Aromatic amine epoxide adducts for corrosion inhibition

    公开(公告)号:US11932795B2

    公开(公告)日:2024-03-19

    申请号:US17337690

    申请日:2021-06-03

    申请人: Ecolab USA Inc.

    摘要: Compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, the method comprising contacting an anticorrosion compound of Formula 1 with the surface, the anticorrosion compound of Formula 1 having a structure corresponding to:




    wherein R1, R2, R3, R4, and R5 are independently selected from hydrogen, hydroxyl, alkyl, alkoxyl, aryl, alkaryl, aralkyl, and —NR8R9; R6 and R7 are independently hydrogen, a substituted alkyl, substituted alkenyl, substituted aryl, substituted alkaryl, or substituted aralkyl, wherein at least one substituent is a hydroxyl or an ether; provided that at least one of R6 and R7 is other than hydrogen; R8 and R9 are independently hydrogen, unsubstituted alkyl, unsubstituted alkenyl, unsubstituted aryl, unsubstituted alkaryl, unsubstituted aralkyl, substituted alkyl, substituted alkenyl, or substituted alkaryl, wherein at least one substituent is a hydroxyl or an ether; or any two adjacent groups of R1, R2, R3, R4, and R5 form one or more ring structures.

    Mannich-base inhibitor for decalcification, preparation method and application thereof
    3.
    发明授权
    Mannich-base inhibitor for decalcification, preparation method and application thereof 有权
    用于脱钙的曼尼希碱抑制剂及其制备方法和应用

    公开(公告)号:US09399735B2

    公开(公告)日:2016-07-26

    申请号:US13990389

    申请日:2012-04-27

    IPC分类号: C09K15/30 C10G75/02 C23F11/14

    摘要: A mannich-base inhibitor for decalcification, a preparation method and application thereof are provided. The inhibitor comprises 10-80% mannich-base component calculated in the total weight percent of the inhibitor, while the rest is at least one compound selected from imidazoline inhibitor with molecular weight between 110 and 750, and alkynyloxy amine inhibitor. The mannich-base inhibitor component is prepared through mannich reaction with 1 mol organic polyamine containing three or more primary amine bases and/or secondary amine bases, 3-7 mol ketones, and 3-7 mol aldehydes. The inhibitor which can be effectively compounded and cooperated with oil demulsifying agent and oil decalcifying agent, have the advantages of stable property, strong absorbability, high film strength and film density with its inhibition rate exceeding 90%. The inhibitor is especially adapted for inhibiting the steel corrosion caused by the mixed medium of salt, acid and water from the desalination and dehydration apparatus of oil refinery below 160° C.

    摘要翻译: 提供了一种用于脱钙的甘露糖酸碱抑制剂,其制备方法和应用。 抑制剂包含以抑制剂总重量百分数计算的10-80%甘露糖基组分,而其余为选自分子量为110至750的咪唑啉抑制剂和炔氧基胺抑制剂中的至少一种化合物。 甘露糖基抑制剂组分通过与含有三个或更多个伯胺碱和/或仲胺碱,3-7mol酮和3-7mol醛的1mol有机多胺的甘露糖反应制备。 可与油破乳剂和脱油剂配合使用的抑制剂具有性能稳定,吸水性强,膜强度高,膜密度高,抑制率超过90%的优点。 该抑制剂特别适用于在低于160℃的炼油厂的脱盐脱水装置中抑制由盐,酸和水的混合介质引起的钢腐蚀。

    MANNICH-BASE INHIBITOR FOR DECALCIFICATION, PREPARATION METHOD AND APPLICATION THEREOF
    5.
    发明申请
    MANNICH-BASE INHIBITOR FOR DECALCIFICATION, PREPARATION METHOD AND APPLICATION THEREOF 有权
    用于分解的MANNICH-BASE抑制剂,其制备方法和应用

    公开(公告)号:US20130256602A1

    公开(公告)日:2013-10-03

    申请号:US13990389

    申请日:2012-04-27

    IPC分类号: C09K15/30

    摘要: A mannich-base inhibitor for decalcification, a preparation method and application thereof are provided. The inhibitor comprises 10-80% mannich-base component calculated in the total weight percent of the inhibitor, while the rest is at least one compound selected from imidazoline inhibitor with molecular weight between 110 and 750, and alkynyloxy amine inhibitor. The mannich-base inhibitor component is prepared through mannich reaction with 1 mol organic polyamine containing three or more primary amine bases and/or secondary amine bases, 3-7 mol ketones, and 3-7 mol aldehydes. The inhibitor which can be effectively compounded and cooperated with oil demulsifying agent and oil decalcifying agent, have the advantages of stable property, strong absorbability, high film strength and film density with its inhibition rate exceeding 90%. The inhibitor is especially adapted for inhibiting the steel corrosion caused by the mixed medium of salt, acid and water from the desalination and dehydration apparatus of oil refinery below 160° C.

