公开(公告)号：US07148000B2

公开(公告)日：2006-12-12

申请号：US10126977

申请日：2002-04-22

Applicant: Takayoshi Oyamada ,  Kouta Fukui ,  Toyohisa Oya

Inventor： Takayoshi Oyamada ,  Kouta Fukui ,  Toyohisa Oya

IPC: G03C1/498

CPC classification number: G03C1/49809 ,  G03C1/0051 ,  G03C1/061 ,  G03C1/49827 ,  G03C1/49845 ,  G03C1/49881 ,  G03C7/30541 ,  G03C2001/0157 ,  G03C2001/03594 ,  G03C2200/60

Abstract: The present invention is directed to a heat-developable photosensitive material and an image-forming process using the heat-developable photosensitive material. The material generally includes at least one photosensitive silver halide, a reducing agent for silver ions, a binder, and non-photosensitive organic silver salt particles on one surface of a support. The non-photosensitive organic silver salt particles are specified and the reducing agent is specified. The material may include specific non-photosensitive organic silver salt particles and a development accelerator.

公开(公告)号：US06924089B2

公开(公告)日：2005-08-02

申请号：US10209260

申请日：2002-08-01

Applicant: Toyohisa Oya ,  Hirokazu Kyota ,  Kouta Fukui

Inventor： Toyohisa Oya ,  Hirokazu Kyota ,  Kouta Fukui

IPC: G03C1/498

CPC classification number: G03C1/498 ,  G03C1/49827 ,  G03C1/49845

Abstract: An object of the present invention is to provide a novel heat-developable photosensitive material which hardly exerts an influence on the image color tone and exhibits high sensitivity.Disclosed is a heat-developable photosensitive material comprises, on the same surface of a substrate, at least (a) photosensitive silver halide, (b) a reducible silver salt, (c) a compound represented by the general formula (5), (d) a binder, (e) a compound represented by the general formula (6) or (7), and (f) a compound represented by the general formula (3).

Abstract translation: 本发明的目的是提供一种几乎不对图像色调产生影响并显示出高灵敏度的新型热显影感光材料。 公开了一种热显影感光材料，其在基材的相同表面上至少包含（a）感光卤化银，（b）可还原银盐，（c）由通式（5）表示的化合物，（ d）粘合剂，（e）由通式（6）或（7）表示的化合物，和（f）由通式（3）表示的化合物。

公开(公告)号：US07229753B2

公开(公告)日：2007-06-12

申请号：US09809178

申请日：2001-03-16

Applicant: Toyohisa Oya ,  Kouta Fukui ,  Yasuhiro Yoshioka ,  Kazunobu Katoh

Inventor： Toyohisa Oya ,  Kouta Fukui ,  Yasuhiro Yoshioka ,  Kazunobu Katoh

IPC: G03C1/498

CPC classification number: G03C1/49827 ,  G03C1/061 ,  G03C1/49845 ,  Y10S430/166

Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following general formula (1), and (d) a binder: Q1—NHNH—R1:   Formula (1) wherein, in the general formula (1), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—R1 at a carbon atom, and R1 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group, provided that when R1 is propylcarbamoyl group, Q1 is not 2,3,5,6-tetrachloro-4-cyanophenyl group. According to the present invention, there is provided a novel photothermographic materials showing high sensitivity, high development speed and little fluctuation of performance due to heat development temperature variation.

Abstract translation: 一种光热成像材料，其至少包含（a）光敏卤化银，（b）可还原的银盐，（c）由以下通式（1）表示的还原化合物和（d）粘合剂： -formulae description =“In-line Formulas”end =“lead”？> Q <1> -NHNH-R 1：式（1）<？ 其中，在通式（1）中，Q 1表示与NHNH-R键合的5至7元不饱和环， SUP> 1，R 1表示氨基甲酰基，酰基，烷氧基羰基，芳氧基羰基，磺酰基或氨磺酰基，条件是当 R 1是丙基氨基甲酰基，Q 1不是2,3,5,6-四氯-4-氰基苯基。 根据本发明，提供了一种新型光热敏成像材料，其显示出高灵敏度，高显影速度，并且由于显影温度变化而导致性能波动小。

公开(公告)号：US20060057508A1

公开(公告)日：2006-03-16

申请号：US11221743

申请日：2005-09-09

Applicant: Kouta Fukui ,  Takayoshi Oyamada

Inventor： Kouta Fukui ,  Takayoshi Oyamada

IPC: G03C5/16

CPC classification number: G03C1/49872 ,  G03C1/49809 ,  G03C1/49881 ,  G03C2001/7635 ,  G03C2200/35 ,  G03C2200/52

Abstract: An image forming method using a photothermographic material including, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a first non-photosensitive organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer disposed on the same side as the image forming layer and farther from the support than the image forming layer, wherein the non-photosensitive layer contains a second organic silver salt which is different from the first non-photosensitive organic silver salt, and the photothermographic material is thermally developed for 3 seconds to 20 seconds after imagewise exposure. An image forming method with excellent resistance to stain before exposure, raw stock storability, and resistance to defects after processing is provided.

