公开(公告)号：US4091013A

公开(公告)日：1978-05-23

申请号：US706099

申请日：1976-07-16

申请人： Rolf Putter ,  Gunther Klag ,  Heinz Ulrich Blank

发明人： Rolf Putter ,  Gunther Klag ,  Heinz Ulrich Blank

IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C309/47 ,  C07C143/60 ,  C07C85/04

CPC分类号： C07C309/47

摘要： 1-Amino-naphthalene-7-sulphonic acid is prepared by reacting 1-chloro-naphthalene-4,7-disulphonic acid with ammonia at elevated temperatures in the presence of water and optionally in the presence of a catalyst such as a copper catalyst.

摘要翻译： 1-氨基 - 萘-7-磺酸是通过使1-氯 - 萘-4,7-二磺酸与氨在升高的温度下在水存在下和任选地在催化剂例如铜催化剂存在下反应来制备的。

公开(公告)号：US4094852A

公开(公告)日：1978-06-13

申请号：US707546

申请日：1976-07-22

申请人： Rudolf Sundermann ,  Gunther Rottloff ,  Ernst Grigat ,  Rolf Putter

发明人： Rudolf Sundermann ,  Gunther Rottloff ,  Ernst Grigat ,  Rolf Putter

IPC分类号： C08G73/00 ,  C08G73/06

CPC分类号： C08G73/0655

摘要： A polytrimerizable mixture of30 to 99.9% by weight of at least one aromatic, polyfunctional cyanic acid ester or a prepolymer thereof, and0.1 to 70% by weight of at least one high-boiling ester with a boiling point above 250.degree. C at 760 Torr,Said mixture results in polytriazines having a significant improvement in elasticity, flexibility and resistance to hydrolysis.

摘要翻译： 至少一种芳香族，多功能的氰酸酯或其制备物的重量百分比为30至99.9％的多聚三聚体混合物，以及至少一个高沸点酯的重量为0.1-70％，沸点高于250℃，760℃ Torr，在聚合物中的混合结果在弹性，柔性和抗水解性方面有重大改进。

公开(公告)号：US4178308A

公开(公告)日：1979-12-11

申请号：US920033

申请日：1978-06-28

申请人： Willi Schossler ,  Horst Behre ,  Rolf Putter

发明人： Willi Schossler ,  Horst Behre ,  Rolf Putter

IPC分类号： C07C309/50 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C22B34/12 ,  H03D13/00 ,  C07C143/66

CPC分类号： C22B34/12

摘要： A process has been invented for the preparation of a mono-alkali metal salt of 1-amino-8-naphthol-3,6-disulphonic acid comprising reacting 1-naphthylamine-3,6,8-trisulphonic acid and/or a salt thereof and/or a naphthylamine-trisulphonic acid isomer mixture and/or salt thereof with an alkali metal hydroxide solution at elevated pressure and elevated temperature and in the presence of an alcohol or alcoholate, and separating out the mono-alkali metal salt by acidification. The process results in the procurement of higher yields of the desired product and in the formation of less by-products.

摘要翻译： 已经发明了一种制备1-氨基-8-萘酚-3,6-二磺酸的单碱金属盐的方法，其包括使1-萘胺-3,6,8-三磺酸和/或其盐 和/或萘胺 - 三磺酸异构体混合物和/或其盐与碱金属氢氧化物溶液在升高的压力和升高的温度下，在醇或醇化物的存在下，通过酸化分离出单碱金属盐。 该过程导致采购更高产量的所需产品和形成较少的副产物。

公开(公告)号：US4049630A

公开(公告)日：1977-09-20

申请号：US631560

申请日：1975-11-13

申请人： Rudolf Sundermann ,  Rolf Putter ,  Ernst Grigat

发明人： Rudolf Sundermann ,  Rolf Putter ,  Ernst Grigat

IPC分类号： C08G73/00 ,  C07D251/26 ,  C07D251/34 ,  C08G18/83 ,  C08G63/91 ,  C08G73/06

CPC分类号： C08G73/065 ,  C07D251/26 ,  C07D251/34 ,  C08G18/833 ,  C08G63/916

摘要： Process for the preparation of s-triazine prepolymers which comprisesA. condensing a hydroxy compound which has 2 or more alcoholic hydroxyl groups;B. condensing the resulting condensation product with an aromatic hydroxy compound; andC. thereafter reacting the free hydroxyl groups of the condensation product obtained from (b) with cyanogen halide and in the presence of a base.

