NANOCOMPOSITE PARTICLES OF CONVERSION CHEMISTRY AND MIXED ELECTRONIC IONIC CONDUCTOR MATERIALS
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    发明申请
    NANOCOMPOSITE PARTICLES OF CONVERSION CHEMISTRY AND MIXED ELECTRONIC IONIC CONDUCTOR MATERIALS 审中-公开
    转化化学和混合电子离子导体材料的纳米复合颗粒

    公开(公告)号:US20160164135A1

    公开(公告)日:2016-06-09

    申请号:US14827105

    申请日:2015-08-14

    摘要: Positive electrode films for a Li-secondary battery are provided. The films include composite particles including a mixed electronic ionic conductor (MEIC), a metal fluoride (MF), and optionally an electrically conductive additive comprising carbon. The films include a catholyte and a binder that are both in contact with the composite particle surfaces but not contained therein. The composite particles are characterized by a porosity of less than about 15% v/v at 25° C. Methods of forming positive electrode films for a Li-secondary battery are also provided. Methods of forming positive electrode films including annealed composite particles for a Li-secondary battery are also provided. The methods include preparing a composite including a mixed electronic ionic conductor (MEIC) including a member selected from metal oxides, metal sulfides, metal halides, metal oxyhalides, and combinations thereof, a nanodimensioned metal fluoride (MF), optionally a binder, and optionally an electrically conductive additive comprising carbon.

    摘要翻译: 提供了用于锂二次电池的正电极膜。 膜包括复合颗粒,包括混合电子离子导体(MEIC),金属氟化物(MF)和任选的包含碳的导电添加剂。 膜包括与复合颗粒表面接触但不包含在其中的阴极电解液和粘合剂。 复合颗粒的特征在于在25℃下孔隙率小于约15%v / v。还提供了形成Li-二次电池的正极膜的方法。 还提供了形成用于锂二次电池的退火复合颗粒的正电极膜的方法。 所述方法包括制备包括包含选自金属氧化物,金属硫化物,金属卤化物,金属卤化物及其组合的组分的混合电子离子导体(MEIC)的复合材料,纳米尺寸金属氟化物(MF),任选的粘合剂,以及任选地 包含碳的导电添加剂。