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公开(公告)号：US11945249B2
公开(公告)日：2024-04-02
申请号：US17441059
申请日：2020-02-25
CPC分类号： B41M5/3372 , B41M5/323 , B41M2205/04
摘要： The present invention provides a thermosensitive recording medium having a high degree of water resistance and excellent surface qualities. The thermosensitive recording medium has a thermosensitive recording layer comprising a colorless or pale colored basic leuco dye and an electron accepting developing agent on a substrate, but does not have a protective layer on the thermosensitive recording layer, and the thermosensitive recording layer further comprises (i) a carboxy-modified polyvinyl alcohol as a binder, (ii) an epichlorohydrin resin and a modified polyamine/amide resin (excluding those contained in the category of epichlorohydrin resin) as crosslinking agents, and (iii) an acrylic resin with a glass transition temperature (Tg) of lower than or equal to 50 degree C. and a minimum film forming temperature (MFT) of higher than or equal to 40 degree C.
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公开(公告)号：US10464362B2
公开(公告)日：2019-11-05
申请号：US15770053
申请日：2016-10-19
发明人： Yasuaki Matsumori , Akihito Ogino , Kenji Hirai
摘要： As a thermosensitive recording medium utilizes a coloring reaction between a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent, a thermosensitive recording medium using an environment-friendly color developing agent is provided. Provided is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer comprises a gluconolactone as the electron accepting color developing agent.
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公开(公告)号：US11613850B2
公开(公告)日：2023-03-28
申请号：US17276092
申请日：2019-09-19
发明人： Junji Yamamoto , Youko Jyoumei , Kenji Hirai
摘要： An object is to provide a base paper for paper tubes that has lower environmental impact and is used for manufacturing of paper tubes offering excellent water resistance. As a solution, a base paper for paper tubes is provided, wherein: it has two or more but no more than five paper layers; the paper layers are bonded by a water-soluble or water-dispersible adhesive; and its elution rate is 2.0 percent or lower.
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公开(公告)号：US20230027721A1
公开(公告)日：2023-01-26
申请号：US17784584
申请日：2020-12-08
发明人： Kenji Hirai , Yoshimi Midorikawa , Yuka Murata , Kentaro Kawasaki
IPC分类号： B41M5/44 , B41M5/333 , C08F265/06 , C08F2/24 , C08F2/44
摘要： Provided is a thermosensitive recording medium having a sufficient water resistance to moisture and humidity, such as for outdoor use in rainy weather and the like, and also having a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like. As the protective layer comprises a specific silane-modified acrylic resin which is an aqueous emulsion of core-shell type p articles, in a thermosensitive recording medium having a thermosensitive recording layer on a substrate and a protective layer on the thermosensitive recording layer, the thermosensitive re cording medium has a sufficient water resistance and also has a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like.
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公开(公告)号：US12053997B2
公开(公告)日：2024-08-06
申请号：US17784584
申请日：2020-12-08
发明人： Kenji Hirai , Yoshimi Midorikawa , Yuka Murata , Kentaro Kawasaki
IPC分类号： B41M5/44 , B41M5/333 , B41M5/337 , C08F2/26 , C08F265/06
CPC分类号： B41M5/443 , B41M5/3333 , B41M5/3372 , B41M5/44 , C08F2/26 , C08F265/06 , B41M2205/04 , B41M2205/40 , C08F265/06 , C08F220/14 , C08F220/1804 , C08F220/1804 , C08F220/1806 , C08F230/085 , C08F216/1491
摘要： Provided is a thermosensitive recording medium having a sufficient water resistance to moisture and humidity, such as for outdoor use in rainy weather and the like, and also having a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like. As the protective layer comprises a specific silane-modified acrylic resin which is an aqueous emulsion of core-shell type p articles, in a thermosensitive recording medium having a thermosensitive recording layer on a substrate and a protective layer on the thermosensitive recording layer, the thermosensitive re cording medium has a sufficient water resistance and also has a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like.
