公开(公告)号：US09249067B2

公开(公告)日：2016-02-02

申请号：US13642676

申请日：2011-04-15

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

IPC分类号： C07C2/66 ,  C07C7/12

CPC分类号： C07C2/66 ,  C07C7/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085 ,  C07C15/04

摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in−1 (12 cm−1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.

公开(公告)号：US20130211164A1

公开(公告)日：2013-08-15

申请号：US13642676

申请日：2011-04-15

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C7/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085 ,  C07C15/04

摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in−1 (12 cm−1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.

摘要翻译： 本发明提供了一种由至少部分未经处理的具有催化剂毒素和烷基化剂的可烷化芳族化合物制备烷基化芳族化合物的改进方法，其中用具有表面积的处理组合物处理所述可烷基化芳族化合物流以减少催化剂毒物 /表面体积比大于或等于30in-1（12cm-1）在处理区域与烷基化反应区分离，处理条件包括温度为约30℃至约300℃至 形成包含所述经处理的可烷基化芳族化合物的流出物。

公开(公告)号：US20130197287A1

公开(公告)日：2013-08-01

申请号：US13642690

申请日：2011-04-15

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

IPC分类号： C07C2/66 ,  C07C7/12

CPC分类号： C07C2/66 ,  C07C7/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085 ,  C07C15/04

摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in−1 (12 cm−1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.

摘要翻译： 本发明提供了一种由至少部分未处理的具有催化剂毒物的可烷化芳族化合物制备烷基化芳族化合物的改进方法，其中用具有表面积/表面体积比的处理组合物处理所述可烷基化芳族化合物流以还原催化剂毒物 在包括温度为约30℃至约300℃的处理条件下与烷基化反应区分离的处理区中大于或等于30in -1（12cm -1），以形成流出物，其包含 所述经处理的可烷基化芳族化合物。

公开(公告)号：US08993820B2

公开(公告)日：2015-03-31

申请号：US13642690

申请日：2011-04-15

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Terry E. Helton

IPC分类号： C07C2/66 ,  C07C7/12

CPC分类号： C07C2/66 ,  C07C7/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085 ,  C07C15/04

摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in−1 (12 cm−1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.

摘要翻译： 本发明提供了一种由至少部分未处理的具有催化剂毒物的可烷化芳族化合物制备烷基化芳族化合物的改进方法，其中用具有表面积/表面体积比的处理组合物处理所述可烷基化芳族化合物流以还原催化剂毒物 在包括温度为约30℃至约300℃的处理条件下与烷基化反应区分离的处理区中大于或等于30in -1（12cm -1），以形成流出物，其包含 所述经处理的可烷基化芳族化合物。

公开(公告)号：US20110224469A1

公开(公告)日：2011-09-15

申请号：US12721326

申请日：2010-03-10

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Maruti Bhandarkar ,  Brian Maerz ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Maruti Bhandarkar ,  Brian Maerz ,  Terry E. Helton

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C6/126 ,  C07C7/13 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  C07C15/04 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02

摘要： Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound.

摘要翻译： 公开了通过在第一和第二烷基化催化剂存在下使包含可烷基化芳族化合物，烷基化剂和痕量水和杂质的进料流接触来生产烷基化芳族化合物的方法，其中除去水和杂质以改善 这种烷基化催化剂的循环长度。 在脱水区中除去水和一部分杂质。 具有第一烷基化催化剂的第一烷基化区，在一些实施方案中为大孔分子筛，起到除去较大部分杂质如氮和其它物质的作用，并将较小部分的可烷基化芳族化合物烷基化。 在一些实施方案中，第二烷基化区是中孔分子筛，起到除去较少部分杂质的作用，并使大部分可烷基化芳族化合物烷基化。

公开(公告)号：US08629311B2

公开(公告)日：2014-01-14

申请号：US12721326

申请日：2010-03-10

申请人： Matthew J. Vincent ,  Vijay Nanda ,  Maruti Bhandarkar ,  Brian Maerz ,  Terry E. Helton

发明人： Matthew J. Vincent ,  Vijay Nanda ,  Maruti Bhandarkar ,  Brian Maerz ,  Terry E. Helton

IPC分类号： C07C2/66 ,  C07C6/12

CPC分类号： C07C2/66 ,  C07C6/126 ,  C07C7/13 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  C07C15/04 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02

摘要： Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound.

