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    Ammonia borane purification method
    1.
    发明授权
    Ammonia borane purification method 有权
    氨硼烷净化方法

    公开(公告)号：US09005562B2

    公开(公告)日：2015-04-14

    申请号：US13729316

    申请日：2012-12-28

    申请人： BoroScience International, Inc. ,  WeylChem Sustainable Materials, LLC

    发明人： Bernard Franklin Spielvogel ,  Kevin Joel Drost

    IPC分类号： C01B35/14 ,  C01B35/18 ,  C01B21/087

    CPC分类号： C01B35/146 ,  C01B21/087

    摘要： A method of purifying ammonia borane is provided whereby crude ammonia borane is dissolved in a basic aqueous solution, the solution is heated to decompose and precipitate impurities found in the crude ammonia borane, and the impurities are separated by filtration. The aqueous solution containing dissolved ammonia borane is then cooled to a temperature of from 10° C. to −10° C., to precipitate the ammonia borane, which is recovered and dried to yield a high-purity product.

    摘要翻译： 提供了一种纯化氨硼烷的方法，其中将粗氨硼烷溶解在碱性水溶液中，将溶液加热分解并沉淀在粗氨甲烷中发现的杂质，并通过过滤分离杂质。 然后将含有溶解氨硼烷的水溶液冷却至10℃至-10℃的温度，以沉淀氨硼烷，将其回收并干燥，得到高纯度产物。

    NONLINEAR OPTICAL CRYSTALS AND THEIR MANUFACTURE AND USE
    3.
    发明申请
    NONLINEAR OPTICAL CRYSTALS AND THEIR MANUFACTURE AND USE 有权
    非线性光学晶体及其制造和使用

    公开(公告)号：US20120063475A1

    公开(公告)日：2012-03-15

    申请号：US13301538

    申请日：2011-11-21

    申请人： Douglas A. Keszler ,  Ning Ye

    发明人： Douglas A. Keszler ,  Ning Ye

    IPC分类号： H01S3/10 ,  C09K11/68 ,  C01B35/18

    CPC分类号： C30B9/00 ,  C09K11/7712 ,  C30B9/12 ,  C30B17/00 ,  C30B29/10 ,  C30B29/22 ,  G02F1/3551

    摘要： Described are nonlinear optical (NLO) crystals, including aluminum-borate NLO crystals, that have low concentrations of contaminants that adversely affect the NLO crystal's optical properties, such as compounds that contain transition-metal elements and/or lanthanides, other than yttrium, lanthanum, and lutetium. Some NLO crystals with low concentrations of these contaminants are capable of second harmonic generation at very short wavelengths. Also described are embodiments of a method for making these NLO crystals. Some embodiments involve growing a single NLO crystal, such as an aluminum-borate NLO crystal, from a mixture containing a solvent that is substantially free of harmful contaminants. The described NLO crystals can be used, for example, in laser devices.

    摘要翻译： 描述了非线性光学（NLO）晶体，包括铝 - 硼酸盐NLO晶体，其具有低浓度的污染物，其不利地影响NLO晶体的光学性质，例如包含过渡金属元素和/或镧系元素的化合物，除了钇，镧 和镥。 一些具有低浓度这些污染物的NLO晶体能够在非常短的波长下产生二次谐波。 还描述了制造这些NLO晶体的方法的实施方案。 一些实施方案涉及从含有基本上不含有害污染物的溶剂的混合物中生长单个NLO晶体，例如铝 - 硼酸盐NLO晶体。 所描述的NLO晶体可以用于例如激光器件中。

    Preparation of decaborane (14) through hydride ion abstraction reactions
    4.
    发明授权
    Preparation of decaborane (14) through hydride ion abstraction reactions 失效
    通过氢化物离子抽提反应制备十硼烷（14）

    公开(公告)号：US4338289A

    公开(公告)日：1982-07-06

    申请号：US291713

    申请日：1981-08-10

    申请人： Sheldon G. Shore ,  Mark A. Toft ,  Francis L. Himpsl

    发明人： Sheldon G. Shore ,  Mark A. Toft ,  Francis L. Himpsl

    IPC分类号： C01B35/02 ,  C01B35/18 ,  C07F5/02

    CPC分类号： C07F5/027 ,  C01B35/026

    摘要： Disclosed is a method for the preparation of decaborane-14(B.sub.10 H.sub) in high yields from B.sub.5 H.sub.9 which involve three basic procedure steps as follows:(1) conversion of B.sub.5 H.sub.9 to a solid, [N(CH.sub.3).sub.4 ][B.sub.9 H.sub.14 ], by reacting NaH in a tetrahydrofuran (THF) solution in the presence of [N(CH.sub.3).sub.4 ][Cl];(2) performing a hydride abstraction on the solid after removal of THF by reacting, while stirring, a boron trihalide selected from BBr.sub.3 and BCl.sub.3 to form B.sub.10 H.sub.14 ; and,(3) separating the B.sub.10 H.sub.14 from the solid reaction mixture by a sublimation procedure.

