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    Method for producing semicarbazones
    1.
    发明授权
    Method for producing semicarbazones 有权
    缩氨基脲的制备方法

    公开(公告)号：US07795465B2

    公开(公告)日：2010-09-14

    申请号：US10592271

    申请日：2005-03-16

    Applicant: Thomas Zierke ,  Stefan Engel ,  Peter Otto

    Inventor： Thomas Zierke ,  Stefan Engel ,  Peter Otto

    IPC: C07C253/30 ,  C07C281/06

    CPC classification number: C07C281/14

    Abstract: The invention relates to a process for preparing semicarbazone compounds of the formula I, where R1 and R2 are each independently hydrogen, halogen, CN, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, and R3 is C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, by reacting a hydrazone compound of the general formula II, where R is C1-C4-alkoxy, amino, C1-C4-alkylamino or di(C1-C4-alkyl)amino, and R1, R2 are each as defined above, with an aniline compound of the general formula III where R3 is as defined above.

    Abstract translation: 本发明涉及一种制备式I的缩氨基脲化合物的方法，其中R 1和R 2各自独立地为氢，卤素，CN，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷基或C 1 -C 4 - 卤代烷氧基和R 3是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基，通过使通式II的腙化合物，其中R是C 1 -C 4 - 烷氧基，氨基，C 1 -C 4 - 烷基氨基 或二（C 1 -C 4 - 烷基）氨基，并且R 1，R 2各自如上所定义，与通式III的苯胺化合物反应，其中R 3如上定义。

    Process for the Isomerization of Semicarbazone Compounds
    2.
    发明申请
    Process for the Isomerization of Semicarbazone Compounds 审中-公开
    缩氨基脲化合物异构化方法

    公开(公告)号：US20110105794A1

    公开(公告)日：2011-05-05

    申请号：US13001063

    申请日：2009-06-22

    Applicant: Thomas Zierke ,  Stefan Engel

    Inventor： Thomas Zierke ,  Stefan Engel

    IPC: C07C237/18

    CPC classification number: C07C281/14

    Abstract: The present invention relates to a process for the isomerization of the Z-isomer I-Z of a semicarbazone compound of the general formula (I) into its E-isomer I-E wherein the variables in formula (I) have the meanings as defined in the description.

    Abstract translation: 本发明涉及将通式（I）的缩氨基脲化合物的Z-异构体I-Z异构化为其E-异构体I-E的方法，其中式（I）中的变量具有如说明书中所定义的含义。

    Method For Producing Semicarbazones
    3.
    发明申请
    Method For Producing Semicarbazones 有权
    生产缩氨基脲的方法

    公开(公告)号：US20070203356A1

    公开(公告)日：2007-08-30

    申请号：US10592271

    申请日：2005-03-16

    Applicant: Thomas Zierke ,  Stefan Engel ,  Peter Otto

    Inventor： Thomas Zierke ,  Stefan Engel ,  Peter Otto

    IPC: C07C281/06

    CPC classification number: C07C281/14

    Abstract: The invention relates to a process for preparing semicarbazone compounds of the formula I, where R1 and R2 are each independently hydrogen, halogen, CN, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, and R3 is C1-C4-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, by reacting a hydrazone compound of the general formula II, where R is C1-C4-alkoxy, amino, C1-C4-alkylamino or di(C1-C4-alkyl)amino, and R1, R2 are each as defined above, with an aniline compound of the general formula III where R3 is as defined above.

    Abstract translation: 本发明涉及一种制备式I的缩氨基脲化合物的方法，其中R 1和R 2各自独立地为氢，卤素，CN，C 1， C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 3 - 烷基，C 1 -C 4 - C 1 -C 4烷基或C 1 -C 4 - 卤代烷氧基，R 3是C 1 - C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基或C 1 -C 3 通过使通式II的腙化合物反应，其中R是C 1 -C 4 - 烷氧基，氨基，C

    Ink reservoir for automatic recording, writing, and drawing devices
    5.
    发明申请
    Ink reservoir for automatic recording, writing, and drawing devices 审中-公开
    用于自动记录，写入和绘图设备的墨水盒

    公开(公告)号：US20060055749A1

    公开(公告)日：2006-03-16

    申请号：US11229048

    申请日：2005-09-16

    Applicant: Rainer Schuster ,  Stefan Engel

    Inventor： Rainer Schuster ,  Stefan Engel

    IPC: B41J2/175

    CPC classification number: B41J2/17556 ,  B41J2/17513 ,  B41J2/17523 ,  B41J2002/17516

    Abstract: An ink reservoir or tank for automatic recording, writing, and drawing devices, particularly ink-jet systems, such as printers and plotters, wherein a sleeve or bandage is arranged within the ink reservoir. The ink pouch and the printing device are entirely or partially surrounded by the sleeve or bandage. In addition, the sleeve or bandage is constructed with respect to shape and dimensions in such a way that a free space exists between the outer wall of the sleeve or bandage and the inner side of the housing wall of the ink reservoir.