摘要翻译： 制备s-三嗪预聚物的方法，其包括A.冷凝具有2个或更多个醇溶性羟基的羟基化合物; B.用芳族羟基化合物浓缩结晶凝结产物; 和C.反应自（B）与氰基卤化物和碱的存在产生的冷凝产物的自由羟基组合。

公开(公告)号：US4377535A

公开(公告)日：1983-03-22

申请号：US219615

申请日：1980-12-24

申请人： Reinhard Kaiser ,  Horst Behre ,  Jurgen Dammann ,  Rolf Putter ,  Axel Vogel

发明人： Reinhard Kaiser ,  Horst Behre ,  Jurgen Dammann ,  Rolf Putter ,  Axel Vogel

IPC分类号： C07C309/40 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C143/55 ,  C07B11/00

CPC分类号： C07C309/00

摘要： A process has been provided for the preparation of nitro-T-acid by nitration of naphthalene-1,3,6-trisulphonic acid from a nitration mixture which has reacted to the extent of at least 80% which naphthalene-1,3,6-trisulphonic acid or a mixture containing the latter. Nitro-T-acid (and T-acid) is an intermediate for the preparation of H-acid which, in turn, is an intermediate for the preparation of dyestuffs.

摘要翻译： 已经提供了一种通过从硝化混合物中硝化萘-1,3,6-三磺酸制备硝基-T-酸的方法，该硝化混合物的反应程度至少为80％，该萘-1,3,6 - 三磺酸或含有后者的混合物。 硝基T酸（和T酸）是制备H酸的中间体，其又是制备染料的中间体。

公开(公告)号：US4166826A

公开(公告)日：1979-09-04

申请号：US920032

申请日：1978-06-28

申请人： Willi Schossler ,  Rolf Putter ,  Horst Behre

发明人： Willi Schossler ,  Rolf Putter ,  Horst Behre

IPC分类号： C07C309/50 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C07C143/66

CPC分类号： C07C303/22

摘要： A process has been invented for the preparation of a mono-alkali metal of 1-amino-8-naphthol-3,6-disulphonic acid, comprising reacting 1-naphthylamine-3,6,8-trisulphonic acid and/or a salt thereof and/or a naphthylamine trisulphonic acid isomer mixture and/or salt thereof with an alkali metal hydroxide solution in the presence of an alcohol and/or alcoholate and in the presence of a substance which contains at least one oxygen atom bonded to a nitrogen atom, at elevated pressure and elevated temperature, and separating out the mono-alkali metal salt of 1-amino-8-naphthol-3,6-disulphonic acid by acidification. The process results in the procurement of higher yields of the desired product and in the formation of less by-products.

摘要翻译： 已经发明了一种制备1-氨基-8-萘酚-3,6-二磺酸的单碱金属的方法，包括1-萘胺-3,6,8-三磺酸和/或其盐 和/或萘胺三磺酸异构体混合物和/或其盐与碱金属氢氧化物溶液在醇和/或醇化物的存在下，在含有至少一个与氮原子键合的氧原子的物质存在下， 在升高的压力和升高的温度下，通过酸化分离出1-氨基-8-萘酚-3,6-二磺酸的单碱金属盐。 该过程导致采购更高产量的所需产品和形成较少的副产物。

公开(公告)号：US4046796A

公开(公告)日：1977-09-06

申请号：US658815

申请日：1976-02-17

申请人： Gunther Rottloff ,  Rudolf Sundermann ,  Ernst Grigat ,  Rolf Putter

发明人： Gunther Rottloff ,  Rudolf Sundermann ,  Ernst Grigat ,  Rolf Putter

IPC分类号： C07C323/20 ,  C07C20060101 ,  C07C67/00 ,  C07C253/00 ,  C07C261/02 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C08G73/06 ,  C08G73/08 ,  C07C122/00

CPC分类号： C07C261/02

摘要： Highly pure aromatic polyfunctional cyanic acid esters having a high stability in storage and being extraordinary suitable for use as starting compound for the production of plastics by cyclopoly-trimerization are obtained by a special process. Alkaline earth and/or alkali metal salts of polyfunctional aromatic hydroxy compounds said alkaline earth and/or alkali metal compound capable of phenolate formation are used in excess of up to 0.1 mol per mol of aromatic hydroxy group are reacted with an excess of cyanogen halide. The cyanogen halide excess comprises up to 1 mol per mol of aromatic hydroxy group plus excess mol of the metal compound used for salt production.

摘要翻译： 通过特殊的方法获得高度纯度的芳香族多官能氰酸酯，其储存稳定性高，非常适用于通过环聚三聚制备塑料的起始化合物。 使多官能芳族羟基化合物的碱土金属和/或碱金属盐使用能够形成苯酚的碱土金属和/或碱金属化合物超过每摩尔芳族羟基高达0.1摩尔与过量的卤化氰反应。 氰卤化物过量包括至多1摩尔每摩尔芳族羟基加上过量的用于生产盐的金属化合物。

公开(公告)号：US3978028A

公开(公告)日：1976-08-31

申请号：US529663

申请日：1974-12-04

申请人： Rudolf Sundermann ,  Rolf Putter ,  Ernst Grigat

发明人： Rudolf Sundermann ,  Rolf Putter ,  Ernst Grigat

IPC分类号： C08G65/00 ,  C07D251/34 ,  C08G65/40 ,  C08G65/48 ,  C08G73/00 ,  C08G73/06 ,  C09K21/10

CPC分类号： C08G73/065

摘要： S-Triazine prepolymers, useful in the preparation of polytriazines, are prepared by condensing an aromatic dihydroxy or polyhydroxy compound with less than one-third mol of cyanuric chloride per hydroxy group. Thereafter the free hydroxy groups in the condensation product are reacted with a cyanogen halide in the presence of a base. The condensation is preferably carried out in a melt at temperatures of from 100.degree.-240.degree.C.

