公开(公告)号：US06462043B1

公开(公告)日：2002-10-08

申请号：US09485873

申请日：2000-02-16

申请人： Peter Maienfisch

发明人： Peter Maienfisch

IPC分类号： C07D25108

CPC分类号： C07D213/40 ,  C07D213/61 ,  C07D213/89 ,  C07D251/08 ,  C07D261/08 ,  C07D277/28 ,  C07D277/32 ,  C07D307/14 ,  C07D401/14 ,  C07D405/14 ,  C07D413/14 ,  C07D417/14

摘要： The invention relates to a method for producing an organic compound of formula (I) and optionally its E/Z-isomers, E/Z-isomer mixtures and/or tautomers, each in free or salt form, R1 representing hydrogen or C1-C4 alkyl, R2 representing hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl or a radical —CH2B, Het representing an unsubstituted or substituted heterocyclic radical and B representing phenyl, 3-pyridyl or thiazolyl, these being optionally substituted. The invention is characterized in that a compound of formula (IIa) Q—A—Q, wherein A represents a direct bond or an organic radical, or of formula (IIb), wherein U represents an organic radical, Q representing (1) in the compounds (IIa) and (IIb) and R1, R2 and Het having the meaning given above for formula (I), and optionally their E/Z-isomers, E/Z-isomer mixtures and/or tautomers, each in free or salt form are hydrolyzed. The invention also relates to a method for producing compounds of formulae (IIa), (IIb), (IIIa) and (IIIb), and to a method for combating pests with compounds of formulae (IIa) and (IIb).

摘要翻译： 本发明涉及一种制备式（I）的有机化合物和任选的其E / Z-异构体，E / Z-异构体混合物和/或互变异构体的方法，各自为游离或盐形式，R1表示氢或C1-C4 烷基，R 2表示氢，C 1 -C 6烷基，C 3 -C 6环烷基或基团-CH 2 B，Het表示未取代或取代的杂环基，B表示苯基，3-吡啶基或噻唑基，它们任选被取代。 本发明的特征在于，式（IIa）QAQ的化合物，其中A表示直接键或有机基团，或式（IIb），其中U表示有机基团，Q表示化合物（IIa ）和（IIb），并且具有上述式（I）给出的含义的R1，R2和Het，以及任选的它们的E / Z-异构体，E / Z-异构体混合物和/或互变异构体，各自为游离或盐形式 。 本发明还涉及制备式（Ⅱa），（Ⅱb），（Ⅲa）和（Ⅲb）化合物的方法，以及用式（IIa）和（IIb）化合物防治害虫的方法。

公开(公告)号：US06482241B1

公开(公告)日：2002-11-19

申请号：US09657737

申请日：2000-09-08

申请人： Georges Metzger ,  Dieter Reinehr ,  Claude Eckhardt ,  Fabienne Cuesta

发明人： Georges Metzger ,  Dieter Reinehr ,  Claude Eckhardt ,  Fabienne Cuesta

IPC分类号： C07D25108

CPC分类号： C07D251/68 ,  C11D3/42 ,  D06M13/07 ,  D06M13/358 ,  D06M2101/04 ,  D06M2101/06 ,  D06M2101/10 ,  D06M2101/12 ,  D06M2101/16 ,  D06M2101/28 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/25

摘要： The present invention provides, as a first aspect, an asymmetric compound having the formula: in which M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; Xa and Xb are the same or different and each is NH2; NH(C1-C4alkyl); NH(C2-C4alkoxyalkyl); N(C1-C4alkyl)2; N(CH2CH2OH)2; a group NH—Z—NR1R2 in which Z is C2-C14alkylene or optionally substituted arylene, and R1 and R2 are the same or different and each is C1-C12alkyl or R1 and R2, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; an aminoacid residue; C1-C4alkoxy; hydroxy-substituted-C2-C4alkoxy; and Ya and Yb are the same or different and each is a substituted amino group having both UVA and UVB-absorbing properties having the formula: in which R3 is CN; SO2R5 in which R5 is, C1-C12alkyl, C1-C12alkoxy, NH2, NH(C1-C4alkyl), N(C1-C4alkyl)2, N(CH2CH2OH)2, C1-C4alkoxy or hydroxy-substituted-C2-C4alkoxy; COR5 in which R5 has its previous significance; COOM in which M has its previous significance or NHCOR5 in which R5 has its previous significance and in which R4 has the same significance as R3 or is H, OH, C1-C4alkyl or C1-C4alkoxy and one of Xa and Xb can be identical to one of Ya and Yb, provided that one of Xa and Xb is different from the other and/or one of Ya and Yb is different from the other. The present invention also relates to a method of improving the sun protection factor (SPF) of textile fibre material, especially cotton, polyamide and wool, comprising treating them with the new compounds.

摘要翻译： 作为第一方面，本发明提供具有下式的不对称化合物：其中M是氢，碱金属原子，铵或由胺形成的阳离子; Xa和Xb相同或不同，各自为NH 2; NH（C 1 -C 4烷基）; NH（C 2 -C 4烷氧基烷基）; N（C 1 -C 4烷基）2; N（CH 2 CH 2 OH）2; 其中Z为C 2 -C 14亚烷基或任选取代的亚芳基的基团NH-Z-NR 1 R 2，并且R 1和R 2相同或不同，并且各自为C 1 -C 12烷基或R 1和R 2以及它们各自连接的氮原子 形成吗啉代，哌啶子基或哌嗪基环; 氨基酸残基; C1-C4烷氧基; 羟基取代的C 2 -C 4烷氧基; Ya和Yb相同或不同，并且各自为具有下式的UVA和UVB吸收性质的取代氨基：其中R3为CN; 其中R 5为C 1 -C 12烷基，C 1 -C 12烷氧基，NH 2，NH（C 1 -C 4烷基），N（C 1 -C 4烷基）2，N（CH 2 CH 2 OH）2，C 1 -C 4烷氧基或羟基取代的C 2 -C 4烷氧基的SO 2 R 5; COR5其中R5具有以前的意义; 其中M具有其先前意义的COOM或其中R5具有其先前意义的NHCOR5，并且其中R 4与R 3具有相同的含义或为H，OH，C 1 -C 4烷基或C 1 -C 4烷氧基，X a和X b中的一个可以相同 Ya和Yb中的一个，其中Xa和Xb中的一个与另一个不同，和/或Ya和Yb中的一个与另一个不同。本发明还涉及一种改善防晒因子（SPF）的方法 纺织纤维材料，特别是棉花，聚酰胺和羊毛，包括用新化合物处理它们。