    摘要翻译： 公开了一种以B5H9高产率制备十硼烷-14（B10H14）的方法，其涉及三个基本步骤如下：（1）将B5H9转化为固体，[N（CH 3）4] [B 9 H 14] 在[N（CH 3）4] [Cl]存在下，使NaH在四氢呋喃（THF）溶液中反应; （2）通过在搅拌下使选自BBr 3和BCl 3的三卤化硼反应形成B10H14，在除去THF后对固体进行氢化物抽提; 和（3）通过升华程序从固体反应混合物中分离出B10H14。

    Process for the synthesis of tetradecahydroundecaborate compounds
    5.
    发明授权
    Process for the synthesis of tetradecahydroundecaborate compounds 失效
    合成十四氢十硼酸盐化合物的方法

    公开(公告)号：US4115520A

    公开(公告)日：1978-09-19

    申请号：US837981

    申请日：1977-09-29

    申请人： Gary Burr Dunks ,  Kathy Palmer Ordonez

    发明人： Gary Burr Dunks ,  Kathy Palmer Ordonez

    IPC分类号： C01B35/00 ,  C01B35/02 ,  C01B35/18

    CPC分类号： C01B35/00 ,  C01B35/026

    摘要： Tetradecahydroundecaborate compounds, MB.sub.11 H.sub.14, wherein M represents a monovalent cation are prepared by the reaction of the corresponding octahydroborate compounds, MB.sub.3 H.sub.8, with boron trifluoride. The reaction is carried out at a temperature of 100.degree. C. to 120.degree. C., preferably in an inert solvent medium.

    摘要翻译： 通过相应的八氢硼酸盐化合物MB3H8与三氟化硼的反应制备十四碳十二硼酸盐化合物，MB11H14，其中M表示一价阳离子。 该反应在100℃至120℃的温度下进行，优选在惰性溶剂介质中进行。

    ISOTOPICALLY-ENRICHED BORANES AND METHODS OF PREPARING THEM
    9.
    发明申请
    ISOTOPICALLY-ENRICHED BORANES AND METHODS OF PREPARING THEM 有权
    同位素丰富的波兰及其制备方法

    公开(公告)号：US20110217223A1

    公开(公告)日：2011-09-08

    申请号：US13109778

    申请日：2011-05-17

    申请人： Bernard Spielvogel ,  Kevin Cook

    发明人： Bernard Spielvogel ,  Kevin Cook

    IPC分类号： C01B35/18

    CPC分类号： H01L21/2658 ,  C01B6/10 ,  Y02P20/582

    摘要： The invention provides new methods for synthesis of large boron hydride clusters, e.g., boron hydride molecules of the formula BnHm where 5≦n≦96 and m≦n+8, wherein m and n satisfy the electron counting rules of macropolyhedral boranes. The invention is particularly useful for synthesis of octadecaborane (B18H22). Preferred methods of the invention include iteratively generating a conjugate acid from a salt of the [BaHb]c− or [Bn+2Hm−4]2− anion followed by degradation under conditions conducive to concentrating and drying of the conjugate acid to provide a borane BnHm and residual salt of the [BaHb]c− or [Bn+2Hm−4]2− anion which is reused in the method of synthesis. The invention further provides isotopically enriched boranes, particularly isotopically enriched 10B18H22 and 11B18H22.

    摘要翻译： 本发明提供了用于合成大的硼氢化物簇的新方法，例如式BnHm的硼氢化物分子，其中5和nlE; n和nlE; 96和m和nlE; n + 8，其中m和n满足大面积硼烷的电子计数规则。 本发明对于十八硼烷（B18H22）的合成特别有用。 本发明的优选方法包括从[BaHb] c-或[Bn + 2Hm-4] 2-阴离子的盐反复生成共轭酸，然后在有利于浓缩和干燥共轭酸的条件下降解以提供硼烷 BnHm和在合成方法中重复使用的[BaHb] c-或[Bn + 2Hm-4] 2-阴离子的残留盐。 本发明还提供同位素富集的硼烷，特别是同位素富集的10B18H22和11B18H22。

    NONLINEAR OPTICAL CRYSTALS AND THEIR MANUFACTURE AND USE
    10.
    发明申请
    NONLINEAR OPTICAL CRYSTALS AND THEIR MANUFACTURE AND USE 有权
    非线性光学晶体及其制造和使用

    公开(公告)号：US20080043787A1

    公开(公告)日：2008-02-21

    申请号：US11765406

    申请日：2007-06-19

    申请人： Douglas Keszler ,  Ning Ye

    发明人： Douglas Keszler ,  Ning Ye

    IPC分类号： H01S3/10 ,  C01B35/18

    CPC分类号： C30B9/00 ,  C09K11/7712 ,  C30B9/12 ,  C30B17/00 ,  C30B29/10 ,  C30B29/22 ,  G02F1/3551

    摘要： Described are nonlinear optical (NLO) crystals, including aluminum-borate NLO crystals, that have low concentrations of contaminants that adversely affect the NLO crystal's optical properties, such as compounds that contain transition-metal elements and/or lanthanides, other than yttrium, lanthanum, and lutetium. Some NLO crystals with low concentrations of these contaminants are capable of second harmonic generation at very short wavelengths. Also described are embodiments of a method for making these NLO crystals. Some embodiments involve growing a single NLO crystal, such as an aluminum-borate NLO crystal, from a mixture containing a solvent that is substantially free of harmful contaminants. The described NLO crystals can be used, for example, in laser devices.

    摘要翻译： 描述了非线性光学（NLO）晶体，包括铝 - 硼酸盐NLO晶体，其具有低浓度的污染物，其不利地影响NLO晶体的光学性质，例如包含过渡金属元素和/或镧系元素的化合物，除了钇，镧 和镥。 一些具有低浓度这些污染物的NLO晶体能够在非常短的波长下产生二次谐波。 还描述了制造这些NLO晶体的方法的实施方案。 一些实施方案涉及从含有基本上不含有害污染物的溶剂的混合物中生长单个NLO晶体，例如铝 - 硼酸盐NLO晶体。 所描述的NLO晶体可以用于例如激光器件中。