Thermoplastic resin-graft-polyblend compositions
    1.
    发明授权
    Thermoplastic resin-graft-polyblend compositions 失效
    热塑性树脂接枝聚合物组合物

    公开(公告)号:US3870769A

    公开(公告)日:1975-03-11

    申请号:US45029974

    申请日:1974-03-12

    摘要: Thermoplastic resin compositions prepared by blending graftpolymers formed of rubbery copolymers obtained by copolymerizing a vinyl monomer with at least one compound selected from the group consisting of acrylic and methacrylic esters of tetrahydrofulfuryl alcohol, ethylene glycol monomethyl ether and 3-methoxybutanol, and at least one compound selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, and mixtures of either of said types of compounds and monomers copolymerizable therewith, with polymers separately prepared from at least one compound consisting of either or combination of said aromatic vinyl compounds and vinyl cyanides.

    摘要翻译: 将通过将乙烯基单体与至少一种选自四氢富糠醇的丙烯酸酯和甲基丙烯酸酯,乙二醇单甲基醚和3-甲氧基丁醇的化合物和至少一种化合物的化合物共聚获得的橡胶状共聚物形成的接枝聚合物制备的热塑性树脂组合物, 选自芳族乙烯基化合物,乙烯基氰化物,以及所述类型的化合物和可与其共聚的单体的混合物,以及由至少一种由所述芳族乙烯基化合物和乙烯基氰化物的组合组成的化合物单独制备的聚合物。

    Molding nitrile resin compositions
    5.
    发明授权
    Molding nitrile resin compositions 失效
    成型NITRILE树脂组合物

    公开(公告)号:US3775518A

    公开(公告)日:1973-11-27

    申请号:US3775518D

    申请日:1972-04-18

    发明人: ENDO R

    摘要: A MOLDING NITRILE RESIN COMPOSITION SUITABLE AS A MATERIAL FOR FOOD-PACKAGING FILMS OR FOOD CONTAINERS WHICH ARE EXCELLENT IN PROCESSABILITY, TRANSPARENCY, IMPACT RESISTANCE, HARDNESS, APPERANCE AND GAS-IMPERMEABILITY, AND WHICH REQUIRED SUBSTANTIALLY NO HEAT STABILIZER, IS OBTAINED BY EMULSION-POLYMERZING IN AN AQUEOUS MEDIUM 95 TO 40 PARTS BY WEIGHT OF A MONOMERIC MIXTURE (A) OF 55 TO 90% BY WEIGHT OF ACRYLONITRILE OR METHACRYLONITRILE AND 10 TO 45% BY WEIGHT OF A LOWER ALKYL ACRYLATE OR A LOWER ALKYL METHACRYLATE, IN THE PRESENCE OF 5 TO 60 PARTS BY WEIGHT OF A RUBBER-LIKE POLYMER (B) COMPOSED OF 30 TO 80% BY WEIGHT OF AN ALKYL ACRYLATE OR AN ALKYL METACRYLATE, 4 TO 50% BY WEIGHT OF A CONJUGATED DIOLEFIN AND 5 TO 30% BY WEIGHT OF A VINYL AROMATIC HYDROCARBON. THE SAID COMPOSITION CAN BE BLENDED, IF NECESSARY, WITH A COPOLYMER OBTAINED BY POLYMERZING IN AN AQUEOUS MEDIUM OF THE SAID MONOMERIC MIXTURE (A) IN THE ABSENCE OF THE SAID RUBBER-LIKE POLYMER (B), IN A PROPORTION OF UP TO 100 PART BY WEIGHT OF THE COPOLYMER PER 100 PARTS BY WEIGHT OF THE SAID COMPOSITION, TO ADJUST THE CONTENT OF SAID RUBBER-LIKE POLYMER (B) TO ANY VALUE WITHIN THE RANGE OF 5 TO 30% BY WEIGHT BASED ON THE WEIGHT OF THE RESULTING COMPOSITION.

    Method of separating an insoluble liquid from polymer composition
    7.
    发明授权
    Method of separating an insoluble liquid from polymer composition 失效
    从聚合物组合物分离不溶性液体的方法

    公开(公告)号:US3742093A

    公开(公告)日:1973-06-26

    申请号:US3742093D

    申请日:1970-04-08

    申请人: WELDING ENGINEERS

    发明人: SKIDMORE R

    摘要: Apparatus and method for separating a substantially insoluble liquid from a mixture containing a polymer or polymer mixture. The liquid is a vapor at the usual temperature and pressure of the polymer extrusion operation and is kept in liquid form by providing a high pressure region in the extruder. A liquid outlet is provided upstream of the high pressure region and the liquid is maintained under pressure and taken off as a liquid. The pressure-maintaining means may be a liquid outlet provided with a pressure control valve, trap or the like.

