Onsite integrated production factory
    1.
    发明授权
    Onsite integrated production factory 有权
    现场综合生产工厂

    公开(公告)号:US08277632B2

    公开(公告)日:2012-10-02

    申请号:US13453496

    申请日:2012-04-23

    申请人: Masataka Murahara

    发明人: Masataka Murahara

    IPC分类号: C25B1/34

    摘要: An onsite integrated production factory having an electrolytic plant, an ethanol plant, a vegetable plant, a culturing plant, and a power generation unit. The onsite integrated production facility is arranged so that fresh water, sulfuric acid or caustic soda produced by and received from the electrolytic plant is used in the ethanol plant to produce and output oxalic acid, sodium oxalate, fuel bioethanol. The oxalic acid or sodium oxalate produced in and received from the ethanol plant is used for removing calcium contained in the sea water in the electrolytic plant. The vegetable plant produces vegetables for generation and outputting of oxygen by receiving the carbon dioxide generated during the fermentation process in the ethanol plant and fresh water from the electrolytic plant. The culturing plant has a fishery farm or reef for using the oxygen generated in the vegetable plant.

    摘要翻译: 现有综合生产工厂有电解厂,乙醇厂,蔬菜厂,养殖厂和发电机组。 在现场综合生产设施中,在乙醇装置中使用由电解厂生产和接收的淡水,硫酸或苛性钠来生产和输出草酸,草酸钠,燃料生物乙醇。 在乙醇装置中生产和接收的草酸或草酸钠用于去除电解设备中海水中含有的钙。 蔬菜厂通过接收乙醇厂发酵过程中产生的二氧化碳和来自电解厂的淡水,生产和输出氧气。 养殖厂有一个渔场或礁石,用于在蔬菜厂使用氧气。

    Process for the removal of metal impurities by an electrochemical route
    3.
    发明授权
    Process for the removal of metal impurities by an electrochemical route 失效
    通过电化学途径去除金属杂质的方法

    公开(公告)号:US5976349A

    公开(公告)日:1999-11-02

    申请号:US836794

    申请日:1997-07-28

    IPC分类号: C01D1/40 C25B1/16 C25C7/02

    CPC分类号: C25C7/02 C01D1/40

    摘要: A method for electrochemically purifying solutions with a pH higher than 14 to reduce metal impurities to the level of traces. The method comprises processing the solutions in an electrolytic cell in which the cathode has a fibrous web produced from a mixture of fibres including at least one fraction consisting of electrically conductive fibres and a binder selected from fluoropolymers, said fibrous web being deposited on an electrically conductive porous support. Said cathode may also be combined with a diaphragm or a membrane. A cathode having a fibrous web produced from a mixture of carbon fibres, cellulose compounds, and a cationic polymer such as cationic starch is also disclosed.

    摘要翻译: PCT No.PCT / FR95 / 01530 Sec。 371日期1997年7月28日第 102(e)日期1997年7月28日PCT 1995年11月21日PCT PCT。 公开号WO96 / 15984 日期1996年5月30日一种电化学纯化pH高于14的溶液的方法,以将金属杂质降低到痕量水平。 该方法包括在电解池中处理溶液,其中阴极具有由包含至少一部分由导电纤维组成的纤维和选自含氟聚合物的粘合剂的纤维混合物产生的纤维网,所述纤维网被沉积在导电 多孔支撑。 所述阴极还可以与膜片或膜组合。 还公开了具有由碳纤维,纤维素化合物和阳离子聚合物如阳离子淀粉的混合物制成的纤维网的阴极。

    Process for purifying hydroxide compounds
    4.
    发明授权
    Process for purifying hydroxide compounds 失效
    氢化物化合物的纯化方法

    公开(公告)号:US5753097A

    公开(公告)日:1998-05-19

    申请号:US725626

    申请日:1996-10-03

    摘要: In one embodiment, the invention relates to a process for purifying solutions containing a hydroxide compound, including the steps of: (A) providing an electrochemical cell containing an anode, a cathode, a cation selective membrane and a bipolar membrane, the bipolar membrane having an anion selective side facing the anode and a cation selective side facing the cathode, wherein the cation selective membrane is positioned between the anode and the bipolar membrane, and the bipolar membrane is positioned between the cation selective membrane and the cathode, thereby defining a feed compartment between the cation selective membrane and the anode, a recovery compartment between the bipolar membrane and the cation selective membrane, and a water compartment between the bipolar membrane and the cathode; (B) charging a solution of an ionic compound at a first concentration to the water compartment, and water to the recovery compartment; (C) charging a solution containing the hydroxide compound at a second concentration to the feed compartment; (D) passing a current through the electrochemical cell to produce the hydroxide compound at a third concentration in the recovery compartment; and (E) recovering the hydroxide compound from the recovery compartment.

