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公开(公告)号：US08616695B2
公开(公告)日：2013-12-31
申请号：US13442279
申请日：2012-04-09
IPC分类号： G01D11/00
CPC分类号： C09D11/322 , C09D11/326
摘要： Provided is an ink jet ink including a monoazo pigment and a resin, the ink being used for an ink jet recording system in which the ink is ejected from a recording head by an action of thermal energy. The monoazo pigment is a self-dispersible pigment having an anionic group bonded to a particle surface of the pigment directly or via another atomic group and has a surface charge amount of 5.9×10−2 mmol/g or more and 9.8×10−2 mmol/g or less. The resin has an acid value of 100 mg KOH/g or more and 160 mg KOH/g or less. The mass ratio of the content (mass %) of the resin to the content (mass %) of the monoazo pigment in the ink is 0.05 times or more and 0.25 times or less.
摘要翻译： 提供了一种包括单偶氮颜料和树脂的喷墨油墨，该油墨用于喷墨记录系统，其中通过热能从记录头喷射油墨。 单偶氮颜料是具有阴离子基团的自分散颜料，其直接或通过另一个原子基团与颜料的颗粒表面键合，并且表面带电量为5.9×10 -2 mmol / g以上至9.8×10 -2 mmol / g以下。 该树脂的酸值为100mg KOH / g以上且160mgKOH / g以下。 树脂的含量（质量％）与油墨中单偶氮颜料的含量（质量％）的质量比为0.05倍以上且0.25倍以下。
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公开(公告)号：US20130027476A1
公开(公告)日：2013-01-31
申请号：US13530504
申请日：2012-06-22
申请人： Yasuhito Mori , Tomohiro Yamashita
发明人： Yasuhito Mori , Tomohiro Yamashita
CPC分类号： C09D11/38 , B41J2/2107 , C09D11/322
摘要： The invention provides an ink that inhibits lowering of ejection stability caused by a precipitate derived from a self-dispersible type monoazo pigment and also inhibits deterioration of a liquid contact surface of a heater portion of a recording head. The ink is an ink for ink jet recording system employing an thermal energy, containing a monoazo pigment, a resin and a surfactant represented by the following formula (1). A proportion of a molecular weight of an ethylene oxide group moiety occupying the surfactant is 10% or more and 85% or less, the monoazo pigment is a self-dispersible pigment to the particle surface of which at least one hydrophilic group selected from the group consisting of —COOM, —SO3M, —PO3HM and —PO3M2 is bonded directly or through another atomic group, and the acid value of the resin is 240 mg KOH/g or less.
摘要翻译： 本发明提供了抑制由自分散型单偶氮颜料衍生的沉淀物引起的喷射稳定性的降低的油墨，并且还抑制了记录头的加热器部分的液体接触表面的劣化。 油墨是使用含有单偶氮颜料，树脂和由下式（1）表示的表面活性剂的热能的喷墨记录系统的油墨。 占该表面活性剂的环氧乙烷基部分的分子量的一个比例为10％以上且85％以下，单偶氮颜料是粒子表面的自分散颜料，其中至少一个亲水基团选自基团 由-COOM，-SO3M，-PO3HM和-PO3M2构成的物质直接或通过另一原子团键合，树脂的酸值为240mgKOH / g以下。
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3.发明申请LIQUID COMPOSITION, SET, LIQUID CARTRIDGE, INKJET RECORDING METHOD, AND INKJET RECORDING APPARATUS 有权液体组合物，套装，液体盒，喷墨记录方法和喷墨记录装置公开(公告)号：US20110057994A1
公开(公告)日：2011-03-10
申请号：US12874964
申请日：2010-09-02
摘要： A liquid composition used in combination with an ink containing a coloring material is ejected by the action of thermal energy from a recording head including a heating resistor having a protecting layer that is to come into contact with the liquid composition and that contains at least one of a metal and a metal oxide. The liquid composition contains at least either an organic compound having a carboxy group and an amino group or an amine oxide compound, an organic acid having a carboxy group, and water.
摘要翻译： 与含有着色材料的油墨组合使用的液体组合物通过来自包括具有与液体组合物接触的保护层的加热电阻器的记录头的热能的作用喷射，并且包含至少一种 金属和金属氧化物。 液体组合物至少含有具有羧基和氨基的有机化合物或氧化胺化合物，具有羧基的有机酸和水。
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公开(公告)号：US08998397B2
公开(公告)日：2015-04-07
申请号：US13530504
申请日：2012-06-22
申请人： Yasuhito Mori , Tomohiro Yamashita
发明人： Yasuhito Mori , Tomohiro Yamashita
IPC分类号： B41J2/01 , C09D11/38 , B41J2/21 , C09D11/322
CPC分类号： C09D11/38 , B41J2/2107 , C09D11/322
摘要： The invention provides an ink that inhibits lowering of ejection stability caused by a precipitate derived from a self-dispersible type monoazo pigment and also inhibits deterioration of a liquid contact surface of a heater portion of a recording head. The ink is an ink for ink jet recording system employing an thermal energy, containing a monoazo pigment, a resin and a surfactant represented by the following formula (1). A proportion of a molecular weight of an ethylene oxide group moiety occupying the surfactant is 10% or more and 85% or less, the monoazo pigment is a self-dispersible pigment to the particle surface of which at least one hydrophilic group selected from the group consisting of —COOM, —SO3M, —PO3HM and —PO3M2 is bonded directly or through another atomic group, and the acid value of the resin is 240 mg KOH/g or less.
