Abstract:
Multijunction solar cell structures (100) including high quality epitaxial layers of monocrystalline semiconductor materials that are grown overlying monocrystalline substrates (102) such as large silicon wafers by forming a compliant substrate for growing the monocrystalline layers are disclosed. One way to achieve the formation of a compliant substrate includes first growing an accommodating buffer layer (104) on a silicon wafer. The accommodating buffer (104) layer is a layer of monocrystalline material spaced apart from the silicon wafer by an amorphous interface layer (112) of silicon oxide. The amorphous interface layer (112) dissipates strain and permits the growth of a high quality monocrystalline oxide accommodating buffer layer. Multiple and varied accommodating buffer layers can be used to achieve the monolithic integration of multiple non-lattice matched solar cell junctions.
Abstract:
Islands of compound semiconductor material can be formed in silicon wafers by etching wells into the silicon wafer, growing an accommodating layer on the silicon wafer, and then growing a compound semiconductor layer on the accommodating layer. The accommodating layer may be a layer of monocrystalline oxide and an amorphous interface layer of silicon oxide separating the monocrystalline oxide from the silicon wafer. The layer or layers that make up the accommodating layer can be annealed to form a single amorphous layer. A template layer may be grown between the accommodating layer and the monocrystalline compound semiconductor layer. The various layers follow the contours of the wells in the silicon wafer. A polishing step removes the various layers except in the wells, leaving a flat silicon surface having islands of monocrystalline compound semiconductor material separated from the silicon by the accommodating layer, and by the template layer if present. Electronic components may be formed in the silicon and/or the monocrystalline compound semiconductor material.