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公开(公告)号:US10988707B2
公开(公告)日:2021-04-27
申请号:US16765157
申请日:2018-11-20
Applicant: SUNPINE AB
Inventor: Lars Stigsson , Valeri Naydenov , Christian Hulteberg
Abstract: The present invention describes a method for the treatment of tall oil pitch (TOP), said method comprising heating the TOP and optionally additives including water and steam to a temperature of at least 300° C.; maintaining the temperature in the reactor at 300° C. or higher for a period of time to enable thermal treatment of the TOP to act on components thereof to produce fatty acids and/or rosin acids, and/or derivatives thereof, and/or unsaponifiables and/or derivatives having lower molecular weight compared to the high molecular weight components with molecular weights of at least 350 g/mole present in the original TOP, to yield a modified TOP material with lower viscosity.
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公开(公告)号:US20150353866A1
公开(公告)日:2015-12-10
申请号:US14653501
申请日:2013-12-20
Applicant: SUNPINE AB
Inventor: Lars Stigsson , Valeri NAYDENOV , Johan LUNDBÄCK
IPC: C11B3/12 , C07C4/04 , C11B3/00 , C11B13/00 , B01D3/28 , C10L10/12 , C10L1/188 , C07C51/44 , B01D3/10 , B01D3/14 , C10G3/00 , C10L1/02
CPC classification number: C11B3/006 , B01D3/10 , B01D3/143 , B01D3/28 , C07C4/04 , C07C51/44 , C07C2603/26 , C09F1/02 , C10G3/00 , C10G3/50 , C10G2300/1014 , C10G2400/04 , C10L1/026 , C10L1/08 , C10L1/1616 , C10L1/1888 , C10L10/12 , C10L2200/0469 , C10L2200/0484 , C10L2270/026 , C10L2290/543 , C10L2290/544 , C10L2290/545 , C11B3/008 , C11B3/12 , C11B11/00 , C11B13/005 , Y02E50/13 , Y02P30/20 , Y02W30/74
Abstract: The present invention pertains to a process for refining of crude tall oil (CTO). The process comprises fractionation under vacuum of a refined CTO into at least one stream of refined tall diesel (RTD) or tall oil fatty acids (TOFA), the RTD or TOFA comprises from 2-30% by volume of resin acids and from 20-90% by volume of fatty acids, and at least one stream of resin acid(s) (RA) comprising less than 5% by volume of fatty acids. The stream of RTD or TOFA is deoxygenated forming hydrocarbon compounds in a subsequent step. This invention also relates to a refined tall diesel. Furthermore, a process for the production of a refined tall diesel (RTD) composition, wherein crude sulphate turpentine(s) (CST) is added to the refined tall diesel (RTD) composition, is described.
Abstract translation: 本发明涉及粗妥质油(CTO)的精制方法。 该方法包括在精制CTO的真空下将精馏的高柴油(RTD)或妥尔油脂肪酸(TOFA)的至少一个流分馏,RTD或TOFA包含2-30体积%的树脂酸和20- 90体积%的脂肪酸和至少一种包含小于5体积%脂肪酸的树脂酸(RA)流。 RTD或TOFA的流在随后的步骤中脱氧形成烃化合物。 本发明还涉及精制高级柴油。 此外,描述了生产精制高柴油(RTD)组合物的方法,其中将粗硫酸盐松节油(CST)加入到精制高柴油(RTD)组合物中。
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公开(公告)号:US09719047B2
公开(公告)日:2017-08-01
申请号:US14653501
申请日:2013-12-20
Applicant: SunPine AB
Inventor: Lars Stigsson , Valeri Naydenov , Johan Lundback
IPC: C11B3/12 , C07C4/04 , C11B3/00 , C11B13/00 , B01D3/28 , C10L10/12 , C10L1/188 , C07C51/44 , B01D3/10 , B01D3/14 , C10G3/00 , C10L1/02 , C09F1/02 , C11B11/00 , C10L1/08 , C10L1/16
CPC classification number: C11B3/006 , B01D3/10 , B01D3/143 , B01D3/28 , C07C4/04 , C07C51/44 , C07C2603/26 , C09F1/02 , C10G3/00 , C10G3/50 , C10G2300/1014 , C10G2400/04 , C10L1/026 , C10L1/08 , C10L1/1616 , C10L1/1888 , C10L10/12 , C10L2200/0469 , C10L2200/0484 , C10L2270/026 , C10L2290/543 , C10L2290/544 , C10L2290/545 , C11B3/008 , C11B3/12 , C11B11/00 , C11B13/005 , Y02E50/13 , Y02P30/20 , Y02W30/74
Abstract: The present invention pertains to a process for refining of crude tall oil (CTO). The process comprises fractionation under vacuum of a refined CTO into at least one stream of refined tall diesel (RTD) or tall oil fatty acids (TOFA), the RTD or TOFA comprises from 2-30% by volume of resin acids and from 20-90% by volume of fatty acids, and at least one stream of resin acid(s) (RA) comprising less than 5% by volume of fatty acids. The stream of RTD or TOFA is deoxygenated forming hydrocarbon compounds in a subsequent step. This invention also relates to a refined tall diesel. Furthermore, a process for the production of a refined tall diesel (RTD) composition, wherein crude sulphate turpentine(s) (CST) is added to the refined tall diesel (RTD) composition, is described.