摘要翻译： 本发明提供了抑制由自分散型单偶氮颜料衍生的沉淀物引起的喷射稳定性的降低的油墨，并且还抑制了记录头的加热器部分的液体接触表面的劣化。 油墨是使用含有单偶氮颜料，树脂和由下式（1）表示的表面活性剂的热能的喷墨记录系统的油墨。 占该表面活性剂的环氧乙烷基部分的分子量的一个比例为10％以上且85％以下，单偶氮颜料是粒子表面的自分散颜料，其中至少一个亲水基团选自基团 由-COOM，-SO3M，-PO3HM和-PO3M2构成的物质直接或通过另一原子团键合，树脂的酸值为240mgKOH / g以下。
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5.发明授权Liquid composition, set, liquid cartridge, inkjet recording method, and inkjet recording apparatus 有权液体组合物，组合物，液体盒，喷墨记录方法和喷墨记录装置公开(公告)号：US08740370B2
公开(公告)日：2014-06-03
申请号：US12874964
申请日：2010-09-02
IPC分类号： C09D11/00
摘要： A liquid composition used in combination with an ink containing a coloring material is ejected by the action of thermal energy from a recording head including a heating resistor having a protecting layer that is to come into contact with the liquid composition and that contains at least one of a metal and a metal oxide. The liquid composition contains at least either an organic compound having a carboxy group and an amino group or an amine oxide compound, an organic acid having a carboxy group, and water.
摘要翻译： 与含有着色材料的油墨组合使用的液体组合物通过来自包括具有与液体组合物接触的保护层的加热电阻器的记录头的热能的作用喷射，并且包含至少一种 金属和金属氧化物。 液体组合物至少含有具有羧基和氨基的有机化合物或氧化胺化合物，具有羧基的有机酸和水。
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公开(公告)号：US20120268532A1
公开(公告)日：2012-10-25
申请号：US13442279
申请日：2012-04-09
CPC分类号： C09D11/322 , C09D11/326
摘要： Provided is an ink jet ink including a monoazo pigment and a resin, the ink being used for an ink jet recording system in which the ink is ejected from a recording head by an action of thermal energy. The monoazo pigment is a self-dispersible pigment having an anionic group bonded to a particle surface of the pigment directly or via another atomic group and has a surface charge amount of 5.9×10−2 mmol/g or more and 9.8×10−2 mmol/g or less. The resin has an acid value of 100 mg KOH/g or more and 160 mg KOH/g or less. The mass ratio of the content (mass %) of the resin to the content (mass %) of the monoazo pigment in the ink is 0.05 times or more and 0.25 times or less.
摘要翻译： 提供了一种包括单偶氮颜料和树脂的喷墨油墨，该油墨用于喷墨记录系统，其中通过热能从记录头喷射油墨。 单偶氮颜料是具有阴离子基团的自分散颜料，其直接或通过另一个原子基团与颜料的颗粒表面键合，并且表面带电量为5.9×10 -2 mmol / g以上至9.8×10 -2 mmol / g以下。 该树脂的酸值为100mg KOH / g以上且160mgKOH / g以下。 树脂的含量（质量％）与油墨中单偶氮颜料的含量（质量％）的质量比为0.05倍以上且0.25倍以下。
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公开(公告)号：US20080278552A1
公开(公告)日：2008-11-13
申请号：US12101910
申请日：2008-04-11
IPC分类号： B41J2/175
CPC分类号： B41J2/17556 , C09D11/30
摘要： An ink jet recording ink tank includes: an ink retention member, which to hold ink exerts a negative pressure through capillary force; and ink, which is retained in the ink retention member, for which a dynamic surface tension in a lifetime of 50 msec, obtained by a maximum bubble pressure method, is higher than an interfacial tension of the ink retention member, a dynamic surface tension in a lifetime of 5000 msec is lower than the interfacial tension of the ink retention member, and a difference between the dynamic surface tension in the lifetime of 50 msec and the dynamic surface tension in the lifetime of 5000 msec is equal to or greater than 8 mN/m.
