Adhesive-resin-modified adhesive mass

    公开(公告)号:US10808146B2

    公开(公告)日:2020-10-20

    申请号:US15757826

    申请日:2016-08-16

    申请人: TESA SE

    摘要: The invention relates to a UV-cross-linked, polyacrylate-based adhesive mass that has high adhesive force and high cohesion and that can be produced by means of a hot-melt process with subsequent cross-linking. This is achieved by providing an adhesive mass that can be obtained by cross-linking a composition, which comprises at least one poly(meth)acrylate having a weight-average molar mass Mw of at least 100,000 g/mol and at least one polyfunctional α-cleaver and is characterized in that the composition contains at least one adhesive-force-increasing resin having a weight average molar mass Mw of at most 30,000 g/mol, which resin can be obtained by polymerizing a monomer composition M1, comprising at least one compound according to formula (I) H2C═C(R1)(COOR2), wherein R1 represents a hydrogen atom or a methyl group and R2 represents a hydrogen atom or a functionalized or non-functionalized C1-C20 alkyl group.

    Crosslinker-accelerator system for polyacrylates

    公开(公告)号:US10174139B2

    公开(公告)日:2019-01-08

    申请号:US13745298

    申请日:2013-01-18

    申请人: tesa SE

    IPC分类号: C08F20/10 C09J133/08

    摘要: In the context of a polyacrylate-based composition, the intention is to allow controlled thermal crosslinking. This is accomplished by provision of a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance conforming to the general formula (I) NR3  (I), in which the radicals R independently of one another are a hydrogen atom or an organic radical having 1 to 20 carbon atoms, with at least one of the radicals R being an organic radical with 1 to 20 carbon atoms, and comprising at least one alcoholic OH group.

    Crosslinker-accelerator system for polyacrylates

    公开(公告)号:US09908953B2

    公开(公告)日:2018-03-06

    申请号:US13745346

    申请日:2013-01-18

    申请人: tesa SE

    摘要: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10  (I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).

    Crosslinker-Accelerator System for Polyacrylates
    5.
    发明申请
    Crosslinker-Accelerator System for Polyacrylates 有权
    聚丙烯酸酯交联剂 - 加速剂体系

    公开(公告)号:US20130190457A1

    公开(公告)日:2013-07-25

    申请号:US13745346

    申请日:2013-01-18

    申请人: tesa SE

    IPC分类号: C08F20/18

    摘要: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at leastone substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10  (I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).

    摘要翻译: 基于聚丙烯酸酯的组合物中的受控热交联通过交联剂 - 促进剂体系完成,所述交联剂 - 促进剂体系用于具有适于进入与环氧基团的连接反应的官能团的聚丙烯酸酯的热交联,所述交联剂加速剂体系包含至少一种包含至少一个环氧基团的物质(交联剂) 和其中基团R 1,R 2,R 9和R 10彼此独立地为氢原子或取代或未取代的至少一种通式(I)R 1 R 2 N-CR 3 R 4 -CR 5 R 6 - (CR 7 R 8)n -NR 9 R 10(I) 具有1至8个碳原子的烷基或环烷基或与主链键合且具有1至8个碳原子的亚烷基,其中基团R 1,R 2,R 9和R 10中的至少一个不是氢原子; R 3,R 4,R 5,R 6,R 7和R 8彼此独立地为氢原子或具有1至8个碳原子的烷基或形成5-7元环亚烷基; n为0〜4的整数(促进剂)。

    Crosslinker-accelerator system for polyacrylates

    公开(公告)号:US10906997B2

    公开(公告)日:2021-02-02

    申请号:US15834634

    申请日:2017-12-07

    申请人: TESA SE

    摘要: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at least
    one substance having at least one epoxide group as crosslinker and
    at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n=0; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

    Crosslinker-accelerator system for polyacrylates

    公开(公告)号:US09896521B2

    公开(公告)日:2018-02-20

    申请号:US13736476

    申请日:2013-01-08

    申请人: tesa SE

    摘要: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at least one substance having at least one epoxide group as crosslinker and at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n is an integer from 0 to 4; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

    Process for preparing polyacrylates
    8.
    发明授权
    Process for preparing polyacrylates 有权
    制备聚丙烯酸酯的方法

    公开(公告)号:US09410028B2

    公开(公告)日:2016-08-09

    申请号:US13717939

    申请日:2012-12-18

    申请人: tesa SE

    CPC分类号: C08K5/36 C08F2/38 C08F20/18

    摘要: Process for preparing polyacrylates, by the free-radical polymerization of monomer mixtures comprising at least 70% by weight of at least one acrylic and/or methacrylic ester in the presence of amino acids as regulator substances, and reaction solution comprising one or more solvents and one or more monomers, at least 50% by weight of the solvents being organic solvents, and at least 70% by weight of the monomers being acrylic and/or methacrylic esters, with at least one amino acid being present.

    摘要翻译: 在作为调节剂物质的氨基酸存在下,通过包含至少70重量%的至少一种丙烯酸和/或甲基丙烯酸酯的单体混合物的自由基聚合以及包含一种或多种溶剂的反应溶液和 一种或多种单体,至少50重量%的溶剂是有机溶剂,并且至少70重量%的单体是丙烯酸和/或甲基丙烯酸酯,其中存在至少一个氨基酸。

    Crosslinker-Accelerator System for Polyacrylates
    9.
    发明申请
    Crosslinker-Accelerator System for Polyacrylates 审中-公开
    聚丙烯酸酯交联剂 - 加速剂体系

    公开(公告)号:US20130190460A1

    公开(公告)日:2013-07-25

    申请号:US13745298

    申请日:2013-01-18

    申请人: tesa SE

    IPC分类号: C08F20/10

    摘要: In the context of a polyacrylate-based composition, the intention is to allow controlled thermal crosslinking. This is accomplished by provision of a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprisingat least one substance comprising at least one epoxide group (crosslinker) and at least one substance conforming to the general formula (I) NR3  (I), in which the radicals R independently of one another are a hydrogen atom or an organic radical having 1 to 20 carbon atoms, with at least one of the radicals R being an organic radical with 1 to 20 carbon atoms, and comprising at least one alcoholic OH group.

    摘要翻译: 在基于聚丙烯酸酯的组合物的上下文中,意图是允许受控的热交联。 这通过提供用于具有适于进入与环氧基团的连接反应的官能团的聚丙烯酸酯的热交联的交联剂 - 促进剂体系来实现,所述组合物包含至少一种包含至少一种环氧基团(交联剂)和至少一种符合 通式(I)NR 3(I),其中基团R彼此独立地为氢原子或具有1至20个碳原子的有机基团,其中基团R中的至少一个为有机基团,具有1个 至20个碳原子,并且包含至少一个醇OH基团。