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公开(公告)号：US4162234A
公开(公告)日：1979-07-24
申请号：US812072
申请日：1977-07-01
IPC分类号： B01J23/00 , B01J23/88 , B01J23/887 , B01J27/057 , B01J27/186 , B01J27/192 , C07C5/48 , C07C45/35 , C07C51/25 , B01J21/02 , B01J23/10 , B01J27/02 , B01J27/14
CPC分类号： B01J23/8873 , B01J23/002 , B01J23/887 , B01J23/8871 , B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J23/8877 , B01J23/8878 , B01J27/0576 , B01J27/186 , B01J27/192 , C07C253/26 , C07C45/35 , C07C5/48 , C07C51/252 , B01J2523/00 , Y02P20/52
摘要： Catalysts containing iron, bismuth, molybdenum plus nickel, cobalt, magnesium, zinc, cadmium, strontium or calcium are promoted with yttrium, zirconium, silver, sulfur, cerium, thorium, praseodymium, ruthenium, gallium, niobium, germanium, chromium, tin, manganese, indium, copper, tellurium, lanthanum, tantalum, tungsten or mixture thereof to give extremely desirable catalysts for various oxidation reactions.
摘要翻译： 含有铋，锆，银，硫，铈，钍，镨，钌，镓，铌，锗，铱，镓，铌，锗，镉，锡等的铁，铋，钼，镍，钴，镁， 锰，铟，铜，碲，镧，钽，钨或其混合物，以得到用于各种氧化反应的非常理想的催化剂。
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公开(公告)号：US4377534A
公开(公告)日：1983-03-22
申请号：US293822
申请日：1981-08-17
IPC分类号： B01J23/88 , B01J23/887 , B01J23/89 , C07C120/14
CPC分类号： B01J23/8873 , B01J23/8871 , B01J23/8872 , B01J23/8876 , B01J23/8993 , C07C253/26 , Y02P20/52
摘要： Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.
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3.发明授权Process for the oxidation of olefins using catalysts containing various promoter elements 失效使用含有各种促进元素的催化剂氧化烯烃的方法
公开(公告)号：US4001317A
公开(公告)日：1977-01-04
申请号：US490428
申请日：1974-07-22
IPC分类号： B01J23/88 , B01J23/887 , B01J23/89 , B01J27/02 , B01J27/192 , C07C45/34 , C07C45/35 , C07C51/25 , C07C51/32 , C07C45/04
CPC分类号： B01J23/8873 , B01J23/8872 , B01J23/8875 , B01J23/8876 , B01J23/8993 , B01J27/02 , B01J27/192 , C07C45/34 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from germanium, cerium, thorium, manganese, niobium, chromium, praseodymium, yttrium, zirconium, ruthenium, gallium, tin, indium, copper, lanthanum, tantalum or tungsten. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.
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公开(公告)号：US4327037A
公开(公告)日：1982-04-27
申请号：US881313
申请日：1978-02-27
IPC分类号： B01J23/887 , B01J23/89 , C07C120/14
CPC分类号： C07C253/26 , B01J23/8876 , B01J23/8993 , Y02P20/52
摘要： Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.
摘要翻译： 已经发现含铁，钼，铋和镍，钴，镁，锌，镉，钙或铍的催化剂在给定的时间内给予特别大量的丙烯腈或甲基丙烯腈，当锰，锑，钍，锆，钇或其混合物 被引入到催化剂中。
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5.发明授权Process for the oxidation of olefins using catalysts containing various promoter elements 失效使用含有各种启动子元素的催化剂进行烯烃氧化的方法
公开(公告)号：US4190608A
公开(公告)日：1980-02-26
申请号：US717838
申请日：1976-08-26
IPC分类号： B01J23/887 , B01J23/89 , B01J27/192 , C07C45/35 , C07C51/25 , C07C47/20 , C07C51/20
CPC分类号： C07C45/35 , B01J23/8876 , B01J23/8993 , B01J27/192 , C07C51/252 , B01J2523/00
摘要： The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from germanium, cerium, thorium, manganese, niobium, chromium, praseodymium, yttrium, zirconium, ruthenium, gallium, tin, indium, copper, lanthanum, tantalum or tungsten. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.
