公开(公告)号：US20030027704A1

公开(公告)日：2003-02-06

申请号：US10194052

申请日：2002-07-15

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Yoshiaki Sakatani ,  Hironobu Koike ,  Hiroyuki Ando

IPC: C04B035/00 ,  B01J031/00 ,  B01J037/00 ,  B01J021/04

CPC classification number: C01G23/0532 ,  C01P2002/84 ,  C03C17/25 ,  C03C17/256 ,  C03C2217/21 ,  C03C2217/212 ,  C03C2217/71 ,  C03C2218/111 ,  C09C1/3661 ,  C09C1/3669 ,  C09C1/3692 ,  Y10S502/522

Abstract: A ceramics dispersion liquid is provided. The dispersion liquid may form an applied film easily recovering hydrophilic properties with light irradiation even when contaminated by lipophilic materials. The ceramics dispersion liquid comprises a ceramics, a dispersion medium, and at least one compound selected from a carboxylic acid, an ammonium carboxylate, a salt of carboxylic acid with metal selected from Ia group, IIa group, IIIa group, Va group, VIa group, VIIa group, VIII group, Ib group, IIb group, IIIb group, IVb group and lanthanoid group, and a salt of oxalic acid with metal selected from IVa group.

Abstract translation: 提供陶瓷分散液。 即使在被亲油性物质污染的情况下，分散液也可形成容易回收亲水性的涂膜。 陶瓷分散液包含陶瓷，分散介质和至少一种选自羧酸，羧酸铵，羧酸盐与选自Ia族，IIa族，IIIa族，Va族，VIa族的金属的化合物 ，VIIa族，VIII族，Ib族，IIb族，IIIb族，IVb族和镧系元素，草酸盐与选自IVa族的金属。

公开(公告)号：US20020021999A1

公开(公告)日：2002-02-21

申请号：US09901609

申请日：2001-07-11

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Yoshiaki Sakatani ,  Hiroyuki Ando ,  Hironobu Koike

IPC: C01G023/04

CPC classification number: B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J37/031 ,  C01G23/0532 ,  C01P2006/62 ,  C01P2006/63

Abstract: A titanium oxide showing sufficiently high photocatalytic activities by irradiation of visible light is provided. Using the titanium oxide, an excellent photocatalyst and photocatalyst coating composition are also provided. The titanium oxide has a selected ion chromatogram in which an evolution gas having 28 of a ratio of mass number to electric charge quantity exhibits at least one peak at about 600null C. or higher, the selected ion chromatogram being measured in a thermogravimetry-mass-spectroscopy.

Abstract translation: 提供了通过可见光照射显示足够高的光催化活性的氧化钛。 使用二氧化钛，还提供了优异的光催化剂和光催化剂涂料组合物。 氧化钛具有选择的离子色谱图，其中具有质量数与电荷量比的28的析出气体在约600℃或更高温度下表现出至少一个峰，所选择的离子色谱图以热重分析 - 质量 光谱学。

公开(公告)号：US20030161784A1

公开(公告)日：2003-08-28

申请号：US10368362

申请日：2003-02-20

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Kensen Okusako ,  Hiroyuki Ando

IPC: C01G023/04

CPC classification number: C01G23/053 ,  C01G23/0532 ,  C01P2002/02 ,  C01P2002/88 ,  C01P2004/62 ,  C01P2006/12

Abstract: A titanium oxide precursor which is used for producing a fine-particle titanium oxide showing a high photocatalytic activity is provided. The titanium oxide precursor is an oxygen-atom-containing titanium compound other than anatase-form titanium oxide, and has a maximum exothermic peak at a temperature in the range of from about 30null C. to about 500null C. in a differential thermal analysis curve and shows decrease in weight in a thermogravimetry curve at about the same temperature at which the maximum exothermic peak is shown in the differential thermal analysis curve when subjected to a thermogravimetry and differential thermal analysis under the condition of a temperature rising rate of 20null C./min.

