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公开(公告)号:US09391318B2
公开(公告)日:2016-07-12
申请号:US13941253
申请日:2013-07-12
发明人: Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
CPC分类号: H01M4/366 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/16 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要: Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.
摘要翻译: 提供活性物质颗粒,其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构,其具有二次粒子,其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分,以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。
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公开(公告)号:US10516165B2
公开(公告)日:2019-12-24
申请号:US15918956
申请日:2018-03-12
发明人: Hiroyuki Toya , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
IPC分类号: H01M4/505 , C01G53/00 , H01M4/131 , H01M4/525 , H01M10/052
摘要: An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same. A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.
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公开(公告)号:US20180205080A1
公开(公告)日:2018-07-19
申请号:US15918956
申请日:2018-03-12
发明人: Hiroyuki TOYA , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
IPC分类号: H01M4/505 , H01M10/052 , H01M4/525 , H01M4/131 , C01G53/00
摘要: An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution] A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.
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