Process for producing hydrogen from water using cobalt and barium
compounds
    3.
    发明授权
    Process for producing hydrogen from water using cobalt and barium compounds 失效
    使用钴和钡化合物从水中生产氢的方法

    公开(公告)号:US4180555A

    公开(公告)日:1979-12-25

    申请号:US934768

    申请日:1978-08-17

    IPC分类号: C01B3/06 C01B1/09 C01B1/00

    CPC分类号: C01B3/063 Y02E60/36

    摘要: A thermochemical process for producing hydrogen comprises the step of reacting CoO with BaO or Ba(OH).sub.2 in the presence of steam to produce H.sub.2 and novel double oxides of Ba and Co having the empirical formulas BaCoO.sub.2.33 and Ba.sub.2 CoO.sub.3.33. The double oxide can be reacted with H.sub.2 O to form Co.sub.3 O.sub.4 and Ba(OH).sub.2 which can be recycled to the original reaction. The Co.sub.3 O.sub.4 is converted to CoO by either of two procedures. In one embodiment Co.sub.3 O.sub.4 is heated, preferably in steam, to form CoO. In another embodiment Co.sub.3 O.sub.4 is reacted with aqueous HCl solution to produce CoCl.sub.2 and Cl.sub.2. The CoCl.sub.2 is reacted with H.sub.2 O to form CoO and HCl and the CoO is recycled to the initial reaction step. The Cl.sub.2 can be reacted with H.sub.2 O to produce HCl. HCl can be recycled for reaction with Co.sub.3 O.sub.4.

    摘要翻译: 用于制备氢的热化学方法包括在蒸气存在下使CoO与BaO或Ba(OH)2反应以产生H 2和具有经验式BaCoO3.33和Ba2CoO3.33的新型双重氧化物Ba和Co的步骤。 双氧化物可以与H 2 O反应形成Co3O4和Ba(OH)2,可以将其再循环到原始反应中。 Co3O4通过两种方法之一转化为CoO。 在一个实施方案中,Co 3 O 4优选在蒸汽中加热以形成CoO。 在另一个实施方案中,Co 3 O 4与HCl水溶液反应以产生CoCl 2和Cl 2。 CoCl 2与H 2 O反应形成CoO和HCl,CoO再循环至初始反应步骤。 Cl2可与H 2 O反应产生HCl。 可以将HCl再循环用于与Co 3 O 4反应。