公开(公告)号：US20150133599A1

公开(公告)日：2015-05-14

申请号：US14600072

申请日：2015-01-20

Applicant: SABIC Global Technologies B.V.

Inventor： Navinchandra S. ASTHANA ,  Kenneth F. MILLER ,  Ganesh KANNAN

IPC: C08G63/553 ,  C08L67/02

CPC classification number: C08G63/553 ,  C08G63/185 ,  C08L51/04 ,  C08L55/02 ,  C08L67/02 ,  C08L2205/02 ,  C08L2205/025 ,  C08L25/06

Abstract: An amorphous copolyester comprising the reaction product of: (a) a monomer of formula I wherein R1, R2, R3, and R5 are each independently hydrogen or a C1-3 alkyl group, a is 0-1, b is 0-4, c is 0-4 and d is 0-3, and each R4 is independently hydrogen or a C1-3 alkyl group; (b) a virgin monomer selected from terephthalic acid, a di(C1-3 alkyl) terephthalate, and combinations thereof, and (c) 1,4-cyclohexane dimethanol; wherein the residue of monomer (a) is present in an amount from 7 to less than 12 mole % of the copolyester based on moles of repeat units in the polyester; and the copolyester has a glass transition temperature of at least 107° C., an intrinsic viscosity of at least 0.7 dl/g, and a molded sample has a Notched Izod value of at least 290 J/m determined in accordance with ASTM D256.

Abstract translation: 一种无定形共聚酯，其包含以下反应产物：（a）式I的单体，其中R 1，R 2，R 3和R 5各自独立地为氢或C 1-3烷基，a为0-1，b为0-4， c为0-4，d为0-3，各R 4独立地为氢或C 1-3烷基; （b）选自对苯二甲酸，二（C 1-3烷基）对苯二甲酸酯及其组合的原始单体，和（c）1,4-环己烷二甲醇; 其中单体（a）的残余物以基于聚酯中重复单元的摩尔数的7至小于12摩尔％的共聚酯的量存在; 共聚酯的玻璃化转变温度为至少107℃，特性粘度为0.7dl / g以上，成型品的缺口伊佐德值至少为290J / m，根据ASTM D256测定。