-
公开(公告)号:US10143201B2
公开(公告)日:2018-12-04
申请号:US15476303
申请日:2017-03-31
发明人: Hans Tobler , Harald Walter , Ulrich Johannes Haas
IPC分类号: A01N43/56 , A01N43/50 , A01N55/00 , A01N43/40 , A01N43/54 , A01N43/653 , A01N43/84 , A01N57/20
摘要: A composition suitable for control of diseases caused by phytopathogens comprising (A) a compound of formula I wherein R1 is difluoromethyl or trifluoromethyl and X is chloro, fluoro or bromo; and (B) at least one compound selected from compounds known for their fungicidal activity; and a method of controlling diseases on useful plants, especially rust diseases on soybean plants.
-
公开(公告)号:US09878970B1
公开(公告)日:2018-01-30
申请号:US15717327
申请日:2017-09-27
IPC分类号: C07C22/02 , C07C22/04 , C07C205/06 , C07C205/11 , C07C205/12 , C07C17/32 , C07C17/266 , C07C209/36 , C07C17/23 , C07C17/26 , C07C201/12
CPC分类号: C07C17/32 , C07C17/23 , C07C17/26 , C07C17/266 , C07C22/02 , C07C22/04 , C07C201/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C209/365 , C07C2601/10 , C07C2603/66 , C07C211/61
摘要: The present invention relates to a novel a process for the preparation of 9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-ylamine which process comprises a) reacting cyclopentadiene in the presence of a radical initiator and CXCl3, wherein X is chloro or bromo, to a compound of formula I1, or aa) reacting cyclopentadiene with CXCl3, wherein X is chloro, in the presence of a metal catalyst to a compound of formula I1, wherein X is chloro, b) reacting the compound of formula I1 with a base in the presence of an appropriate solvent to the compound of formula III, c) and converting the compound of formula III in the presence of 1,2-dehydro-6-nitrobenzene to the compound of formula IV, and d) hydrogenating the compound of formula IV in the presence of a metal catalyst.
-
公开(公告)号:US20130253225A1
公开(公告)日:2013-09-26
申请号:US13889041
申请日:2013-05-07
发明人: Hans Tobler , Harald Walter , Josef Ehrenfreund , Camilla Corsi , Fanny Giordano , Martin Zeller , Gottfried Seifert , Shailesh Shah , Neil George , Ian Jones , Paul Bonnett
IPC分类号: C07C211/61 , C07C209/32 , C07C205/06
CPC分类号: C07C211/61 , A01N43/56 , C07C205/06 , C07C209/325 , C07C209/70 , C07C2603/66 , C07D231/14
摘要: The present invention relates to a process for the preparation of compounds of formula I wherein R1 and R2 are each independently of the other hydrogen or C1-C5alkyl and R3 is CF3 or CF2H, by a) reaction of a compound of formula II wherein R1 and R2 are as defined for formula I, with at least one reducing agent to form a compound of formula III wherein R1 and R2 are as defined for formula I, and b) reaction of that compound with at least one reducing agent to form a compound of formula IV wherein R1 and R2 are as defined for formula I, and (c) reaction of that compound with a compound of formula V wherein Q is chlorine, fluorine, bromine, iodine, hydroxy or C1-C6alkoxy and R3 is as defined for formula I, to form the compound of formula I; and to novel intermediates for use in that process.
摘要翻译: 本发明涉及一种制备式Ⅰ化合物的方法,其中R1和R2分别独立地为氢或C1-C5烷基,R3为CF3或CF2H,通过a)式II化合物的反应其中R 1和 R 2如式I所定义,与至少一种还原剂形成式III化合物,其中R 1和R 2如式I所定义,和b)该化合物与至少一种还原剂的反应形成式 式IV其中R1和R2如式I所定义,和(c)该化合物与式V化合物的反应,其中Q是氯,氟,溴,碘,羟基或C 1 -C 6烷氧基,R 3如式 I,形成式I化合物; 以及用于该过程的新型中间体。
-
公开(公告)号:US11102977B2
公开(公告)日:2021-08-31
申请号:US16564912
申请日:2019-09-09
发明人: Harald Walter , Urs Neuenschwander , Ronald Zeun , Josef Ehrenfreund , Hans Tobler , Camilla Corsi , Clemens Lamberth
IPC分类号: A01N43/56 , A01N43/653 , A01N43/78 , A01N25/00 , A01N43/707 , A01N43/36
摘要: The invention relates to fungicidal compositions comprising as active ingredient a combination of components A) and B) as defined in the patent claims, to a method of controlling phytopathogenic diseases on crop plants using such a composition and to a method of protecting natural substances of vegetable and/or animal origin and/or their processed forms using such a composition.
-
公开(公告)号:US20200000092A1
公开(公告)日:2020-01-02
申请号:US16564912
申请日:2019-09-09
发明人: Harald Walter , Urs Neuenschwander , Ronald Zeun , Josef Ehrenfreund , Hans Tobler , Camilla Corsi , Clemens Lamberth
IPC分类号: A01N43/56 , A01N43/653 , A01N43/78 , A01N25/00 , A01N43/707 , A01N43/36
摘要: The invention relates to fungicidal compositions comprising as active ingredient a combination of components A) and B) as defined in the patent claims, to a method of controlling phytopathogenic diseases on crop plants using such a composition and to a method of protecting natural substances of vegetable and/or animal origin and/or their processed forms using such a composition.
