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    Process for producing aryloxy-substituted phosphazene derivatives
    5.
    发明授权
    Process for producing aryloxy-substituted phosphazene derivatives 失效
    制备芳氧基取代的磷腈衍生物的方法

    公开(公告)号：US5075453A

    公开(公告)日：1991-12-24

    申请号：US401570

    申请日：1989-08-29

    Applicant: Shinichiro Ueyama ,  Kazuhiko Fujikawa ,  Yasuhiro Yoshikawa ,  Tetsuhiko Okamoto ,  Masayuki Furukawa ,  Tadaichi Nishikawa

    Inventor： Shinichiro Ueyama ,  Kazuhiko Fujikawa ,  Yasuhiro Yoshikawa ,  Tetsuhiko Okamoto ,  Masayuki Furukawa ,  Tadaichi Nishikawa

    IPC: C07F9/06 ,  C07F9/6581 ,  C08G79/02 ,  C10M105/74

    CPC classification number: C07F9/65814 ,  C07F9/067 ,  C08G79/025 ,  C10M105/74

    Abstract: A process for producing an aryloxy-substituted phosphazene derivative represented by the formula(N.dbd.P).sub.n (OAr).sub.l Cl.sub.m-l R.sup.1.sub.p (III)which comprises reacting a chlorophosphazene derivative represented by the general formula(N.dbd.P).sub.n Cl.sub.m R.sup.1.sub.p (I)with, a hydroxy aryl compound represented by the general formulaHOAr (II)whereR.sup.1 represents hydroxy group, NH.sub.2 group, --OR.sup.4 group, --SR.sup.4 group or ##STR1## group, where R.sup.4, R.sup.5 and R.sup.6 represent independently an alkyl group, an alkenyl group, alkynyl group or an aryl group or one of R.sup.5 or R.sup.6 may be hydrogen or R.sup.5 and R.sup.6 may form, together with a nitrogen atom bonded thereto, a saturated or an unsaturated heterocyclic ring,n is an integer of 3 to 20,m is an integer of 1 to 2n,p is 2n-m,Ar represents substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, or substituted or unsubstituted N-maleimidophenyl,l is an integer of 1 to m,wherein the reaction is carried out under the presence of an acid acceptor and a pyridine derivative represented by the formula ##STR2## where Q.sup.1 and Q.sup.2 represent identical or different lower alkyl groups or constitute together with a nitrogen atom bonded thereto, a pyrrolidine ring, piperidine ring or morpholine ring.

    Abstract translation: 一种制备由式（N = P）n（OAr）1 Clm-lR1p（III）表示的芳氧基取代的磷腈衍生物的方法，其包括使由通式（N = P）nClmR1p（I）表示的氯代膦腈衍生物 与通式为HOAr（II）表示的羟基芳基化合物，其中R 1表示羟基，NH 2基，-OR 4基团，-SR 4基团或基团，其中R 4，R 5和R 6独立地表示烷基， 烯基，炔基或芳基，或者R 5或R 6中的一个可以是氢或R 5，R 6可以与其键合的氮原子一起形成饱和或不饱和杂环，n为3〜20的整数， m为1〜2n的整数，p为2n-m，Ar表示取代或未取代的苯基，取代或未取代的萘基，或取代或未取代的N-马来酰亚胺基苯基，l为1〜m的整数，其中， 在酸受体和吡啶衍生物代表的存在下 其中Q1和Q2表示相同或不同的低级烷基，或与其键合的氮原子一起构成吡咯烷环，哌啶环或吗啉环。

    Photographic development process
    6.
    发明授权
    Photographic development process 失效
    摄影发展过程

    公开(公告)号：US3552968A

    公开(公告)日：1971-01-05

    申请号：US3552968D

    申请日：1967-07-05

    Applicant: AGFA GEVAERT NV

    Inventor： WILLEMS JOZEF FRANS

    IPC: C07F9/6581 ,  C08G65/327 ,  G03C1/043 ,  G03C5/30 ,  G03C1/02 ,  G03C1/48

    CPC classification number: G03C1/043 ,  C07F9/65814 ,  C08G65/327 ,  Y10S430/15

    Abstract: A PHOTOGRAPHIC LIGHT-SENSITIVE MATERIAL COMPRISING A SILVER HALIDE EMULSION LAYER CONTAINING A COMPOUND CORRESPONDING TO ONE OF THE FOLLOWING STRUCTURAL FORMULAE IA OR IB:

    2-A1,2-Z1,4-A2,4-Z2,6-A3,6-Z3-1,3,5,2,4,6-

    TRIAZATRIPHOSPHORINE OR

    2-A1,2-Z1,4-A2,4-Z2,6-A3,6-Z3,8-A4,8-Z4-1,3,5,7,2,4,6,8-

    TETRAZATETRAPHOSPHOCINE

    WHEREIN:

    EACH OF A1, A2, A3, A4, Z1, Z2, Z3, AND Z4 STANDS FOR A CHLORINE ATOM OR A POLYOXYALKYLENE GROUP OF THE FORMULA -(OR1)N-X, AT LEAST ONE OF THE GROUPS A1, A2, A3, A4, Z1, Z2, Z3, OR Z4 BEING THE GROUP -(OR1)N-X WHEREIN N REPRESENTS AN INTEGER OF AT LEAST 5, THE