摘要翻译： 公开了通过在第一和第二烷基化催化剂存在下使包含可烷基化芳族化合物，烷基化剂和痕量水和杂质的进料流接触来生产烷基化芳族化合物的方法，其中除去水和杂质以改善 这种烷基化催化剂的循环长度。 在脱水区中除去水和一部分杂质。 具有第一烷基化催化剂的第一烷基化区，在一些实施方案中为大孔分子筛，起到除去较大部分杂质如氮和其它物质的作用，并将较小部分的可烷基化芳族化合物烷基化。 在一些实施方案中，第二烷基化区是中孔分子筛，起到除去较少部分杂质的作用，并使大部分可烷基化芳族化合物烷基化。

公开(公告)号：US07777087B2

公开(公告)日：2010-08-17

申请号：US12624118

申请日：2009-11-23

申请人： Michael C. Clark ,  Vijay Nanda ,  Chung-Ming Chi ,  Maruti Bhandarkar ,  Brian Maerz ,  Matthew J. Vincent

发明人： Michael C. Clark ,  Vijay Nanda ,  Chung-Ming Chi ,  Maruti Bhandarkar ,  Brian Maerz ,  Matthew J. Vincent

IPC分类号： C07C2/66

CPC分类号： C10G29/205 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/02 ,  C07C15/085

摘要： A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone.

摘要翻译： 公开了一种在多级反应体系中生产烷基芳族化合物的方法，其包含至少第一和第二串联连接的烷基化反应区，每个含有烷基化催化剂。 将包含可烷基化芳族化合物和包含烯烃的第二进料的第一进料引入第一烷基化反应区。 第一烷基化反应区和第二烷基化反应区在温度和压力有效的条件下运行，以在烷基化催化剂存在下使芳族化合物与烯烃进行烷基化，温度和压力使芳族化合物至少部分在 液相。 在第一烷基化反应区（其可以是反应器保护床）中的烷基化催化剂与第二反应区中的烷基化催化剂相比，每单位体积催化剂具有更多的酸性位点。

公开(公告)号：US09322793B2

公开(公告)日：2016-04-26

申请号：US13640344

申请日：2011-04-08

申请人： Matthew J. Vincent ,  David L. Fletcher ,  Vijay Nanda

发明人： Matthew J. Vincent ,  David L. Fletcher ,  Vijay Nanda

IPC分类号： G01N25/00 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  C10G29/20 ,  C10G45/72 ,  C10G47/36 ,  C10G61/00 ,  C10G69/12 ,  B01J29/70

CPC分类号： G01N25/00 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J29/70 ,  B01J29/7038 ,  C07C2/70 ,  C07C2529/06 ,  C10G29/205 ,  C10G45/08 ,  C10G45/72 ,  C10G47/36 ,  C10G61/00 ,  C10G69/123 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2400/30

摘要： Disclosed is a method for determining when to replace a guard bed material used to remove one or more catalyst poisons from a feed based on a parameter change in a process. A guard bed having a guard bed material is in fluid communication with a catalyst bed having a catalyst. At least three monitors are positioned in said guard bed or said catalyst bed and at least one parameter of the guard bed or catalyst bed is monitored. A feed component comprising one or more catalyst poisons is supplied to said guard bed or said catalyst bed. The feed is contacted with said guard bed material or said catalyst to remove at least a portion of a catalyst poison and to form a product which produces an increase or a decrease in said parameter. The monitored parameters are compared to determine when to replace the guard bed material.

