公开(公告)号：US3850895A

公开(公告)日：1974-11-26

申请号：US30690172

申请日：1972-11-15

申请人： SNAM PROGETTI

发明人： PRIOLA A ,  CESCA S ,  FERRARIS G

IPC分类号： C08F4/00 ,  C08F2/04 ,  C08F4/42 ,  C08F10/10 ,  C08F210/12 ,  C08D1/26 ,  C08D3/02 ,  C08D3/10

CPC分类号： C08F10/10 ,  C08F4/52

摘要： Y-Z(-(Y'')N)(-(R'')H)-X

WEHEREIN X IS AN ATOM OF HAOLGEN, Z IS NITROGEN, CARBON OR PHOSPHOROUS; R'' IS HYDROGEN RADICAL WITH FROM 1 TO 10 CARBON ATOMS, OR HYDROGEN, OR IS EQUAL TO X; Y IS A MEMBER OF THE GROUP CONSISTING OF

-SO2-R", -CO-R", -COO-R", -P(=O)(-R")2,

(R")2-N-C(=N-R")-, -C(=S)-R", -C(=S)-O-R", -C(-R")2-NO2

-C(-R")2-CN, -N=C=O, =C(-R")-NO2, -C(-R")=N, =C(-CL)-R"

1. PROCESS FOR THE PRODUCTION OF BUTYL RUBBER THROUGH THE COPOLYMERIZATION OF ISOBUTYLENE AND ISOPRENE WHEREIN THE IMPROVEMENT COMPRISES CONDUCTING THE COPOLYMERIZATION REACTION IN THE PRESENCE OF A CATALYTIC SYSTEM CONSISTING ESSENTIALLY OF: (A) A METALORGANIC COMPOUND OF ALUMINUM HAVING THE FORMULA AIR3 OR AIR2X WHERE X IS A HALOGEN ATOM AND R IS A HYDROCARBON RADICAL WITH FROM 1 TO 10 CARBON ATOMS, OR HYDROGEN; AND (B) A COMPOUND CONTAINING A MOBILE HALOGEN GROUP OR AT LEAST ONE IN WHICH THE HALOGEN GROUP IS EASILY EXCHANGEABLE DUE TO THE PRESENCE OF AN ELECTROPHILIC GROUP REPRESENED BY THE FORMULA
Y'' IS EQUAL TO Y, OR TO R''; Y OR Y'' MAY BE A BIVALENT RADICAL LINKED THROUGH A DOUBLE BON DIRECTLY TO Z; Y AND Y'' MAY BE CONNECTED TO EACH OTHER CLOSING THEMSELVES CYCLICALLY ON Z; R'''' IS AN ALKYLIC OR ARYLIC RADICAL, SIMPLE OR SUBSTITUTED; N AND H ARE 0 OR 1.

公开(公告)号：US3850894A

公开(公告)日：1974-11-26

申请号：US30690072

申请日：1972-11-15

申请人： SNAM PROGETTI

发明人： GIUSTI P ,  FERRARIS G ,  BASSAREDDA M ,  PRIOLA A ,  CESCA S

IPC分类号： C08F4/00 ,  C08F4/42 ,  C08F210/12 ,  C08F236/08 ,  C08D1/26 ,  C08D3/04 ,  C08D3/10

CPC分类号： C08F210/12 ,  C08F4/52

摘要： 1. PROCESS FOR THE PRODUCTION OF BUTYL RUBBER THROUGH THE COPOLYMERIZATION OF ISOLBUTYLENE AND ISOPRENE WHEREIN THE IMPROVEMENT COMPRISES CONDUCTING THE COPOLYMERIZATION IN THE PRESENCE OF A CATALYTIC SYSTEM CONSISTING ESSENTIALLY OF: (A) A METALORGANIC COMPOUND OF ALUMINUM REPRESENTED BY THE FORMULA AIR3 OR AIR2X WHEREIN X IS A HALOGEN ATOM; R IS A HYDROCARBON RADICAL WITH FROM 1 TO 10 CARBON ATOMS OR HYDROGEN; AND (B) A HALOID OF AN ORGANIC ACID OR THIOACID REPRESENTED BY THE GENERAL FORMULA

R''-C(=Y)-X''

IN WHICH X'' IS A HALOGEN ATOM; R'' IS AN ALKYLIC RESIDUE, CYCLOALKYLIC, ALKYLARYLIC, ALKYLCYCLOALKYLIC, OR IS EQUAL TO X'' OR IS REPRESENTED BY THE FORMULA

-C(=Y)-X''

AND Y IS OXYGEN OR SULPHUR.