-
公开(公告)号:US10405548B2
公开(公告)日:2019-09-10
申请号:US15953825
申请日:2018-04-16
发明人: Harald Walter , Urs Neuenschwander , Ronald Zeun , Josef Ehrenfreund , Hans Tobler , Camilla Corsi , Clemens Lamberth
IPC分类号: A01N43/56 , A01N43/78 , A01N25/00 , A01N43/36 , A01N43/653 , A01N43/707
摘要: The invention relates to fungicidal compositions comprising as active ingredient a combination of components A) and B) as defined in the patent claims, to a method of controlling phytopathogenic diseases on crop plants using such a composition and to a method of protecting natural substances of vegetable and/or animal origin and/or their processed forms using such a composition.
-
公开(公告)号:US20170202220A1
公开(公告)日:2017-07-20
申请号:US15476303
申请日:2017-03-31
发明人: Hans Tobler , Harald Walter , Ulrich Johannes Haas
IPC分类号: A01N43/56
CPC分类号: A01N43/56 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/653 , A01N43/84 , A01N55/00 , A01N57/20 , A01N37/34 , A01N37/36 , A01N43/36 , A01N2300/00
摘要: A composition suitable for control of diseases caused by phytopathogens comprising (A) a compound of formula I wherein R1 is difluoromethyl or trifluoromethyl and X is chloro, fluoro or bromo; and (B) at least one compound selected from compounds known for their fungicidal activity; and a method of controlling diseases on useful plants, especially rust diseases on soybean plants.
-
公开(公告)号:US09642365B2
公开(公告)日:2017-05-09
申请号:US15070238
申请日:2016-03-15
发明人: Hans Tobler , Harald Walter , Ulrich Johannes Haas
IPC分类号: A01N43/56 , A01N43/54 , A01N57/20 , A01N43/50 , A01N55/00 , A01N43/40 , A01N43/653 , A01N43/84
CPC分类号: A01N43/56 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/653 , A01N43/84 , A01N55/00 , A01N57/20 , A01N37/34 , A01N37/36 , A01N43/36 , A01N2300/00
摘要: A composition suitable for control of diseases caused by phytopathogens comprising (A) a compound of formula I wherein R1 is difluoromethyl or trifluoromethyl and X is chloro, fluoro or bromo; and (B) at least one compound selected from compounds known for their fungicidal activity; and a method of controlling diseases on useful plants, especially rust diseases on soybean plants.
-
公开(公告)号:US10575523B2
公开(公告)日:2020-03-03
申请号:US16167617
申请日:2018-10-23
发明人: Hans Tobler , Harald Walter , Ulrich Johannes Haas
IPC分类号: A01N43/56 , A01N37/34 , A01N43/50 , A01N55/00 , A01N43/40 , A01N43/54 , A01N43/653 , A01N43/84 , A01N57/20
摘要: A composition suitable for control of diseases caused by phytopathogens comprising (A) a compound of formula I wherein R1 is difluoromethyl or trifluoromethyl and X is chloro, fluoro or bromo; and (B) at least one compound selected from compounds known for their fungicidal activity; and a method of controlling diseases on useful plants, especially rust diseases on soybean plants.
-
公开(公告)号:US20150141712A1
公开(公告)日:2015-05-21
申请号:US14603857
申请日:2015-01-23
IPC分类号: C07C17/32 , C07C205/12
CPC分类号: C07C17/32 , C07C17/23 , C07C17/26 , C07C17/266 , C07C22/02 , C07C22/04 , C07C201/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C209/365 , C07C2601/10 , C07C2603/66 , C07C211/61
摘要: The present invention relates to a novel a process for the preparation of 9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-ylamine which process comprises a) reacting cyclopentadiene in the presence of a radical initiator and CXCl3, wherein X is chloro or bromo, to a compound of formula I1, or aa) reacting cyclopentadiene with CXCl3, wherein X is chloro, in the presence of a metal catalyst to a compound of formula I1, wherein X is chloro, b) reacting the compound of formula I1 with a base in the presence of an appropriate solvent to the compound of formula III, c) and converting the compound of formula III in the presence of 1,2-dehydro-6-nitrobenzene to the compound of formula IV, and d) hydrogenating the compound of formula IV in the presence of a metal catalyst.
摘要翻译: 本发明涉及一种制备9-二氯亚甲基-1,2,3,4-四氢-1,4-亚甲基 - 萘-5-基胺的新方法,该方法包括:a)使环戊二烯在 自由基引发剂和其中X是氯或溴的CXCl 3,或aa)在金属催化剂存在下将环戊二烯与CXCl 3(其中X是氯)与式II化合物反应,其中X是氯 b)使式I1化合物与碱在适当的溶剂存在下反应,得到式III化合物,c)并在1,2-脱氢-6-硝基苯存在下将式III化合物转化为 式Ⅳ化合物,和d)在金属催化剂存在下氢化式Ⅳ化合物。
-
-
-
-
-
-
-
-
-