摘要翻译： 喷墨记录墨水盒包括：保持墨水的墨水保持部件通过毛细管力施加负压; 并且通过最大气泡压力法获得的寿命为50毫秒的动态表面张力保留在油墨保留构件中的油墨高于油墨保持构件的界面张力，动态表面张力 5000毫秒的寿命低于墨水保持构件的界面张力，并且在50msec的寿命期间的动态表面张力与5000msec的寿命期间的动态表面张力之差等于或大于8mN / m。
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公开(公告)号：US20120268521A1
公开(公告)日：2012-10-25
申请号：US13440342
申请日：2012-04-05
申请人： Kenji Moribe , Yasuhito Mori
发明人： Kenji Moribe , Yasuhito Mori
CPC分类号： C09D11/54 , B41J2/01 , B41J2/2107 , C09D11/322
摘要： A set of an ink containing a pigment dispersed by a water-soluble resin and having the surface tension of 38 mN/m or less and a reaction liquid containing a polyvalent metal ion and a surfactant, which is an ethylene oxide adduct of a higher alcohol of a linear primary or secondary alcohol or an isoalkyl alcohol, and has a HLB value of 13.0 or more as determined by the Griffin method. The content of the polyvalent metal ion in the reaction liquid is 10.0 times or more in terms of molar ratio as much as an amount of an acidic group derived from the water-soluble resin in the ink and the content of the surfactant in the reaction liquid is 0.15 times or more in terms of mass ratio as much as the total content of the pigment and water-soluble resin in the ink.
摘要翻译： 一组含有由水溶性树脂分散的表面张力为38mN / m以下的颜料的油墨和含有多价金属离子和表面活性剂的反应液，其是高级醇的环氧乙烷加合物 的线性伯醇或仲醇或异烷醇，并且具有通过格里芬法测定的HLB值为13.0以上。 反应液中的多价金属离子的含量相对于油墨中的水溶性树脂衍生的酸性基团的摩尔比和反应液中的表面活性剂的含量的摩尔比为10.0倍以上 与油墨中的颜料和水溶性树脂的总含量一样多的质量比为0.15倍以上。
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公开(公告)号：US20110141190A1
公开(公告)日：2011-06-16
申请号：US12950623
申请日：2010-11-19
申请人： Kenji Moribe , Mikio Sanada , Yasuhito Mori , Junichi Sakai
发明人： Kenji Moribe , Mikio Sanada , Yasuhito Mori , Junichi Sakai
CPC分类号： C09D11/40 , C09D11/324 , C09D11/326 , C09D11/54
摘要： Provided is a set of a reaction liquid that has a buffering action against pH change and exhibits a pH of 3.5 or more and 5.5 or less, and an ink that has a higher pH than the reaction liquid. The ink comprises a pigment to a surface of a pigment particle of which a basic group that forms a cation form at the pH of the reaction liquid is bonded. The pigment does not have an acidic group having a pKa equal to or less than the pH of the reaction liquid. The pigment is dispersed by a water-soluble polymer that has an acidic group having a pKa equal to or more than the pH of the reaction liquid and equal to or less than the pH of the ink.
摘要翻译： 提供一组反应液，其具有抗pH变化的缓冲作用，并且pH为3.5以上且5.5以下，并且具有比反应液高的pH的墨。 油墨包含颜料到颜料颗粒的表面，其中在反应液体的pH下形成阳离子形式的碱性基团结合。 颜料不具有pKa等于或小于反应液pH的酸性基团。 颜料由具有pKa等于或大于反应液的pH等于或小于墨水pH值的酸性基团的水溶性聚合物分散。
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公开(公告)号：US08783843B2
公开(公告)日：2014-07-22
申请号：US13440342
申请日：2012-04-05
申请人： Kenji Moribe , Yasuhito Mori
发明人： Kenji Moribe , Yasuhito Mori
CPC分类号： C09D11/54 , B41J2/01 , B41J2/2107 , C09D11/322
摘要： A set of an ink containing a pigment dispersed by a water-soluble resin and having the surface tension of 38 mN/m or less and a reaction liquid containing a polyvalent metal ion and a surfactant, which is an ethylene oxide adduct of a higher alcohol of a linear primary or secondary alcohol or an isoalkyl alcohol, and has a HLB value of 13.0 or more as determined by the Griffin method. The content of the polyvalent metal ion in the reaction liquid is 10.0 times or more in terms of molar ratio as much as an amount of an acidic group derived from the water-soluble resin in the ink and the content of the surfactant in the reaction liquid is 0.15 times or more in terms of mass ratio as much as the total content of the pigment and water-soluble resin in the ink.
摘要翻译： 一组含有由水溶性树脂分散的表面张力为38mN / m以下的颜料的油墨和含有多价金属离子和表面活性剂的反应液，其是高级醇的环氧乙烷加合物 的线性伯醇或仲醇或异烷醇，并且具有通过格里芬法测定的HLB值为13.0以上。 反应液中的多价金属离子的含量相对于油墨中的水溶性树脂衍生的酸性基团的摩尔比和反应液中的表面活性剂的含量的摩尔比为10.0倍以上 与油墨中的颜料和水溶性树脂的总含量一样多的质量比为0.15倍以上。
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