摘要:
Compositions and methods for inhibiting polymerization of ethylenically unsaturated monomers are provided. The compositions include a water-soluble phenylenediamine composition.
摘要:
Compositions and methods for inhibiting polymerization of ethylenically unsaturated monomers are provided. The compositions include a water-soluble phenylenediamine composition.
摘要:
Method of inhibiting polymerization of alkenyl monomers comprising contacting the alkenyl monomers with: wherein R1 and R2 independently of one another are alkyl, phenyl, aryl, alkoxy, or carboxy groups; and oxygen. Mixture comprising: a) alkenyl monomers with: wherein R1 and R2 independently of one another are alkyl, phenyl, aryl, alkoxy or carboxy groups; and c) oxygen.
摘要:
The invention relates to composition comprising: at least one free radical polymerizable vinyl compound; and an active amount of inhibition composition comprising metal ions, halogen ions and a ligand having a donor atom selected from oxygen, nitrogen, sulfur, phosphorus and a combination thereof, the metal ions being selected from ions of Ti, Mo, Re, Ru, Fe, Rh, Ni, Pd, Co, Os, Cu and any combination thereof; wherein the composition is free of a nitroxyl compound of a secondary amine having no hydrogen atom on α-C atom. A method for inhibiting the premature polymerization of at least one free radical polymerizable vinyl compound, comprising: adding an active amount of the inhibition composition to the at least one free radical polymerizable vinyl compound.
摘要:
Methods and compositions are provided for inhibiting the polymerization of a vinyl aromatic monomer, such as styrene monomer, during elevated temperature processing thereof or during storage or shipment of polymer containing product. The compositions comprise a combination of a quinone methide derivative A) and a phenol compound B). The methods comprise adding from about 1-10,000 ppm of the combination to the monomer containing medium, per one million parts of the monomer.
摘要:
Compositions and methods for inhibiting polymerization of ethylenically unsaturated monomers are provided. The compositions include a water-soluble phenylenediamine composition.
摘要:
A method for dispersing polymerization by-products and maintaining said by-products in solution in a hydrocarbon processing system during acrylic acid and acrylate monomer formation is disclosed, which includes adding to the monomer an effective inhibiting amount of an N-alkyl polyalkenyl succinimide dispersant.
摘要:
Methods and compositions are provided for inhibiting the polymerization of a vinyl aromatic monomer, such as styrene monomer, during elevated temperature processing thereof or during storage or shipment of polymer containing product. The compositions comprise a combination of a quinone methide derivative A) and a phenol compound B). The methods comprise adding from about 1-10,000 ppm of the combination to the monomer containing medium, per one million parts of the monomer.
摘要:
A method for dispersing polymerization by-products and maintaining said by-products in suspension in a hydrocarbon processing system during acrylic acid and acrylate monomer formation is disclosed, which includes adding to the monomer an effective inhibiting amount of an N-alkyl polyalkenyl succinimide dispersant.
摘要:
Quinone methide derivatives such as 4-benzylidene-2,6-di-tert-butyl-cyclohexa-2,5 dienone are used to inhibit styrene monomer polymerization in the dehydrogenator portion of a styrene monomer production system. The inhibitor contacts the dehydrogenation effluent and does not partition in substantial amounts to the aqueous phase that is separated in the phase separator.