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公开(公告)号：US12097481B2
公开(公告)日：2024-09-24
申请号：US17260525
申请日：2019-07-22
发明人： Jose Casaban-Julian , John Breen , Conor Hamill
CPC分类号： B01J20/28011 , B01J20/226 , B01J20/28064 , B01J20/28066 , B01J20/3007 , B01J20/3085 , B01J2220/46
摘要： This invention relates to a continuous process for the preparation of a metal-organic framework comprising a hydrophobic compound. The process comprises the steps of: (a) providing a first component comprising either (i) a metal-organic framework, or (ii) a first reactant which includes at least one metal in ionic form and a second reactant which includes at least one ligand capable of associating with the metal in ionic form in order to form a metal-organic framework. (b) providing a hydrophobic compound, and (c) mixing the first component and the hydrophobic compound in order to form the metal-organic framework comprising the hydrophobic compound. The invention also relates to the use of a hydrophobic polymer, a silane compound and/or a siloxane compound to improve the water stability of a metal-organic framework.
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公开(公告)号：US11458455B2
公开(公告)日：2022-10-04
申请号：US16772359
申请日：2018-12-06
发明人： Stuart James , Paschal McCloskey , Mark Garrett , Conor Hamill , Jose Casaban-Julian , John Breen
摘要： A process for the preparation of a shaped MOF, the process comprising: providing a first reactant comprising at least one metal in ionic form and a second reactant comprising at least one organic ligand capable of associating with said metal in ionic form, and optionally a solvent; allowing the first and second reactants to react to form a MOF; and forming a shaped body directly from the mixture of step b) using an extruder or continuous kneader; wherein the initial ratio of the at least one metal in ionic form to the at least one organic ligand is controlled such that shaped bodies having a minimum defined crush strength are formed without the use of an external binder or lubricant.
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