    摘要翻译: 在一个实施方案中,本发明涉及一种用于纯化含有氢氧化物化合物的溶液的方法,包括以下步骤:(A)提供含有阳极,阴极,阳离子选择性膜和双极性膜的电化学电池,所述双极性膜具有 面向阳极的阴离子选择侧和面向阴极的阳离子选择侧,其中阳离子选择性膜位于阳极和双极膜之间,并且双极膜位于阳离子选择性膜和阴极之间,从而限定进料 阳离子选择性膜和阳极之间的隔间,双极性膜和阳离子选择性膜之间的回收室,以及双极性膜与阴极之间的水隔室; (B)将第一浓度的离子化合物的溶液装入水室,并将水加到回收室; (C)将含有第二浓度的氢氧化物的溶液装入进料室; (D)使电流通过电化学电池以在回收室中产生第三浓度的氢氧化物; 和(E)从回收室回收氢氧化物。

    Method of purifying aqueous solutions of alkali metal hydroxides
    5.
    发明授权
    Method of purifying aqueous solutions of alkali metal hydroxides 失效
    净化碱金属氢氧化物水溶液的方法

    公开(公告)号:US4189362A

    公开(公告)日:1980-02-19

    申请号:US3151

    申请日:1979-01-15

    申请人: Ronald L. Dotson

    发明人: Ronald L. Dotson

    摘要: An electrolytic process is described for purifying an aqueous solution of an alkali metal hydroxide containing an impurity of a soluble heavy metal complex comprised of a heavy metal cation and a plurality of anions.For example, an aqueous solution of sodium hydroxide containing a soluble heavy metal complex, such as mercuric polysulfide, [HgS].sup.+ S.sup.-, is charged to the electrolytic chamber of an electrolytic cell. An electric current is employed to reduce heavy metal cations to a separate phase in elemental form, and simultaneously to oxidize anions to a separate phase in elemental form, and to form a slurry of the separate phases in elemental forms in the aqueous solution.The slurry is removed from the electrolytic chamber and the phases of elemental forms are separated from the purified aqueous solution. The purified alkali metal hydroxide solution is sold commercially or otherwise utilized.

    摘要翻译: 描述了用于纯化含有由重金属阳离子和多个阴离子组成的可溶性重金属络合物的杂质的碱金属氢氧化物的水溶液的电解方法。 例如,将含有可溶性重金属络合物如汞硫化物[HgS] + S-的氢氧化钠水溶液加入到电解槽的电解室中。 使用电流将重金属阳离子还原为单质相的单质相,同时将阴离子氧化成单质相的单质相,并在水溶液中形成元素分离相的浆液。 将浆料从电解槽中取出,并将元素相与纯化的水溶液分离。 纯化的碱金属氢氧化物溶液以商业或其他方式销售。

    Apparatus and method for purifying alkali metal hydroxide solutions
    6.
    发明授权
    Apparatus and method for purifying alkali metal hydroxide solutions 失效
    用于净化碱金属氢氧化物溶液的装置和方法

    公开(公告)号:US3784456A

    公开(公告)日:1974-01-08

    申请号:US3784456D

    申请日:1972-03-02

    发明人: OTTO J

    CPC分类号: C01D1/40 C25B9/06

    摘要: Aqueous alkali metal hydroxide solutions are purified by passage through a porous cathode of an electrolytic cell having an anode located downstream of the cathode. An electrolytic cell of special construction particularly useful is described.

    摘要翻译: 通过通过具有位于阴极下游的阳极的电解池的多孔阴极来纯化碱金属氢氧化物水溶液。 描述特别有用的特殊结构的电解池。

    Method and apparatus for making and concentrating an aqueous caustic alkali
    10.
    发明授权
    Method and apparatus for making and concentrating an aqueous caustic alkali 有权
    用于制造和浓缩苛性碱水溶液的方法和设备

    公开(公告)号:US08986517B2

    公开(公告)日:2015-03-24

    申请号:US13650932

    申请日:2012-10-12

    摘要: A method for concentrating an aqueous caustic alkali produced by a membrane cell process by using a single or multiple effect evaporator system in which the vapor flows in a counter direction to the aqueous caustic alkali flow and the heat recovered from the catholyte circulation line is used as part of the concentration process. In one embodiment, a catholyte heat recovery heat exchanger and flash evaporation chamber are located after the last effect of a multiple effect evaporator system. In another embodiment, the catholyte heat recovery heat exchanger and flash evaporation chamber are located prior to the single or multiple effect evaporator system. In yet another embodiment, the catholyte heat recovery process is used in conjunction with additional heat exchanger processes to further concentrate the final product as desired.

    摘要翻译: 通过使用单一或多重效应蒸发器系统浓缩通过膜电池工艺产生的苛性碱水溶液的方法,其中蒸汽沿碱性碱水流向逆向流动并且从阴极电解液循环管线回收的热量被用作 部分浓缩过程。 在一个实施方案中,阴极电解液热回收热交换器和闪蒸蒸发室位于多效蒸发器系统的最后效果之后。 在另一个实施方案中,阴极电解液热回收热交换器和闪蒸蒸发室位于单效或多效蒸发器系统之前。 在另一个实施方案中,阴极电解液热回收方法与另外的热交换器方法结合使用,以根据需要进一步浓缩最终产物。