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公开(公告)号:US09499767B2
公开(公告)日:2016-11-22
申请号:US14653470
申请日:2012-12-21
Applicant: SunPine AB
Inventor: Lars Stigsson , Valeri Naydenov , Johan Lundback
IPC: C11B3/00 , C10G3/00 , C07C4/04 , C10L10/12 , C07C51/44 , B01D3/10 , B01D3/14 , B01D3/28 , C09F1/02 , C11B3/12 , C11B11/00 , C11B13/00 , C10L1/02 , C10L1/188 , C10L1/08 , C10L1/16
CPC classification number: C11B3/006 , B01D3/10 , B01D3/143 , B01D3/28 , C07C4/04 , C07C51/44 , C07C2603/26 , C09F1/02 , C10G3/00 , C10G3/50 , C10G2300/1014 , C10G2400/04 , C10L1/026 , C10L1/08 , C10L1/1616 , C10L1/1888 , C10L10/12 , C10L2200/0469 , C10L2200/0484 , C10L2270/026 , C10L2290/543 , C10L2290/544 , C10L2290/545 , C11B3/008 , C11B3/12 , C11B11/00 , C11B13/005 , Y02E50/13 , Y02P30/20 , Y02W30/74
Abstract: A process for pre-treatment of a crude tall oil (CTO) for removal of impurities is disclosed. The process comprises a first pre-treatment step involving a CTO wash and a separation of a first oil phase comprising refined CTO and an aqueous phase holding impurities, and a second step involving a separation of a second oil phase from the aqueous phase. A process for refining of crude tall oil (CTO) is also disclosed. The process comprises fractionation under vacuum of a refined CTO into at least one stream of refined tall diesel (RTD) or tall oil fatty acids (TOFA) and at least one stream of resin acid(s) (RA). The stream of RTD or TOFA is deoxygenated forming hydrocarbon compounds in a subsequent step. This invention also relates to a refined tall diesel. Furthermore, a process for the production of a refined tall diesel (RTD) composition, wherein crude sulphate turpentine(s) (CST) is added to the refined tall diesel (RTD) composition, is described.
Abstract translation: 公开了用于去除杂质的粗妥尔油(CTO)的预处理方法。 该方法包括涉及CTO洗涤和分离包含精制CTO和含有杂质的水相的第一油相的第一预处理步骤,以及涉及将第二油相与水相分离的第二步骤。 还公开了粗妥质油(CTO)的精制方法。 该方法包括在精制CTO的真空下将精制高级柴油(RTD)或妥尔油脂肪酸(TOFA)和至少一种树脂酸(RA)流的至少一个流分馏。 RTD或TOFA的流在随后的步骤中脱氧形成烃化合物。 本发明还涉及精制高级柴油。 此外,描述了生产精制高柴油(RTD)组合物的方法,其中将粗硫酸盐松节油(CST)加入到精制高柴油(RTD)组合物中。
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公开(公告)号:US20150307810A1
公开(公告)日:2015-10-29
申请号:US14653470
申请日:2012-12-21
Applicant: SUNPINE AB
Inventor: Lars Stigsson , Valeri Naydenov , Johan Lundback
CPC classification number: C11B3/006 , B01D3/10 , B01D3/143 , B01D3/28 , C07C4/04 , C07C51/44 , C07C2603/26 , C09F1/02 , C10G3/00 , C10G3/50 , C10G2300/1014 , C10G2400/04 , C10L1/026 , C10L1/08 , C10L1/1616 , C10L1/1888 , C10L10/12 , C10L2200/0469 , C10L2200/0484 , C10L2270/026 , C10L2290/543 , C10L2290/544 , C10L2290/545 , C11B3/008 , C11B3/12 , C11B11/00 , C11B13/005 , Y02E50/13 , Y02P30/20 , Y02W30/74
Abstract: A process for pre-treatment of a crude tall oil (CTO) for removal of impurities is disclosed. The process comprises a first pre-treatment step involving a CTO wash and a separation of a first oil phase comprising refined CTO and an aqueous phase holding impurities, and a second step involving a separation of a second oil phase from the aqueous phase. A process for refining of crude tall oil (CTO) is also disclosed. The process comprises fractionation under vacuum of a refined CTO into at least one stream of refined tall diesel (RTD) or tall oil fatty acids (TOFA) and at least one stream of resin acid(s) (RA). The stream of RTD or TOFA is deoxygenated forming hydrocarbon compounds in a subsequent step. This invention also relates to a refined tall diesel. Furthermore, a process for the production of a refined tall diesel (RTD) composition, wherein crude sulphate turpentine(s) (CST) is added to the refined tall diesel (RTD) composition, is described.
Abstract translation: 公开了用于去除杂质的粗妥尔油(CTO)的预处理方法。 该方法包括涉及CTO洗涤和分离包含精制CTO和含有杂质的水相的第一油相的第一预处理步骤,以及涉及将第二油相与水相分离的第二步骤。 还公开了粗妥质油(CTO)的精制方法。 该方法包括在精制CTO的真空下将精制高级柴油(RTD)或妥尔油脂肪酸(TOFA)和至少一种树脂酸(RA)流的至少一个流分馏。 RTD或TOFA的流在随后的步骤中脱氧形成烃化合物。 本发明还涉及精制高级柴油。 此外,描述了生产精制高柴油(RTD)组合物的方法,其中将粗硫酸盐松节油(CST)加入到精制高柴油(RTD)组合物中。
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