公开(公告)号：US3850896A

公开(公告)日：1974-11-26

申请号：US30690272

申请日：1972-11-15

申请人： SNAM PROGETTI

发明人： PRIOLA A ,  CESCA S ,  GIUSTI P ,  FERRARIS G ,  BACCAREDDA M

IPC分类号： C08F4/00 ,  C08F4/42 ,  C08F4/60 ,  C08F4/78 ,  C08F10/14 ,  C08F210/12 ,  C08D1/26 ,  C08D3/04 ,  C08D3/10

CPC分类号： C08F10/14 ,  C08F210/12 ,  C08F4/52

摘要： 1. PROCESS FOR THE PRODUCTION OF BUTYL RUBBER THROUGH THE COPOLYMERIZATION OF SIOLBUTYLENE AND ISOPRENE WHEREIN THE IMPROVEMENT COMPRISES CONDUCTING THE COPOLYMERIZATION REACTION IN THE PRESENCE OF A CATALYST SYSTEM CONSISTING ESSENTIALLY OF: (A) A METALORGANIC COMPOSITION OF ALUMINUM REPRESENTED BY THE FORMULA AIR3 OR AIR2X WHEREIN X IS AN ATOM OF HALOGEN, AND R IS A HYDROCARBON RADICAL HAVING FROM 1 TO 10 CARBON ATOMS, OR HYDROGEN; (B) A HALOID OF AN INORGANIC ACID REPRESENTED BY THE GENERAL FORMULA ZNMEXMYP IN WHICH ME IS AN ELEMENT BELONGING TO THE 5*, 6* OR 7* GROUP OF THE PERIODIC SYSTEM; N AND M ARE WHOLE NUMBERS; P IS A WHOLE NUMBER OR ZERO AND THE SUM 2N+M+P IS EQUAL TO THE VALENCY OF SAID ELEMENT; Z IS OXYGEN OR SULPHUR; X IS A HALOGEN ATOM; Y IS AN ORGANIC RESIDUE SELECTED FROM THE ALKYLIC, ACRYLIC, CYCLOHEXYLIC, ETHERIC, AMMIDIC, ACETYLACETONIC AND OXIMIC FUNCTIONAL GROUPS; AND WHEREIN THE MOLAR RATIO OF COMPOUND (B) TO COMPOUND (A) IS BETWEEN 0.5 AND 10-4.

公开(公告)号：US3853829A

公开(公告)日：1974-12-10

申请号：US27593572

申请日：1972-07-28

申请人： SNAM PROGETTI

发明人： PRIOLA A ,  CESCA S ,  FERRARIS G

IPC分类号： C08F16/00 ,  C08F16/12 ,  C08F32/00 ,  C08F36/00 ,  C08F15/02

CPC分类号： C08F16/12

摘要： Vulcanizable, elastomeric copolymers of vinyl ethers and cyclic polyenes, which have a molecular weight above 50,000 and a vinyl ether content in excess of 80%, are prepared by reacting an alkyl vinyl ether such as vinyl isobutyl ether with a conjugated cyclic diolefin wherein both double bonds are endocyclic or with a cyclic diolefin or triolefin having a system of conjugated double bonds, at least one of which is endocyclic, in the presence of a Friedel-Crafts catalyst and a solvent of low or high polarity; the nature and state of the obtained copolymer being controllable by the respective concentrations of the reactants and the polarity of the reaction medium.

摘要翻译： 通过使乙烯基异丁基醚等烷基乙烯基醚与共轭环状二烯烃反应制备，分子量大于50,000，乙烯基醚含量超过80％的乙烯基醚和环状多烯烃的可硫化弹性体共聚物，其中双重 在Friedel-Crafts催化剂和低极性或高极性溶剂的存在下，键是环状的或具有共轭双键体系的环状二烯烃或三烯烃，其中至少一种是环内的; 所得共聚物的性质和状态可由反应物的各自浓度和反应介质的极性控制。

公开(公告)号：US3850897A

公开(公告)日：1974-11-26

申请号：US30749972

申请日：1972-11-17

申请人： SNAM PROGETTI

发明人： FERRARIS G ,  PRIOLA A ,  CESCA S

IPC分类号： C08F4/00 ,  C08F4/42 ,  C08F4/60 ,  C08F10/10 ,  C08D1/26 ,  C08D3/04 ,  C08D3/10

CPC分类号： C08F10/10 ,  C08F4/12 ,  C08F4/16

摘要： IN WHICH R IS HYDROGEN, CYCLOALKYL, OR ARYL; R'' IS A HYDROCARBON RADICAL SELECTED FROM THOSE LISTED FOR R; Y IS AN ATOM OF OXYGEN, OR OF SULPHUR, OR NITROGEN BOUND TO TWO HYDROCARBON RADICALS; AND X IS AN ATOM OF HALOGEN; AND (II) A CO-CATAYLST SELECTED FROM THE FOLLOWING: (A) BRONSTED ACIDS; (B) ALKYL HALOIDS, HALOIDS OF ORGANIC OR INORGANIC ACIDS, OR COMPOUNDS CONTAINING ATOMS OF ACTIVATED HALOGEN; (C) LEWIS ACIDS; AND (D) COMPOUNDS REPRESENTED BY THE FORMULA X''NMEY''M IN WHICH X'' IS AN ATOM OF HALOGEN, Y'' IS OXYGEN, SULPHUR OR A FUNCTIONAL GROUP SELECTED FROM THE ALKOXY, ESTER, AMIDE, ALKYL, CYCLOALKYL, AROMATIC, ARENE, PHOSPHINE, ACETYLACETONE AND OXIME RADICALS; ME IS A METAL CHOSEN FROM TI, SN, ZN, SI, B, AL, HG, PB, W, SB, GE, V, ZR, AS, BI AND MO; AND M AND N ARE WHOLE NUMBERS WHOSE SUM IS EQUAL TO THE VALENCY OF ME EXCEPT IN THE CASE IN WHICH Y IS OXYGEN OR SULPHUR, WHEN IT BECOMES 2M+N; AND WHEREIN THE MOLAR RATIO BETWEEN COMPOUND (II) AND COMPOUND (I) IS LESS THAN 1.
1. PROCESS FOR THE PRODUCTION OF COPOLYMERS OF ISOBUTYLENE AND A CONJUGATED DIENE, WHEREIN THE COPOLYMERIZATION REACTION IS CONDUCTED IN THE PRESENCE OF A CATALYST SYSTEM CONSISTING ESSENTIALLY OF: (I) A METALORGANIC COMPOUND OF ALUMINUM REPRESENTED BY THE FORMULA

RAL(YR'')X