Abstract translation: 一种使用光热敏成像材料的图像形成方法，该光热敏成像材料在载体的至少一侧包括至少含有感光卤化银，第一非感光性有机银盐，还原剂和粘合剂的图像形成层， 至少一个非感光层设置在与图像形成层相同的一侧并且比图像形成层更远离支撑体，其中非感光层含有与第一非光敏有机银不同的第二有机银盐 盐，并且光成像材料在成像曝光后热显影3秒至20秒。 提供了一种在曝光前具有优异的耐污染性，原料储存性和加工后的缺陷耐性的成像方法。

公开(公告)号：US20070031767A1

公开(公告)日：2007-02-08

申请号：US11494743

申请日：2006-07-28

Applicant: Takayoshi Oyamada ,  Kouta Fukui ,  Itsuo Fujiwara

Inventor： Takayoshi Oyamada ,  Kouta Fukui ,  Itsuo Fujiwara

IPC: G03C1/00

CPC classification number: G03C1/49872 ,  G03C1/49818 ,  G03C2001/7635 ,  G03C2007/3025 ,  G03C2200/36

Abstract: The present invention provides a photothermographic material having, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a first reducing agent for silver ions, and a first binder, and a non-photosensitive outermost layer which is disposed on the same side of the support as the side having thereon the image forming layer, wherein the photothermographic material further has a non-photosensitive intermediate layer A between the image forming layer and the outermost layer, and the non-photosensitive intermediate layer A includes at least a second reducing agent for silver ions and a second binder. A photothermographic material which gives an image with high image quality and has improved film physical properties is provided.

Abstract translation: 本发明提供一种光热敏成像材料，其在载体的至少一侧上具有至少包含感光卤化银，非光敏有机银盐，银离子的第一还原剂和第一粘合剂的成像层 ，以及设置在与其上具有图像形成层的一侧的支撑体的相同侧上的非光敏最外层，其中光热敏成像材料在图像形成层和最外层之间还具有非感光中间层A ，非感光性中间层A至少包含第二种银离子还原剂和第二粘合剂。 提供了具有高图像质量并且具有改善的膜物理性质的图像的光热照相材料。

公开(公告)号：US20080076078A1

公开(公告)日：2008-03-27

申请号：US11898748

申请日：2007-09-14

Applicant: Kouta Fukui

Inventor： Kouta Fukui

IPC: G03C1/06

CPC classification number: G03C1/49827 ,  G03C1/49845 ,  G03C1/49863 ,  G03C7/32 ,  G03C2200/36 ,  Y10S430/165

Abstract: The present invention provides a black and white photothermographic material having, on at least one side of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, and a reducing agent for silver ions, wherein the reducing agent for silver ions is a compound represented by the following formula (PP) and having a molecular weight of from 450 to 3000, and the black and white photothermographic material further comprises a compound represented by the following formula (II).

Abstract translation: 本发明提供一种黑色和白色光热敏成像材料，其至少在支持体一侧具有至少一种感光卤化银，非光敏有机银盐和用于银离子的还原剂，其中银还原剂 离子是由下式（PP）表示的化合物，分子量为450〜3000，黑白光热敏成像材料还含有下述式（II）表示的化合物。

公开(公告)号：US20070196779A1

公开(公告)日：2007-08-23

申请号：US11657472

申请日：2007-01-25

Applicant: Kouta Fukui ,  Katsuhisa Ohzeki ,  Yasuaki Deguchi ,  Yasuhiro Yoshioka

Inventor： Kouta Fukui ,  Katsuhisa Ohzeki ,  Yasuaki Deguchi ,  Yasuhiro Yoshioka

IPC: G03C1/00

CPC classification number: G03C1/49818 ,  G03C1/49827 ,  G03C1/49863 ,  G03C5/02 ,  G03C7/3041 ,  G03C7/344 ,  G03C7/346 ,  G03C7/36 ,  G03C7/383 ,  G03C7/3835 ,  G03C7/384 ,  G03C2007/3025 ,  G03C2200/36

Abstract: The present invention provides a black and white photothermographic material including, on at least one side of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, a color developing agent, and a coupler which reacts with an oxidation product of the color developing agent to form a dye, wherein a total amount of ammonia included on one side of the support having thereon the photosensitive silver halide is from 5 mg/m2 to 25 mg/m2, and an optical density of an image formed by imagewise exposing and thermally developing the black and white photothermographic material satisfies the following equation (A): 0.02

