公开(公告)号：US10147513B2

公开(公告)日：2018-12-04

申请号：US15341686

申请日：2016-11-02

Applicant: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.

Inventor： Yuji Zenitani ,  Takashi Nishihara ,  Tetsuya Asano

IPC: H01B1/02 ,  H01B1/00 ,  H01B1/08 ,  C01G25/00 ,  H01M8/124

Abstract: An exemplary proton conductor according to the present disclosure has a perovskite-type crystal structure expressed by the compositional formula AaB1-xB′xO3-δ, where A is at least one selected from among group 2 elements; B is a group 4 element or Ce; B′ is a group 3 element, a group 13 element, or a lanthanoid element; 0.5

公开(公告)号：US09458544B2

公开(公告)日：2016-10-04

申请号：US14604882

申请日：2015-01-26

Applicant: Panasonic Intellectual Property Management Co., Ltd.

Inventor： Yuji Zenitani ,  Takashi Nishihara ,  Tetsuya Asano ,  Akihiro Itou ,  Saifullah Badar

IPC: C25B9/08

CPC classification number: C25B9/08 ,  C25B3/00 ,  C25B11/0478 ,  C25B13/04

Abstract: An exemplary organic hydride conversion device for generating a hydrogen gas through organic hydride conversion according to the present disclosure comprises an anode containing a dehydrogenation catalyst, a cathode containing hydrogenation catalyst, and a proton conductor disposed between the anode and the cathode. The proton conductor has a perovskite crystal structure expressed by the compositional formula AaB1-xB′xO3-x. The A element is an alkaline-earth metal and is contained in a range of 0.4

Abstract translation: 根据本公开通过有机氢化物转化产生氢气的示例性有机氢化物转化装置包括含有脱氢催化剂的阳极，包含氢化催化剂的阴极和设置在阳极和阴极之间的质子导体。 质子导体具有由组成式AaB1-xB'xO3-x表示的钙钛矿晶体结构。 A元素是碱土金属，其含量在0.4

公开(公告)号：US10556794B2

公开(公告)日：2020-02-11

申请号：US15612475

申请日：2017-06-02

Applicant: Panasonic Intellectual Property Management Co., Ltd.

Inventor： Manabu Kanou ,  Yuki Nakata ,  Yuji Zenitani ,  Hyunjeong Nam ,  Saifullah Badar

IPC: C01B3/00 ,  C07C5/32 ,  C25B3/00 ,  C25B3/02

Abstract: The desorbing process of the present disclosure includes a step of bringing a solution containing a hydrogenated aromatic compound, at least one of [P((CH2)mCH3)3((CH2)nCH3) (5≤m≤24, 13≤n≤24)]+ and [N((CH2)mCH3)3((CH2)nCH3) (5≤m≤24, 13≤n≤24)]+, and an anion into contact with an anode; and desorbing hydrogen from the hydrogenated aromatic compound.

公开(公告)号：US09466852B2

公开(公告)日：2016-10-11

申请号：US14582761

申请日：2014-12-24

Applicant: Panasonic Intellectual Property Management Co., Ltd.

Inventor： Tomoyuki Komori ,  Yuji Zenitani ,  Takashi Nishihara

IPC: H01M8/10 ,  C23C14/08 ,  C30B29/22 ,  H01M8/12 ,  H01M4/86 ,  H01M4/92 ,  H01M4/88 ,  H01B1/12 ,  C30B29/02 ,  C25B9/08 ,  C25B13/04 ,  C30B23/02 ,  C23C14/18

CPC classification number: H01M8/1004 ,  C23C14/08 ,  C23C14/185 ,  C25B9/08 ,  C25B13/04 ,  C30B23/02 ,  C30B29/02 ,  C30B29/22 ,  H01B1/122 ,  H01M4/86 ,  H01M4/881 ,  H01M4/92 ,  H01M8/1016 ,  H01M8/12 ,  H01M8/1213 ,  H01M8/1253 ,  H01M2008/1293 ,  H01M2300/0071 ,  H01M2300/0074 ,  Y02E60/521 ,  Y02E60/525

Abstract: A proton conductor includes an electrolytic layer having first and second main surfaces; and a plurality of catalyst particles. The first main surface of the electrolytic layer includes a flat portion and a plurality of recessed portions. The plurality of catalyst particles are respectively located in the plurality of recessed portions. The flat portion of the first main surface and parts of surfaces of the plurality of catalyst particles exposed from the plurality of recessed portions form a third main surface. The electrolytic layer is formed of a single crystal of a perovskite-type oxide having a proton conductivity. The catalyst particles are formed of a single crystal of a noble metal material. The perovskite-type oxide of the electrolytic layer) has a crystal orientation that matches a crystal orientation of the noble metal material of the plurality of catalyst particles.

Abstract translation: 质子导体包括具有第一和第二主表面的电解质层; 和多个催化剂颗粒。 电解质层的第一主表面包括平坦部分和多个凹陷部分。 多个催化剂粒子分别位于多个凹部中。 第一主表面的平坦部分和从多个凹部露出的多个催化剂颗粒的表面的一部分形成第三主表面。 电解质层由具有质子传导性的钙钛矿型氧化物的单晶形成。 催化剂颗粒由贵金属材料的单晶形成。 电解质层的钙钛矿型氧化物）具有与多个催化剂粒子的贵金属材料的结晶取向一致的结晶取向。

公开(公告)号：US10301177B2

公开(公告)日：2019-05-28

申请号：US15612074

申请日：2017-06-02

Applicant: Panasonic Intellectual Property Management Co., Ltd.

Inventor： Yuki Nakata ,  Hyunjeong Nam ,  Saifullah Badar ,  Manabu Kanou ,  Yuji Zenitani

IPC: C25B3/00 ,  C25B3/04 ,  C01B3/00 ,  C07C5/367 ,  C25B1/02 ,  C25B11/04 ,  G01N30/02 ,  C25B13/08 ,  C25B15/00

Abstract: A hydrogen desorption method includes a step of bringing a liquid containing an alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain, a quinone, and an electrolyte into contact with a anode and a step of desorbing hydrogen from the alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain.

公开(公告)号：US09896771B2

公开(公告)日：2018-02-20

申请号：US14606972

申请日：2015-01-27

Applicant: Panasonic Intellectual Property Management Co., Ltd.

Inventor： Yuji Zenitani ,  Takashi Nishihara ,  Tetsuya Asano ,  Akihiro Itou ,  Hiroki Takeuchi

IPC: C25B1/02 ,  C25B9/08 ,  C25B13/04 ,  C01B3/50

CPC classification number: C25B1/02 ,  C01B3/505 ,  C25B9/08 ,  C25B13/04

Abstract: An exemplary dehydrogenation device for generating a hydrogen gas through dehydrogenation according to the present disclosure comprises an anode containing a dehydrogenation catalyst, a cathode containing catalyst capable of reducing protons, and a proton conductor disposed between the anode and the cathode. The proton conductor has a perovskite crystal structure expressed by the compositional formula AaB1-xB′xO3-δ. The A element is an alkaline-earth metal and is contained in a range of 0.4