摘要翻译： 通过将芳族二羟基或多羟基化合物与每个羟基少于三分之一摩尔的氰尿酰氯缩合来制备可用于制备聚三嗪的S-三嗪预聚物。 此后，缩合产物中的游离羟基与卤化氰在碱的存在下反应。 缩合优选在熔体中在100-240℃的温度下进行。

公开(公告)号：US4341719A

公开(公告)日：1982-07-27

申请号：US238327

申请日：1981-02-26

申请人： Rolf Putter ,  Theodor Pfister ,  Manfred Niese ,  Peter Wenzl

发明人： Rolf Putter ,  Theodor Pfister ,  Manfred Niese ,  Peter Wenzl

IPC分类号： C07C309/50 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/22 ,  C07C309/47 ,  C07C143/66

CPC分类号： C07C309/00

摘要： A process for the preparation of 1-amino-2-ethoxy-naphthalene-6-sulphonic acid from 2-hydroxy-naphthalene-6-sulphonic acid which comprises:A. contacting 2-hydroxy-naphthalene-6-sulphonic acid with at least an equimolar amount of an alkali metal nitrite in aqueous solution or suspension in the presence of hydrochloric acid, solution or suspension having a pH in the range of 2 to 5 and being at a temperature of 0.degree. to 20.degree. C.;B. reducing the reaction product of step A in an aqueous suspension by contacting the same with excess iron in the presence of at least an equivalent amount of iron-II ions, relative to the reaction product obtained according to step A, in the presence of a mineral acid at a temperature from 50.degree. to 120.degree. C., and treating the thus-obtained reaction mixture with aqueous alkali metal hydroxide in the presence of iron oxide;C. contacting the product of step B with excess acetic anhydride in an aqueous solution or suspension at a pH in the range of 3 to 10 at a temperature from 0.degree. to 100.degree. C.;D. contacting the product of step C with an ethylating agent in the presence of an acid binding agent in an aqueous-organic solvent or diluent in a pH range from 8 to 14 at a temperature from 20.degree. to 150.degree. C.; andE. deacetylating the product of step D by contacting the same at reflux with an aqueous alkali metal hydroxide.

摘要翻译： 一种从2-羟基 - 萘-6-磺酸制备1-氨基-2-乙氧基 - 萘-6-磺酸的方法，其包括：A.将2-羟基 - 萘-6-磺酸与至少 在盐酸，溶液或悬浮液的存在下，在pH为2至5，温度为0至20℃的水溶液或悬浮液中，等摩尔量的碱金属亚硝酸盐。 B.通过在相对于根据步骤A获得的反应产物存在下，在至少相当量的铁-II离子的存在下，使其与过量的铁接触，将步骤A的反应产物还原在水性悬浮液中 在50〜120℃的温度下进行无机酸处理，在氧化铁存在下用碱金属氢氧化物水溶液处理得到的反应混合物; C.将步骤B的产物与过量的乙酸酐在0至100℃的温度下，在3至10的pH范围内的水溶液或悬浮液中接触。 D.在酸性粘合剂存在下，在pH范围为8-14的含水有机溶剂或稀释剂中，在20-150℃的温度下，使步骤C的产物与乙基化剂接触。 和E.通过使其与碱金属氢氧化物水溶液在回流下使其脱离乙酰化步骤D的产物。

公开(公告)号：US4028393A

公开(公告)日：1977-06-07

申请号：US658814

申请日：1976-02-17

申请人： Gunther Rottloff ,  Rudolf Sundermann ,  Ernst Grigat ,  Rolf Putter

发明人： Gunther Rottloff ,  Rudolf Sundermann ,  Ernst Grigat ,  Rolf Putter

IPC分类号： C07C323/20 ,  C07C20060101 ,  C07C67/00 ,  C07C253/00 ,  C07C261/02 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C08G73/06 ,  C07C122/00

CPC分类号： C07C261/02 ,  C07C2103/94

摘要： Highly pure aromatic polyfunctional cyanic acid esters having a high stability in storage and being extraordinarily suitable for use as starting compound for the production of plastics by cyclopoly-tri-merization are obtained by a special process.A di- or polytrialkyl ammonium phenolate of the formula: ##STR1## in which Ar represents an optionally substituted aromatic radical,R.sub.1, r.sub.2 and R.sub.3 are the same or different and each represents a linear or branched alkyl radical, andn is a number from 2 to 6,Is reacted at a temperature in the range of from -40.degree. to +65.degree. C in the presence of a trialkyl amine and an organic solvent with an excess of cyanogen halide.The excess of cyanogen halide is up to 80% by weight, based on the total weight of the phenolate and the trialkyl amine.

摘要翻译： 通过特殊的方法可获得高度稳定的储存和非常适合用作通过环状三聚化生产塑料的起始化合物的高纯度芳香族多官能氰酸酯。