摘要翻译： 本发明是使用含有铁，铋，钼加上镍，钴，镁，锌，镉或钙中的至少一种的催化剂将烯烃氧化成不饱和醛和酸的方法，根据本发明，选择的元素 来自锗，铈，钍，锰，铌，铬，镨，钇，锆，钌，镓，锡，铟，铜，镧，钽或钨。 这些催化剂还可以含有进一步提高氧化工艺需要的某些元素。
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公开(公告)号：US4139552A
公开(公告)日：1979-02-13
申请号：US430964
申请日：1974-01-04
IPC分类号： B01J23/88 , B01J23/881 , C07C120/14
CPC分类号： B01J23/8876 , B01J23/002 , B01J23/88 , B01J23/881 , B01J23/8898 , C07C253/26 , B01J2523/00 , Y02P20/52
摘要： Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.
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公开(公告)号：US4323703A
公开(公告)日：1982-04-06
申请号：US800981
申请日：1977-05-26
IPC分类号： B01J23/887 , B01J27/192 , C07C51/25 , C07C45/35
CPC分类号： C07C45/35 , B01J23/8876 , B01J27/192 , C07C51/252 , B01J2523/00
摘要： The process comprises the vapor phase oxidation of lower molecular weight olefins to the corresponding unsaturated aldehydes and unsaturated carboxylic acids in the presence of a catalyst comprising the oxides of iron, bismuth, molybdenum and at least one element of the Group II elements as essential components, and optionally the oxides of phosphorus, arsenic and an alkali metal.
摘要翻译： 该方法包括在包含铁，铋，钼和至少一种II族元素的元素作为必要组分的催化剂存在下，将低分子量烯烃气相氧化成相应的不饱和醛和不饱和羧酸， 和任选的磷，砷和碱金属的氧化物。
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公开(公告)号：US4192776A
公开(公告)日：1980-03-11
申请号：US866203
申请日：1978-01-03
IPC分类号： B01J23/887 , B01J21/02 , B01J23/10 , B01J23/84 , B01J27/14
CPC分类号： C07C253/26 , B01J23/8876 , B01J23/8877 , Y02P20/52
摘要： Catalysts containing a rare earth, tantalum or niobium plus iron, bismuth and molybdenum and at least one element of nickel, cobalt, magnesium, zinc, cadmium or calcium are especially effective for the ammoxidation of olefins.
摘要翻译： 包含稀土，钽或铌加铁，铋和钼以及镍，钴，镁，锌，镉或钙的至少一种元素的催化剂对于烯烃的氨氧化是特别有效的。
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公开(公告)号：US4778930A
公开(公告)日：1988-10-18
申请号：US726279
申请日：1985-04-24
IPC分类号： B01J23/88 , B01J23/89 , B01J27/02 , B01J27/192 , C07C45/34 , C07C45/35 , C07C51/25 , C07C45/00 , C07C47/28
CPC分类号： B01J23/8872 , B01J23/002 , B01J23/8876 , B01J23/8993 , B01J27/02 , B01J27/192 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing antimony, iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium within certain compositional limits. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.
摘要翻译： 本发明是在某些组成范围内使用含有锑，铁，铋，钼以及镍，钴，镁，锌，镉或钙中的至少一种的催化剂将烯烃氧化成不饱和醛和酸的方法。 这些催化剂还可以含有进一步提高氧化工艺需要的某些元素。
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公开(公告)号：US4503001A
公开(公告)日：1985-03-05
申请号：US373904
申请日：1982-05-03
IPC分类号： B01J23/887 , B01J27/186 , C07C120/14
CPC分类号： C07C253/26 , B01J23/8876 , B01J27/186 , Y02P20/52
摘要： Monoolefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and a molecular oxygen-containing gas in the presence of a catalyst containing the oxides of iron, bismuth, molybdenum, and cobalt or nickel or both, and optionally an oxide of at least one element selected from the group consisting of the alkali metals, rare earth metals, tantalum and niobium, and optionally one or more of the oxides of the elements selected from the group consisting of phosphorus and arsenic.
摘要翻译： 通过使烯烃，氨和含分子氧气体的混合物在含铁氧化物，铋的催化剂存在下，分别将丙烯和异丁烯等单烯烃转化为相应的不饱和腈，丙烯腈和甲基丙烯腈 ，钼和钴或镍或两者，以及任选的选自碱金属，稀土金属，钽和铌中的至少一种元素的氧化物，以及任选的一种或多种选自以下的元素的氧化物： 由磷和砷组成的组。
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