    摘要翻译: 提供了一种用于脱钙的甘露糖酸碱抑制剂,其制备方法和应用。 抑制剂包含以抑制剂总重量百分数计算的10-80%甘露糖基组分,而其余为选自分子量为110至750的咪唑啉抑制剂和炔氧基胺抑制剂中的至少一种化合物。 甘露糖基抑制剂组分通过与含有三个或更多个伯胺碱和/或仲胺碱,3-7mol酮和3-7mol醛的1mol有机多胺的甘露糖反应制备。 可与油破乳剂和脱油剂配合使用的抑制剂具有性能稳定,吸水性强,膜强度高,膜密度高,抑制率超过90%的优点。 该抑制剂特别适用于在低于160℃的炼油厂的脱盐脱水装置中抑制由盐,酸和水的混合介质引起的钢腐蚀。

    Corrosion inhibitors for cement compositions
    7.
    发明授权
    Corrosion inhibitors for cement compositions 失效
    水泥组合物的腐蚀抑制剂

    公开(公告)号:US6071436A

    公开(公告)日:2000-06-06

    申请号:US631490

    申请日:1996-04-12

    摘要: Compositions and methods relating to cementitious compositions are provided. The addition of an amidoamine that is the reaction product of polyalkylenepolyamines and short-chain alkanedioic acids or reactive derivatives thereof to cementitious compositions has been found useful in inhibiting the corrosion of ferrous metal articles in contact with said composition. The amidoamine is advantageously employed in combination with a hydrophobe compound that enhances corrosion inhibition. The invention also provides aqueous emulsions which contain the amidoamine, one or more hydrophobes, and an emulsifier for the hydrophobe.

    摘要翻译: 提供了与水泥组合物相关的组合物和方法。 已经发现将聚亚烷基多胺和短链链烷二酸或其反应性衍生物的反应产物的酰氨基胺加入水泥质组合物中可用于抑制与所述组合物接触的黑色金属制品的腐蚀。 酰氨基胺有利地与增强腐蚀抑制的疏水化合物组合使用。 本发明还提供含有氨基胺,一种或多种疏水物和用于疏水物的乳化剂的水性乳液。

    Aerosol corrosion inhibitors
    8.
    发明授权
    Aerosol corrosion inhibitors 失效
    气溶胶腐蚀抑制剂

    公开(公告)号:US4602958A

    公开(公告)日:1986-07-29

    申请号:US721444

    申请日:1985-04-09

    IPC分类号: C23F11/14 C09B9/02

    CPC分类号: C23F11/14

    摘要: Corrosion inhibitor compositions comprising a mixture of (1) a volatile amine selected from the group consisting of cyclohexylamine, isopropylamine and morpholine and (2) a tertiary C.sub.12-14 alkylammonium carboxylate selected from the group consisting of a C.sub.12-14 alkylammonium benzoate and a tertiary C.sub.12-14 alkylammonium-N-oleoyl sarcosinate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.

    摘要翻译: 腐蚀抑制剂组合物,其包含(1)选自环己胺,异丙胺和吗啉的挥发性胺的混合物和(2)选自C12-14烷基铵苯甲酸盐和叔碳酸二烷基铵的叔碳酸C12-14烷基铵盐的混合物 C12-14烷基铵-N-油酰肌氨酸盐。 这种组合物可用于抑制含有水基气溶胶制剂的镀锡气溶胶罐内表面的腐蚀。

    Aerosol corrosion inhibitors
    9.
    发明授权
    Aerosol corrosion inhibitors 失效
    气溶胶腐蚀抑制剂

    公开(公告)号:US4600530A

    公开(公告)日:1986-07-15

    申请号:US716479

    申请日:1985-03-27

    IPC分类号: C09K3/30 C23F11/14

    摘要: Corrosion inhibitor compositions comprising a mixture of a nitroalkane containing 1-3 carbon atoms and a tertiary C.sub.12-14 alkylammonium carboxylate selected from the group consisting of a C.sub.12-14 alkylammonium benzoate and a tertiary C.sub.12-14 alkylammonium-N-oleoyl sarcosinate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.

    摘要翻译: 包含含有1-3个碳原子的硝基烷烃和选自C12-14烷基铵苯甲酸盐和叔C12-14烷基铵-N-油酰基肌氨酸钠的叔碳酸C12-14烷基铵盐的混合物的腐蚀抑制剂组合物。 这种组合物可用于抑制含有水基气溶胶制剂的镀锡气溶胶罐内表面的腐蚀。