBSTITUTED AROMATIC RADICAL HAVING A TERTIARY HYDROGEN IN THE A POSITION OF THE BENZENE RING, R2=H1 OR ALKYL RADICAL, R3=H1, AROMATIC OR ALKYL RADICAL, N=1-10,000.
摘要:
A POLYBLEND CONTAINS A MATRIX INTERPOLYMER OF MONOVINYLIDENE AROMATIC HYDROCARBON AND AN ETHYLENEICALLY UNSATURATED NITRILE, AND A GRAFT COPOLYMER HAVING A SUPERSTRATE OF AN INTERPOLYMER OF MONOVINYLIDENE AROMATIC HYDROCARBON AND AN ETHYLENICALLY UNSATURATED NITRILE. IN THE GRAFT COPOLYMER, THE SUBSTRATE COMPRISES AN AGGLOMERATED RUBBERY POLYMER HAVING A MONODISPERSE PARTICLE SIZE, AND BOTH THE MOLECULAR WEIGHT OF THE SUPERSTRATE AND ALSO THE RATIO OF SUPERSTRATE TO SUBSTRATE ARE CAREFULLY CONTROLLED TO PROVIDE AN OPTIMUM BALANCE OF PROPERTIES IN THE POLYBLEND.
摘要:
NORMALLY TACKY PRESSURE-SENSITIVE ADHESIVES AND ADHESIVE TAPES HAVING EXCELLENT SHEAR STRENGTH AND CREEP RESISTANCE, PARTICULARLY AT ELEVATED TEMPERATURES, TOGETHER WITH GOOD PEEL STRENGTH AND TACK PROPERTIES, ARE OBTAINED BY COMBINING TACKIFYING RESIN WITH LOW MOLECULAR WEIGHT A-B BLOCK COPOLYMER. THE COPOLYMER A BLOCK IS NORMOLLY GLASSY AND HAS A GLASS TRANSITION TEMPERATURE ABOVE 75*C. WHILE THE COPOLYMER B BLOCK IS AMORPHOUS AND ELASTOMERIC AT TEMPERATURES ABOVE -20*C. SHEAR STRENGTH OF THE ADHESIVE MAY BE INCREASED BY ADDITION OF BLOCK COPOLYMERS CONTAINING THREE OR MORE BLOCKS.
摘要:
A MOLDING NITRILE RESIN COMPOSITION SUITABLE AS A MATERIAL FOR FOOD-PACKAGING FILMS OR FOOD CONTAINERS WHICH ARE EXCELLENT IN PROCESSABILITY, TRANSPARENCY, IMPACT RESISTANCE, HARDNESS, APPERANCE AND GAS-IMPERMEABILITY, AND WHICH REQUIRED SUBSTANTIALLY NO HEAT STABILIZER, IS OBTAINED BY EMULSION-POLYMERZING IN AN AQUEOUS MEDIUM 95 TO 40 PARTS BY WEIGHT OF A MONOMERIC MIXTURE (A) OF 55 TO 90% BY WEIGHT OF ACRYLONITRILE OR METHACRYLONITRILE AND 10 TO 45% BY WEIGHT OF A LOWER ALKYL ACRYLATE OR A LOWER ALKYL METHACRYLATE, IN THE PRESENCE OF 5 TO 60 PARTS BY WEIGHT OF A RUBBER-LIKE POLYMER (B) COMPOSED OF 30 TO 80% BY WEIGHT OF AN ALKYL ACRYLATE OR AN ALKYL METACRYLATE, 4 TO 50% BY WEIGHT OF A CONJUGATED DIOLEFIN AND 5 TO 30% BY WEIGHT OF A VINYL AROMATIC HYDROCARBON. THE SAID COMPOSITION CAN BE BLENDED, IF NECESSARY, WITH A COPOLYMER OBTAINED BY POLYMERZING IN AN AQUEOUS MEDIUM OF THE SAID MONOMERIC MIXTURE (A) IN THE ABSENCE OF THE SAID RUBBER-LIKE POLYMER (B), IN A PROPORTION OF UP TO 100 PART BY WEIGHT OF THE COPOLYMER PER 100 PARTS BY WEIGHT OF THE SAID COMPOSITION, TO ADJUST THE CONTENT OF SAID RUBBER-LIKE POLYMER (B) TO ANY VALUE WITHIN THE RANGE OF 5 TO 30% BY WEIGHT BASED ON THE WEIGHT OF THE RESULTING COMPOSITION.
摘要:
BLENDS OF CHLORINATED POLYETHYLENE WITH ALKYL ACRYLATEVINYL ALKYLETHER-ACRYLONITRILE COPOLYMERS GRAFTED WITH STYRENE-ACRYLNITRILE ARE CHARACTERIZED BY IMPROVED IMPACT STRENGTH.
摘要:
Apparatus and method for separating a substantially insoluble liquid from a mixture containing a polymer or polymer mixture. The liquid is a vapor at the usual temperature and pressure of the polymer extrusion operation and is kept in liquid form by providing a high pressure region in the extruder. A liquid outlet is provided upstream of the high pressure region and the liquid is maintained under pressure and taken off as a liquid. The pressure-maintaining means may be a liquid outlet provided with a pressure control valve, trap or the like.
摘要:
Thermoplastic blend of ABS, polyarylene poly-sulfone resin (e.g. condensation product of the dipotassium salt of 2,2-bis-(4hydroxyphenyl) propane and 4,4''-dichlorodiphenyl-sulfone), and bromo-aryl compound (hexabromobenzene or hexabromodiphenylether), with or without antimony oxide, is self-extinguishing, has high heat distortion temperature, and good processing characteristics.
摘要:
Production of synthetic vinyl resins having pronounced resistance to color deterioration, while also manifesting high impact strength and transparency, utilizing a butadiene graft polymer formed by the sequential addition to a polymer or copolymer of butadiene of from 80 to 30 parts of monomers for each 100 parts of total resin content, said monomers consisting of from 5 to 80 percent vinyl aromatic compound, from 5 to 50 percent of methyl methacrylate, and from 5 to 60 percent of acrylonitrile, the process being characterized in that at least 80 percent of the butadiene particles at the start are less than 0.1 Mu in diameter and are dispersed in an aqueous emulsion which contains from 0.5 to 10.0 parts of a formaldehyde sulfoxylic salt, and catalytically effective amounts up to three parts of peroxide, for each 100 parts of resinous constituents used, said particle size being maintained at least until polymerization of the monomeric material has been effectively begun, said butadiene graft polymer being independently useful but also being capable of blending with a resin of the vinyl chloride type to produce a final resin of greatly enhanced properties.
摘要:
A LATEX OF A RUBBERY POLYMER HAVING A PARTICLE SIZE OF LESS THAN 0.25 MICRON AND A POLYMERIZABLE VINYLIDENE MONOMER FORMULATION IS SUBJECTED TO POLYMERIZATION CONDITIONS TO PRODUCE POLYMERIZATION AND GRAFTING OF AT LEAST A PORTION OF THE MONOMER FORMULATION ONTO THE RUBBERY POLYMER. SUBSEQUENTLY, A LATEX OF AGGLOMERATED RUBBERY POLYMER HAVING A PARTICLE SIZE OF 0.35-1.2 MICRONS IS ADDED TO THE POLYMERIZING LATEX AND POLYMERIZATION OF THE VINYLIDENE MONOMER FORMULATION IS CONTINUED TO PRODUCE GRAFTING OF AT LEAST A PORTION THEREOF ONTO THE AGGLOMERATED RUBBERY POLYMER.