摘要:
The invention provides a solid material for generating a flow of oxygen, the solid material comprising a chemical mixture for generating said flow of oxygen, the chemical mixture comprising as chemical components:
1-25% w/w of a self-sustaining decomposition additive, wherein the decomposition additive is selected from the group of copper (Cu), aluminium (Al), magnesium (Mg), zinc (Zn), molybdenum (Mo), manganese (Mn), cobalt (Co), nickel (Ni), iron (Fe), cobalt oxides (Co2O3 and Co3O4), copper oxide (CuO), iron oxide (Fe2O3), zinc oxide (ZnO), manganese oide (MnO), manganese dioxide (MnO2), chrome (Cr), chrome oxides, titanium, titanium oxides, and combinations thereof; 65-97% w/w of an oxygen generating component, wherein the oxygen generating component is selected from the group of alkali chlorates and alkali perchlorates, and alkali superoxides; 2-5% w/w of an inorganic binder; wherein said weight percentages are based upon the weight of the total solid material, wherein said solid material has a skeletal density of 2.8-3.5 g/cm3, wherein said solid material has a porosity of 30-50%, and wherein in said chemical mixture components are provided as particles having a volume particle size distribution having its peak between 5 and 100 μm.
摘要:
A compact ignition system for chemical oxygen generators for possible use in an aircraft. The chemical oxygen generator is configured such that a majority of the ignition system can be accommodated within an interior of the generator body. In some embodiments, the ignition system is positioned within a recess of an upper surface of the core of the generator. Housing a majority of the ignition system within the generator allows the overall oxygen-generating capacity of the generator to be increased without requiring a corresponding increase in the overall length of the generator.
摘要:
A chemical oxygen generator includes multiple parallel sequentially connected chemical core sections that extend the duration of operation of the chemical oxygen generator. An end of a first core section is contiguous with a chemical core high reactivity section, and a thermal insulation layer is disposed between an end of a second core section and the chemical core ignition plate, as well as between the bodies of the first and second core sections. A chemical core transition section is disposed between the other end of the first core section and the second core section, to insure that the reaction front propagates properly.
摘要:
The present invention is directed to a chemical oxygen generator to produce cool oxygen gas comprising: a. a charge housing, b. a solid but porous charge contained in the said housing, the charge being made of a chemical mixture that generates oxygen upon decomposition and that will undergo a self-sustained exothermal decomposition after initiation, the said charge containing at most 3.0 wt. % of binder material, the said porous charge allows the generated oxygen to pass through the charge without damaging the virgin material and without creating volumetric burning, the said charge is mounted in the housing in such a way that the generated oxygen passes through the charge and under the pressure difference flows from the moving decomposition front towards the vent, c. an ignition device mounted at one end of the cartridge in such a way that it is capable to initiate a self-sustained decomposition of the charge at the charge surface adjacent to the initiator, d. one or more vents mounted in such a way that the generated oxygen that has passed through the generating porous charge leave the gas generator through the said vents.
摘要:
The invention relates to a process for the production of chlorine dioxide in an apparatus comprising a reaction vessel holding a reaction medium and a circulation conduit leading through a heater for the reaction medium, said process comprising the steps of continuously: a) maintaining the reaction medium at subatmospheric pressure and a temperature sufficient for evaporating water; b) circulating reaction medium through the circulation conduit and the heater; c) reacting alkali metal chlorate, sulfuric acid and hydrogen peroxide in the reaction medium to form chlorine dioxide, oxygen and alkali metal sulfate; d) feeding alkali metal chlorate, sulfuric acid and hydrogen peroxide to the reaction medium, wherein the sulfuric acid is fed through an inlet into the circulation conduit and the hydrogen peroxide is fed through an inlet directly into the reaction vessel or through an inlet into the circulation conduit down-streams the inlet for sulfuric acid at a distance in the flow direction therefrom of at least about the inner diameter of the circulation conduit; and, e) withdrawing a gas comprising chlorine dioxide, oxygen and evaporated water. The invention further relates to an apparatus for the production of chlorine dioxide.
摘要:
The oxygen generation compositions include about 0.5-15% by weight of a substantially carbon-free metal fuel, and about 0.1-20% by weight of alkali metal silicate, stannate, titanate or zirconate as a reaction rate and core rheology modifier and chlorine suppresser. The oxygen generating compositions also contain about 0.1-15% by weight of a transition metal oxide catalyst; and the remainder is substantially an alkali metal chlorate or perchlorate.
摘要:
A candle type chemical oxygen generator which insures complete thermal decomposition of the candle with a predetermined flow rate of oxygen while maintaining the generator housing at a low temperature. Oxygen generated as a result of the thermal decomposition of the oxygen generating candle (32) by triggering the ignition device (F'), passes through cylindrical thermal insulation (36) and an annular gap between the cylindrical thermal insulation (36) and the cylindrical member (37) which houses the candle to thereby cool the cylindrical member, and is supplied to the exterior through the oxygen supply device (S').
摘要:
An improved chemical oxygen generator (10) includes an oxygen generating candle (12) having an oxygen source, which upon decomposition will yield oxygen, and a nontoxic additive to smooth decomposition and suppress formation of toxic free chlorine gas. The nontoxic additive may be taken from the group consisting of: (1) the oxides, hydroxides and carbonates of calcium and the rare earth elements; (2) the hydroxides and carbonates of magnesium; and (3) mixtures of the foregoing. A complete chemical oxygen generator utilizes the candle (12) of the invention. The oxygen generator preferably includes a canister (14), oxygen-generating candle (12), and an ignition device (16). Triggering of the ignition device ignites an ignition pellet (52) which initiates decomposition of the candle body (50). Once initiated, the candle will sustain decomposition to release breathable oxygen until the candle is completely reacted.
摘要:
A substantially fuel-free oxygen-generating composition consisting essentially of an alkali metal chlorate which may contain a small amount of perchlorate, in combination with a catalytic amount in the order of about 0.5 to 5.0% by weight of cobalt oxide.
摘要:
An ignition cone composition including an alkaline metal or alkaline earth metal iodide or oxyiodide in combination with a principal oxidizer consisting of an alkaline metal mono-oxide and usually, an auxiliary oxidizer consisting of one or more alkaline metal and alkaline earth metal peroxides and chlorates which term includes the chlorates and perchlorates. This composition is included as a separate top layer in compressing a chemical oxygen generator composition or other composition to be ignited by the ignition cone compositions. In the preferred form, a water filled fracturable vial is associated with said layer so that upon fracture, the water causes initiation of said ignition cone composition, usually best preformed through the use of an uncompacted or loose powder first fire composition of similar content as said ignition cone composition.