Abstract translation: 本发明提供黑色和白色光热敏成像材料，其至少在支持体一侧包括感光卤化银，非感光性有机银盐，银离子还原剂，彩色显影剂和 成色剂与彩色显影剂的氧化产物反应形成染料，其中在其上具有光敏卤化银的载体的一侧上包含的氨的总量为5mg / m 2 至25mg / m 2，并且通过成像曝光和热显影黑白光热敏成像材料形成的图像的光密度满足以下等式（A）：<？在线公式描述 =“在线公式”end =“lead”？> 0.02 其中D表示 光密度在1至2范围内，Dc表示通过染料在光密度中获得的光密度 图像的ity。

公开(公告)号：US07132229B2

公开(公告)日：2006-11-07

申请号：US11179766

申请日：2005-07-13

Applicant: Kouta Fukui

Inventor： Kouta Fukui

IPC: G03C1/00

CPC classification number: G03C1/49845 ,  G03C2200/33 ,  Y10S430/165

Abstract: A photothermographic material having an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and a non-photosensitive layer on at least one side of a support, in which the binder is a hydrophilic binder, the non-photosensitive layer contains gelatin or a gelatin derivative, the reducing agent is a compound represented by the following formula (R), and at least one compound represented by the following formula (I) or (II) is contained: (wherein in formula (R), R11 and R11′ each independently represent an alkyl group and at least one of R11 and R11′ is a secondary or tertiary alkyl group); (wherein in the formula (I), Q represents an atomic group necessary for forming a 5 or 6-membered imide ring); and (wherein in the formula (II), R5 independently represents a hydrogen atom or a substituent, r represents 0, 1, 2, 3 or 4, and X represents O, S, Se or N(R6)). A photothermographic material that is excellent in coated surface state and has high image quality, and an image forming method are provided.

Abstract translation: 一种具有至少含有感光卤化银，非感光性有机银盐，还原剂和粘合剂的图像形成层和在支撑体的至少一侧上的非感光层的光热敏成像材料，其中， 粘合剂是亲水性粘合剂，非感光层含有明胶或明胶衍生物，还原剂为下式（R）表示的化合物，和至少一种下式（I）或（II）表示的化合物， 含有：（式中，R 11，R 11和R 11'各自独立地表示烷基，R 11〜 >和R 11'是仲或叔烷基）; （式（I）中，Q表示形成5或6元酰亚胺环所必需的原子团）; 式（II）中，R 5独立地表示氢原子或取代基，r表示0,1,2,3或4，X表示O，S，Se或N （R 6））。 提供了具有优异的涂布表面状态并且具有高图像质量的光热敏成像材料和图像形成方法。

公开(公告)号：US20050202356A1

公开(公告)日：2005-09-15

申请号：US11072531

申请日：2005-03-07

Applicant: Kouta Fukui

Inventor： Kouta Fukui

IPC: G03C1/498 ,  G03C1/00 ,  G03C1/76

CPC classification number: G03C1/49809 ,  G03C1/49863

Abstract: The invention provids a black-and-white photothermographic material comprising a support and an image-forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder on one side of the support, wherein a hydrophilic binder constitutes 50 mass % or more of the binder. The non-photosensitive organic silver salt contains at least one kind selected from the group consisting of a silver salt of a nitrogen-containing heterocyclic compound and a silver salt of a mercapto compound. The photothermographic material comprises a fluorine compound having a fluorinated alkyl group with at least 2 carbon atoms and at most 12 fluorine atoms.

Abstract translation: 本发明提供一种黑白光热敏成像材料，其包括载体和含有感光卤化银，非感光性有机银盐，银离子还原剂和载体一侧的粘合剂的图像形成层 其中亲水性粘合剂构成粘合剂的50质量％以上。 非感光性有机银盐含有选自含氮杂环化合物的银盐和巯基化合物的银盐中的至少一种。 光热成像材料包括具有至少2个碳原子和至多12个氟原子的氟化烷基的氟化合物。

公开(公告)号：US06274302B1

公开(公告)日：2001-08-14

申请号：US09311580

申请日：1999-05-14

Applicant: Katsuyuki Watanabe ,  Kouta Fukui

Inventor： Katsuyuki Watanabe ,  Kouta Fukui

IPC: G03C1498

CPC classification number: G03C1/49845 ,  G03C1/061 ,  G03C1/49836 ,  G03C1/49863 ,  G03C2200/36

Abstract: A photothermographic element comprising on a support (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent, (d) an ultrahigh contrast-providing agent, (e) a binder, (f) a specific salicylic acid type antifoggant, and optionally (g) phosphoric acid or a salt thereof has a low fog, high sensitivity, high contrast, and storage stability.

Abstract translation: 一种光热敏成像元件，其包含支撑体（a）感光卤化银，（b）可还原银盐，（c）还原剂，（d）超高对比度提供剂，（e）粘合剂，（f） 特别是水杨酸型防灰雾剂，和（g）磷酸或其盐具有低雾度，高灵敏度，高对比度和储存稳定性。