    摘要翻译: 从含有聚合物或聚合物混合物的混合物中分离基本上不溶的液体的装置和方法。 液体是在聚合物挤出操作的通常温度和压力下的蒸汽,并且通过在挤出机中提供高压区域而保持液态。 液体出口设置在高压区域的上游,液体保持在压力下并以液体的形式取出。 保压装置可以是设有压力控制阀,捕集器等的液体出口。

    Flame resistant composition of abs, polyarylene polysulfone and bromo-aryl compound
    8.
    发明授权
    Flame resistant composition of abs, polyarylene polysulfone and bromo-aryl compound 失效
    ABS,聚亚烷基多糖和BROMO-ARYL化合物的耐火组合物

    公开(公告)号:US3686362A

    公开(公告)日:1972-08-22

    申请号:US3686362D

    申请日:1970-05-22

    申请人: UNLROYAL INC

    摘要: Thermoplastic blend of ABS, polyarylene poly-sulfone resin (e.g. condensation product of the dipotassium salt of 2,2-bis-(4hydroxyphenyl) propane and 4,4''-dichlorodiphenyl-sulfone), and bromo-aryl compound (hexabromobenzene or hexabromodiphenylether), with or without antimony oxide, is self-extinguishing, has high heat distortion temperature, and good processing characteristics.

    摘要翻译: ABS,聚亚芳基聚砜树脂的热塑性混合物[例如 2,2-双 - (4-羟基苯基)丙烷和4,4'-二氯二苯基砜的二钾盐的缩合产物和含有或不含氧化锑的溴 - 芳基化合物(六溴苯或六溴二苯醚) 灭火,热变形温度高,加工性能好。

    Thermoplastic vinyl resin compositions, and method of manufacture
    9.
    发明授权
    Thermoplastic vinyl resin compositions, and method of manufacture 失效
    热塑性乙烯基树脂组合物及其制造方法

    公开(公告)号:US3670052A

    公开(公告)日:1972-06-13

    申请号:US83730969

    申请日:1969-06-27

    摘要: Production of synthetic vinyl resins having pronounced resistance to color deterioration, while also manifesting high impact strength and transparency, utilizing a butadiene graft polymer formed by the sequential addition to a polymer or copolymer of butadiene of from 80 to 30 parts of monomers for each 100 parts of total resin content, said monomers consisting of from 5 to 80 percent vinyl aromatic compound, from 5 to 50 percent of methyl methacrylate, and from 5 to 60 percent of acrylonitrile, the process being characterized in that at least 80 percent of the butadiene particles at the start are less than 0.1 Mu in diameter and are dispersed in an aqueous emulsion which contains from 0.5 to 10.0 parts of a formaldehyde sulfoxylic salt, and catalytically effective amounts up to three parts of peroxide, for each 100 parts of resinous constituents used, said particle size being maintained at least until polymerization of the monomeric material has been effectively begun, said butadiene graft polymer being independently useful but also being capable of blending with a resin of the vinyl chloride type to produce a final resin of greatly enhanced properties.

    摘要翻译: 制造具有显着耐色劣性的合成乙烯基树脂,同时也表现出高冲击强度和透明度,使用通过顺序添加至丁二烯的聚合物或共聚物而形成的丁二烯接枝聚合物,其中每100份均为80至30份单体 的总树脂含量,所述单体由5至80%乙烯基芳族化合物,5至50%甲基丙烯酸甲酯和5至60%的丙烯腈组成,该方法的特征在于至少80%的丁二烯颗粒 开始时直径小于0.1μm,分散在含有0.5〜10.0份甲醛亚硫酸盐的水性乳液中,对于每100份所使用的树脂组分,催化有效量至多3份过氧化物, 所述的粒径保持至少直到单体材料的聚合已被有效地开始,所述丁二烯 接枝聚合物独立地有用,但也能够与氯乙烯类树脂共混以产生极大增强的性能的最终树脂。

    Process for making novel graft copolymer blends
    10.
    发明授权
    Process for making novel graft copolymer blends 失效
    制备新型共聚物共混物的方法

    公开(公告)号:US3663656A

    公开(公告)日:1972-05-16

    申请号:US3663656D

    申请日:1970-06-22

    申请人: MONSANTO CO

    CPC分类号: C08F291/02 C08F285/00

    摘要: A LATEX OF A RUBBERY POLYMER HAVING A PARTICLE SIZE OF LESS THAN 0.25 MICRON AND A POLYMERIZABLE VINYLIDENE MONOMER FORMULATION IS SUBJECTED TO POLYMERIZATION CONDITIONS TO PRODUCE POLYMERIZATION AND GRAFTING OF AT LEAST A PORTION OF THE MONOMER FORMULATION ONTO THE RUBBERY POLYMER. SUBSEQUENTLY, A LATEX OF AGGLOMERATED RUBBERY POLYMER HAVING A PARTICLE SIZE OF 0.35-1.2 MICRONS IS ADDED TO THE POLYMERIZING LATEX AND POLYMERIZATION OF THE VINYLIDENE MONOMER FORMULATION IS CONTINUED TO PRODUCE GRAFTING OF AT LEAST A PORTION THEREOF ONTO THE AGGLOMERATED RUBBERY POLYMER.