    -(OR1)-

    GROUP REPRESENTING REPEATING UNITS ENTIRELY CONSISTING OF ETHYLENE OXIDE UNITS OR A MIXTURE OF ETHYLENE OXIDE UNITS AND PROPYLENE OXIDE UNITS, AND X BEING A TERMINAL GROUP THAT IS UNREACTIVE WITH RESPECT TO AN ACTIVE HALOGEN ATOM OF AN ACID HALIDE COMPOUND AND IS SELECTED FROM THE GROUP CONSISTING OF

    -O-R, -OOC-R, -S-R, OR -N(-R)2

    WHEREIN R IS AN ALKYL, AN ARYL, A CYCLOALKYL, OR A HETEROCYCLIC RADICAL, SAID RADICALS BEING UNREACTIVE WITH RESPECT TO SAID ACTIVE HALOGEN ATOM IS DESCRIBED. THE SILVER HALIDE EMULSION HAS A HIGH DEVELOPING ACTIVATION IN COMBINATION WITH A VERY LOW FOG PRODUCTION.

    Oxidation-resistant cyclophosphazene fluid including triarylphosphine or phosphine oxide
    10.
    发明授权
    Oxidation-resistant cyclophosphazene fluid including triarylphosphine or phosphine oxide 失效
    包含三芳基膦或氧化膦的抗氧化环磷腈流体

    公开(公告)号：US5194652A

    公开(公告)日：1993-03-16

    申请号：US891378

    申请日：1992-05-29

    Applicant: Bassam S. Nader

    Inventor： Bassam S. Nader

    IPC: C07F9/6581 ,  C10M169/04

    CPC classification number: C10M169/04 ,  C07F9/65814 ,  C10M2223/003 ,  C10M2223/023 ,  C10M2223/04 ,  C10M2223/0405 ,  C10M2223/042 ,  C10M2223/0495 ,  C10M2223/06 ,  C10M2223/0603 ,  C10M2223/061 ,  C10M2223/083 ,  C10M2223/103 ,  C10N2240/08

    Abstract: The oxidation resistance of a cyclophosphazene-based fluid (such as a lubricant or a hydraulic fluid) can be improved by the addition to the fluid of an oxidation-inhibiting amount of an aryl phosphine or phosphine oxide. The aryl phosphine or phosphine oxide is preferably present in an amount of about 0.01 to about 5 percent by weight. The aryl phosphine or phosphine oxide can be (a) a symmetric triarylphosphine of formula R.sub.3 P, wherein R is 4-trifluoromethyl phenyl, 3-trifluoromethyl phenyl, 3-trifluoromethoxy phenyl, 3-(3-trifluoromethylphenoxy) phenyl, 3-(perfluoro-2, 5-dimethyl-3, 6-dioxanonyl) phenyl or 1-naphthyl; (b) an oxide of any of these symmetric triarylphosphines; or (c) 1, 3-bis(diphenylphosphino) benzene. The cyclophosphazene fluid component is preferably a (fluorinated phenoxy) (3-perfluoroalkylphenoxy)-cyclic phosphazene of the general formula (I): ##STR1## wherein n is 3 to 7, inclusive; wherein R is individually in each occurrence fluorinated phenoxy or 3-perfluoroalkylphenoxy; and wherein the ratio of fluorinated phenoxy to 3-perfluoroalkylphenoxy is about 1:5 to 1:1 inclusive. Although useful as antioxidants in other fluids such as polyphenyl ethers, perfluorinated aliphatic polyethers and polyol esters, the antioxidant activity of the defined aryl phosphines and phosphine oxides in cyclophosphazene fluids is unexpected because of the significant difference in the pathways of oxidative degradation between the cyclophosphazenes and these other fluids.

    Abstract translation: 通过添加到氧化抑制量的芳基膦或氧化膦的流体，可以改善环磷腈系流体（如润滑剂或液压油）的抗氧化性。 芳基膦或氧化膦优选以约0.01至约5重量％的量存在。 芳基膦或氧化膦可以是（a）式R3P的对称三芳基膦，其中R是4-三氟甲基苯基，3-三氟甲基苯基，3-三氟甲氧基苯基，3-（3-三氟甲基苯氧基）苯基，3-（全氟 - 2,5-二甲基-3,6-二恶烷基）苯基或1-萘基; （b）这些对称三芳基膦中的任何一种的氧化物; 或（c）1,3-双（二苯基膦基）苯。 环磷腈流体组分优选为通式（I）的（氟化苯氧基）（3-全氟烷基苯氧基） - 环磷腈：其中n为3至7，包括端值; 其中R各自单独出现氟化苯氧基或3-全氟烷基苯氧基; 并且其中氟化苯氧基与3-全氟烷基苯氧基的比例为约1:5至1:1。 尽管在其他流体如聚苯醚，全氟化脂族聚醚和多元醇酯中的抗氧化剂是有用的，但是定义的芳基膦和氧化膦在环磷腈流体中的抗氧化活性是出人意料的，因为环磷腈与环氧磷腈之间的氧化降解途径有显着的差异 这些其他液体。

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