GAS DIFFUSION ELECTRODE
    1.
    发明申请
    GAS DIFFUSION ELECTRODE 有权
    气体扩散电极

    公开(公告)号:US20130280625A1

    公开(公告)日:2013-10-24

    申请号:US13997737

    申请日:2011-12-23

    Abstract: A method of preparing a gas diffusion electrode comprising a diffusion layer, and a reaction layer arranged to each other, wherein the diffusion layer is prepared by i) admixing a) sacrificial material, b) polymer and c) a metal-based material and d) optional further components, wherein the sacrificial material has a release temperature below about 275° C. and is added in an amount from about 1 to about 25 wt % based on the total weight of components a)-d) admixed; ii) forming a diffusion layer from the admixture of step i); iii) heating the forming diffusion layer to a temperature lower than about 275° C. so as to release at least a part of said sacrificial material from the diffusion layer. A gas diffusion electrode comprising a diffusion layer and a reaction layer arranged to one another, wherein the diffusion layer has a porosity ranging from about 60 to about 95%, and an electrolytic cell comprising the electrode. An electrolytic cell, a fuel cell comprising the gas diffusion electrode and a metal-air battery comprising the gas diffusion electrode.

    Abstract translation: 一种制备包括扩散层的气体扩散电极和彼此排列的反应层的方法,其中所述扩散层通过以下步骤制备:i)混合a)牺牲材料,b)聚合物和c)金属基材料和d )可选的另外的组分,其中所述牺牲材料具有低于约275℃的释放温度,并且以相对于混合的组分a)-d)的总重量为约1至约25重量%的量加入; ii)从步骤i)的混合物形成扩散层; iii)将成形扩散层加热到低于约275℃的温度,以便从扩散层中释放至少一部分所述牺牲材料。 一种气体扩散电极,包括扩散层和彼此排列的反应层,其中所述扩散层具有约60至约95%的孔隙率,以及包含所述电极的电解池。 电解槽,包括气体扩散电极的燃料电池和包括气体扩散电极的金属空气电池。

    Carbon cloth supported electrode
    3.
    发明授权
    Carbon cloth supported electrode 失效
    碳布支撑电极

    公开(公告)号:US4349428A

    公开(公告)日:1982-09-14

    申请号:US269135

    申请日:1981-06-01

    CPC classification number: C25B11/0489 C25B11/0436 C25B11/12

    Abstract: A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

    Abstract translation: 公开了一种流动阳极,其通过制备约8至约18重量%固体的液体悬浮液制备,固体包含约3.5至约8%的铂,钯,氧化钯或其混合物的粉末状催化剂; 约60至约76%的具有小于约20μm的粒度的碳粉末(载体)和约20至约33%的粒度小于约500μm的惰性粘合剂。 将足够量的悬浮液倒入碳布上以在电极完成时在碳布上形成约0.01至约0.05cm厚的固体层。 向碳布的相对侧施加真空以除去液体,并将催化剂层/布组件在约10至约50MPa的范围内干燥和压缩。 然后将粘合剂在惰性气氛中烧结以完成电极。 该电极用于硫基分解循环中二氧化硫的氧化,用于水分解。

    Gas diffusion electrode
    5.
    发明授权
    Gas diffusion electrode 有权
    气体扩散电极

    公开(公告)号:US09023549B2

    公开(公告)日:2015-05-05

    申请号:US13997737

    申请日:2011-12-23

    Abstract: A method of preparing a gas diffusion electrode comprising a diffusion layer, and a reaction layer arranged to each other, wherein the diffusion layer is prepared by i) admixing a) sacrificial material, b) polymer and c) a metal-based material and d) optional further components, wherein the sacrificial material has a release temperature below about 275° C. and is added in an amount from about 1 to about 25 wt % based on the total weight of components a)-d) admixed; ii) forming a diffusion layer from the admixture of step i); iii) heating the forming diffusion layer to a temperature lower than about 275° C. so as to release at least a part of said sacrificial material from the diffusion layer. A gas diffusion electrode comprising a diffusion layer and a reaction layer arranged to one another, wherein the diffusion layer has a porosity ranging from about 60 to about 95%, and an electrolytic cell comprising the electrode. An electrolytic cell, a fuel cell comprising the gas diffusion electrode and a metal-air battery comprising the gas diffusion electrode.

    Abstract translation: 一种制备包括扩散层的气体扩散电极和彼此排列的反应层的方法,其中所述扩散层通过以下步骤制备:i)混合a)牺牲材料,b)聚合物和c)金属基材料和d )可选的另外的组分,其中所述牺牲材料具有低于约275℃的释放温度,并且以相对于混合的组分a)-d)的总重量为约1至约25重量%的量加入; ii)从步骤i)的混合物形成扩散层; iii)将成形扩散层加热到低于约275℃的温度,以便从扩散层中释放至少一部分所述牺牲材料。 一种气体扩散电极,包括扩散层和彼此排列的反应层,其中所述扩散层具有约60至约95%的孔隙率,以及包含所述电极的电解池。 电解槽,包括气体扩散电极的燃料电池和包括气体扩散电极的金属空气电池。

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