Ketonitriles and method for their production
    2.
    发明授权
    Ketonitriles and method for their production 失效
    KETONITRILES及其生产方法

    公开(公告)号:US3723468A

    公开(公告)日:1973-03-27

    申请号:US3723468D

    申请日:1970-01-28

    CPC classification number: C07D319/06 C10L1/221 C10L1/2493 C10L1/2691 C10L1/30

    Abstract: Ketonitriles of the general formula

    IN WHICH R1 and R2 signify alkyl groups with one to four carbonatoms, R3 and R4 are hydrogen atoms or alkyl groups with one to four C-atoms and wherein R3 and R4 may also together form a carbocyclic ring preferably with five or six C-atoms and n is zero, 1 or 2 produced by condensing diols of the formula

    WITH CYANALDEHYDES OF THE FORMULA WHEREIN R1, R2, R3, R4 and n have the same meanings as set forth above, in the presence of strong acid catalysts where the diols may be in the thickly liquid, impure form. These ketonitriles are useful as herbicides.

    Abstract translation: 通式为R 1和R 2的酮类表示具有1-4个碳原子的烷基,R 3和R 4是氢原子或具有1-4个C原子的烷基,并且其中R 3和R 4也可以一起形成碳环 具有五个或六个C原子,并且n是0,1或2,其通过将下式的二醇与本发明的化合物R1,R2,R3,R4和n的式(Ⅱ)的化合物与上述具有相同含义,在存在 强酸催化剂,其中二醇可以是稠的液体,不纯的形式。 这些酮腈可用作除草剂。

    Prins-type reactions
    3.
    发明授权
    Prins-type reactions 失效
    PRINS型反应

    公开(公告)号:US3644428A

    公开(公告)日:1972-02-22

    申请号:US3644428D

    申请日:1969-07-22

    Applicant: ICI LTD

    CPC classification number: C07D319/06

    Abstract: A PROCESS FOR REACTING A CONJUGATED DIOLEFIN, E.G. 1,3BUTADIENE, WITH FORMALDEHYDE TO GIVE A PRODUCT COMPRISING A MAJOR PROPORTION OF A DIHYDROPYRAN, E.G. 5,6-DIHYDRO2H-PYRAN IN WHICH THE REACTION TAKES PLACE IN THE PRESENCE OF A LEWIS ACID CATALYST AND A SUBSTANTIALLY NON-AQUEOUS SOLVENT.

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