公开(公告)号：US20130203179A1

公开(公告)日：2013-08-08

申请号：US13640344

申请日：2011-04-08

申请人： Matthew J. Vincent ,  David L. Fletcher ,  Vijay Nanda

发明人： Matthew J. Vincent ,  David L. Fletcher ,  Vijay Nanda

IPC分类号： G01N25/00

CPC分类号： G01N25/00 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J29/70 ,  B01J29/7038 ,  C07C2/70 ,  C07C2529/06 ,  C10G29/205 ,  C10G45/08 ,  C10G45/72 ,  C10G47/36 ,  C10G61/00 ,  C10G69/123 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2400/30

摘要： Disclosed is a method for determining when to replace a guard bed material used to remove one or more catalyst poisons from a feed based on a parameter change in a process. A guard bed having a guard bed material is in fluid communication with a catalyst bed having a catalyst. At least three monitors are positioned in said guard bed or said catalyst bed and at least one parameter of the guard bed or catalyst bed is monitored. A feed component comprising one or more catalyst poisons is supplied to said guard bed or said catalyst bed. The feed is contacted with said guard bed material or said catalyst to remove at least a portion of a catalyst poison and to form a product which produces an increase or a decrease in said parameter. The monitored parameters are compared to determine when to replace the guard bed material.

摘要翻译： 公开了一种用于基于过程中的参数变化来确定何时更换用于从进料中去除一种或多种催化剂毒物的保护床材料的方法。 具有防护床材料的保护床与具有催化剂的催化剂床流体连通。 至少三个监视器位于所述保护床或所述催化剂床中，并且监视保护床或催化剂床的至少一个参数。 将包含一种或多种催化剂毒物的进料组分供应到所述保护床或所述催化剂床。 进料与所述保护床材料或所述催化剂接触以除去至少一部分催化剂毒物并形成产生所述参数的增加或减少的产物。 比较监测的参数，以确定何时更换防护层材料。

公开(公告)号：US20100069693A1

公开(公告)日：2010-03-18

申请号：US12624118

申请日：2009-11-23

申请人： Michael C. Clark ,  Vijay Nanda ,  Chung-Ming Chi ,  Maruti Bhamdarkar ,  Brian Maerz ,  Matthew J. Vincent

发明人： Michael C. Clark ,  Vijay Nanda ,  Chung-Ming Chi ,  Maruti Bhamdarkar ,  Brian Maerz ,  Matthew J. Vincent

IPC分类号： C07C2/00

CPC分类号： C10G29/205 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/02 ,  C07C15/085

摘要： A process is disclosed for producing an alkylaromatic compound in a multistage reaction system comprising at least first and second series-connected alkylation reaction zones, each containing an alkylation catalyst. A first feed comprising an alkylatable aromatic compound and a second feed comprising an alkene are introduced into the first alkylation reaction zone. The first and second alkylation reaction zones are operated under conditions of temperature and pressure effective to cause alkylation of the aromatic compound with the alkene in the presence of the alkylation catalyst, the temperature and pressure being such that the aromatic compound is at least partly in the liquid phase. The alkylation catalyst in the first alkylation reaction zone, which may be a reactor guard bed, has more acid sites per unit volume of catalyst than the alkylation catalyst in the second reaction zone.

摘要翻译： 公开了一种在多级反应体系中生产烷基芳族化合物的方法，其包含至少第一和第二串联连接的烷基化反应区，每个含有烷基化催化剂。 将包含可烷基化芳族化合物和包含烯烃的第二进料的第一进料引入第一烷基化反应区。 第一烷基化反应区和第二烷基化反应区在温度和压力有效的条件下运行，以在烷基化催化剂存在下使芳族化合物与烯烃进行烷基化，温度和压力使芳族化合物至少部分在 液相。 在第一烷基化反应区（其可以是反应器保护床）中的烷基化催化剂与第二反应区中的烷基化催化剂相比，每单位体积催化剂具有更多的酸性位点。