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公开(公告)号：US10000083B2
公开(公告)日：2018-06-19
申请号：US15318813
申请日：2015-05-26
发明人： Akihito Ogino , Kenji Hirai
CPC分类号： B41M5/3336 , B41M5/323 , B41M5/3333 , B41M5/3372 , B41M5/3377 , B41M5/42 , B41M5/426 , B41M5/44 , B41M2205/04 , B41M2205/40
摘要： A thermosensitive recording medium is provided that is excellent in heat discoloration resistance in the blank portions and in bar code readability. It also has excellent water resistance and printing (recording) run-ability. The thermosensitive recording medium includes a support, a thermosensitive recording layer installed on the support, and a protective layer on the thermosensitive recording layer. The thermosensitive recording layer contains two kinds of electron accepting color developing agents, a sulfonic acid compound and a diphenyl sulfone compound. Both the thermosensitive recording layer and the protective layer contain crosslinking agents, and at least one, and preferably both, of the thermosensitive recording layer and the protective layer contain an ammonium zirconium carbonate as the crosslinking agent.
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公开(公告)号：US20170129266A1
公开(公告)日：2017-05-11
申请号：US15318813
申请日：2015-05-26
发明人： Akihito Ogino , Kenji Hirai
CPC分类号： B41M5/3336 , B41M5/323 , B41M5/3333 , B41M5/3372 , B41M5/3377 , B41M5/42 , B41M5/426 , B41M5/44 , B41M2205/04 , B41M2205/40
摘要： A thermosensitive recording medium is provided that is excellent in heat discoloration resistance in the blank portions and in bar code readability. It also has excellent water resistance and printing (recording) run-ability. The thermosensitive recording medium includes a support, a thermosensitive recording layer installed on the support, and a protective layer on the thermosensitive recording layer. The thermosensitive recording layer contains two kinds of electron accepting color developing agents, a sulfonic acid compound and a diphenyl sulfone compound. Both the thermosensitive recording layer and the protective layer contain crosslinking agents, and at least one, and preferably both, of the thermosensitive recording layer and the protective layer contain an ammonium zirconium carbonate as the crosslinking agent.
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公开(公告)号：US11912052B2
公开(公告)日：2024-02-27
申请号：US17776334
申请日：2020-11-11
发明人： Kentaro Kawasaki , Yuka Murata , Kenji Hirai , Yoshimi Midorikawa
CPC分类号： B41M5/42 , B41M5/323 , B41M5/333 , B41M5/3331 , C09B7/00 , C09B67/0065 , B41M5/327 , B41M5/3275 , B41M5/3333 , B41M5/48 , B41M2205/32
摘要： Provided is a thermosensitive recording medium having excellent oil resistance among various performances required for the thermosensitive recording medium. The thermosensitive recording medium has a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains N-[2-(3-phenylureido)phenyl] benzenesulfonamide and an urea-based compound represented by the general formula 1 as the electron accepting color developing agents,
wherein R1 represents a substituted or unsubstituted alkyl group, aralkyl group or aryl group, and R2 represents a hydrogen atom or an alkyl group.-
公开(公告)号：US20230144275A1
公开(公告)日：2023-05-11
申请号：US17802599
申请日：2021-02-08
发明人： Kenji Hirai , Kentaro Kawasaki , Yuka Murata , Yoshimi Midorikawa
IPC分类号： B41M5/333
CPC分类号： B41M5/3336 , B41M2205/04
摘要： Provided is a thermosensitive recording medium being excellent in oil resistance among various performances required for the thermosensitive recording medium, and being further excellent in heat resistance, plasticizer resistance, and printing (recording) run-ability.
That is a thermosensitive recording medium having a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains at least two kinds of urea compounds. The two kinds of urea compounds comprise the first urea compound being represented by the following general formula 1, and the second urea compound being represented by the following general formula 2.
wherein R1 represents a substituted or unsubstituted alkyl group, aralkyl group or aryl group, and R2 represents a hydrogen atom or an alkyl group,
wherein R4 to R8 represent a hydrogen atom, a halogen atom, a nitro group, an amino group, an alkyl group, an alkoxy group, an aryloxy group, and the like, and m represents an integer of 0 to 2.-
公开(公告)号：US20220410610A1
公开(公告)日：2022-12-29
申请号：US17776334
申请日：2020-11-11
发明人： Kentaro Kawasaki , Yuka Murata , Kenji Hirai , Yoshimi Midorikawa
摘要： Provided is a thermosensitive recording medium having excellent oil resistance among various performances required for the thermosensitive recording medium. The thermosensitive recording medium has a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains N-[2-(3-phenylureido)phenyl] benzenesulfonamide and an urea-based compound represented by the general formula 1 as the electron accepting color developing agents, wherein R1 represents a substituted or unsubstituted alkyl group, aralkyl group or aryl group, and R2 represents a hydrogen atom or an alkyl group.
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