Abstract translation: 提供了用于制备显示高光催化活性的微粒二氧化钛的二氧化钛前体。 氧化钛前体是除锐钛矿型氧化钛以外的含氧原子的钛化合物，并且在差热中在约30℃至约500℃的温度范围内具有最大放热峰 分析曲线，并且在温度升高速率为20°的条件下进行热重分析和差热分析时，在差热分析曲线中显示最大放热峰的相同温度下，在热重分析曲线中显示重量减少 C./min。

公开(公告)号：US20020132734A1

公开(公告)日：2002-09-19

申请号：US10026000

申请日：2001-12-21

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Yoshiaki Sakatani ,  Hiroyuki Ando ,  Hironobu Koike

IPC: B01J023/00 ,  C22B034/10

CPC classification number: C01G23/04 ,  C01G23/0532 ,  C01P2002/77

Abstract: A titanium hydroxide is provided which can be utilized for producing a photocatalyst exhibiting a superior photocatalytic activity by irradiation of visible light. The titanium hydroxide has a primary differential spectrum (of radial structure function in connection with titanium K absorption edge) having maximal intensities (U1 and U2) and minimal intensities (L1 and L2) at interatomic distances in the range of from 1.4 null to 2.8 null, the maximal intensities being at an interatomic distance of from 1.4 null to 1.7 null and of from 2.2 null to 2.5 null and the minimal intensities being at an interatomic distance of from 1.9 null to 2.2 null and of from 2.5 null to 2.8 null; and index X calculated by the equation Xnull(U2nullL2)/(U1nullL1) of about 0.06 or more.

Abstract translation: 提供氢氧化钛，其可用于制备通过照射可见光而显示出优异的光催化活性的光催化剂。 氢氧化钛具有在原子间距离在1.4至2.8埃范围内具有最大强度（U1和U2）和最小强度（L1和L2）的初级差分光谱（与钛K吸收边缘相关的径向结构功能） 最大强度为原子间距离为1.4至1.7埃，最小强度为原子间距离为1.9至2.2埃，范围为2.5至2.8埃; 并且通过等式X =（U2-L2）/（U1-L1）计算的指数X为大约0.06或更大。

公开(公告)号：US20020077251A1

公开(公告)日：2002-06-20

申请号：US09978800

申请日：2001-10-18

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Kensen Okusako ,  Hiroyuki Ando

IPC: B01J023/00

CPC classification number: B01J21/063 ,  B01J21/06 ,  B01J23/06 ,  B01J23/10 ,  B01J23/20 ,  B01J23/30 ,  B01J35/002 ,  B01J35/004 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/10 ,  B82Y30/00 ,  C01G23/047 ,  C01G33/00 ,  C01G41/02 ,  C01P2002/72 ,  C01P2002/84 ,  C01P2002/85 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/12 ,  Y10T428/2991

Abstract: A photocatalyst is provided, which comprises a titanium oxide and a metal-containing compound other than titanium oxide on the surface of the titanium oxide, wherein the metal-containing compound is a metal oxide having an acid site and the photocatalyst has a BET specific surface area of about 55 m2/g or larger, or wherein the metal-containing compound is a basic metal-containing compound and the photocatalyst has an anatase-crystalline structure and an anatase-crystalline size of about 10 nm or larger. The photocatalyst shows sufficiently high photocatalytic activities by irradiation of visible light.

Abstract translation: 提供了一种光催化剂，其包含在氧化钛表面上的氧化钛和除了氧化钛之外的含金属化合物，其中所述含金属化合物是具有酸性位点的金属氧化物，并且所述光催化剂具有BET比表面积 面积为约55m 2 / g以上，或者其中含金属化合物为含碱性金属的化合物，光催化剂具有约10nm以上的锐钛矿型结晶和锐钛矿型结晶尺寸。 光催化剂通过可见光的照射显示足够高的光催化活性。