    Abstract translation: 用于自动记录，书写和绘图装置的墨水储存器或储存器，特别是诸如打印机和绘图仪的喷墨系统，其中套筒或绷带布置在墨水储存器内。 墨水袋和打印装置被套筒或绷带完全或部分地包围。 此外，套筒或绷带相对于形状和尺寸被构造成使得在套筒或绷带的外壁和储墨器的壳体壁的内侧之间存在自由空间。

    Ink base for pigmented inks, inks manufactured therefrom and their use
    6.
    发明授权
    Ink base for pigmented inks, inks manufactured therefrom and their use 失效
    用于着色油墨的油墨基底，由其制造的油墨及其用途

    公开(公告)号：US06884287B2

    公开(公告)日：2005-04-26

    申请号：US10717060

    申请日：2003-11-19

    Applicant: Anke Müller ,  Manuela Geis ,  Stefan Engel

    Inventor： Anke Müller ,  Manuela Geis ,  Stefan Engel

    IPC: B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/02 ,  C09D17/00

    CPC classification number: C09D17/002

    Abstract: An ink base for producing pigmented inks having a water base contains a drying retarder and a pH adjusting agent. The drying retarder contains at least diethylene glycol, 1,6-hexane diol, and pentaerythritol. The pH adjusting agent (PH) contains at least one amine. The ink base contains at least 30.0-95.5% by wt. diethylene glycol; 3.0-40.0% by wt. 1,6-hexane diol; 0.01-3.0% by wt. pentaerythritol; and 1.5-15.0% by wt. amine(s).

    Abstract translation: 用于生产具有水基的着色油墨的油墨基底含有干燥缓凝剂和pH调节剂。 干燥缓凝剂至少含有二甘醇，1,6-己二醇和季戊四醇。 pH调节剂（PH）含有至少一种胺。 油墨基质含有至少30.0-95.5重量％。 二甘醇 3.0-40.0重量％ 1,6-己二醇; 0.01-3.0重量％ 季戊四醇 和1.5〜15.0重量％。 胺。

    2-benzoylcyclohexane-1,3-dione as herbicides
    7.
    发明授权
    2-benzoylcyclohexane-1,3-dione as herbicides 有权
    2-苯甲酰基环己烷-1,3-二酮作为除草剂

    公开(公告)号：US06432881B1

    公开(公告)日：2002-08-13

    申请号：US09485231

    申请日：2000-02-07

    Applicant: Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    Inventor： Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC: C07D23112

    CPC classification number: A01N43/56 ,  C07D207/20 ,  C07D303/22 ,  C07D305/06 ,  C07D307/28 ,  C07D333/16

    Abstract: 2-Benzoylcyclohexane-1,3-diones of formula I : where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxy, alkenyl, alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3 (n=0, 1, 2), —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen or optionally substituted alkyl, haloalkyl, alkenyl, alkynyl, phenyl or phenylalkyl; Q is optionally substituted cyclohexane-2-yl-1,3-dione; X1 is optionally substituted alkylene, propenylene, alkenylene or alkynylene; R4 is hydrogen or optionally substituted alkyl, alkenyl, alkynyl, phenyl, phenylalkyl; Het is a three- to six-membered, optionally substituted heterocyclic or heteroaromatic group; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of formula I, compositions comprising them, and the use of the compounds of formula I and the compositions comprising them for controlling harmful plants are described.

    Abstract translation: 式I的2-苯甲酰基环己烷-1,3-二酮其中：R1和R2各自为氢，巯基，硝基，卤素，氰基，氰硫基，烷基，卤代烷基，烷氧基，烯基，炔基，-OR3，-OCOR3，-OSO2R3 ，-S（O）n R 3（n = 0,1,2），-SO 2 OR 3，-SO 2 N（R 3）2，-NR 3 SO 2 R 3或-NR 3 COR 3; R 3是氢或任选取代的烷基，卤代烷基，烯基，炔基，苯基或苯基 Q是任选取代的环己烷-2-基-1,3-二酮; X 1是任选取代的亚烷基，亚丙烯基，亚烯基或亚炔基; R 4是氢或任选取代的烷基，烯基，炔基，苯基，苯基烷基; 至六元，任选取代的杂环或杂芳族基团;及其农业上有用的盐，制备式I化合物的方法和中间体，包含它们的组合物，以及式I化合物及其组合物用于控制有害植物的用途 被描述。

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