公开(公告)号：US20150141574A1

公开(公告)日：2015-05-21

申请号：US14396951

申请日：2013-04-24

Applicant: Li JIA ,  Joseph SCAVUZZO ,  Joseph KENNEDY

Inventor： Li Jia ,  Joseph Kennedy ,  Joseph Scavuzzo

IPC: C08G77/42 ,  C08F36/08 ,  C08F22/10 ,  C08G77/388 ,  C08F10/06 ,  C08F12/08 ,  C08F10/10 ,  C08F36/06

CPC classification number: C08G77/42 ,  C08F10/06 ,  C08F10/10 ,  C08F12/08 ,  C08F22/10 ,  C08F36/06 ,  C08F36/08 ,  C08G69/08 ,  C08G69/10 ,  C08G77/388 ,  C08G81/024

Abstract: The present invention is generally directed to a new class of TPEs made from peptide terminated low Tg polymers and methods for making them. The middle block of these TPE is a telechelic polymer with a Tg that is below the intended service temperature of the TPE. The terminal peptide segments of these TPEs are short (from about 1 to about 10 amino acids long) and tend to from sheet type secondary structures through intermolecular hydrogen bonds, creating physical crosslinks between polymer chains. The dissimilarity of the peptide hard component and the elastomeric soft component results in very strong segregation between the microphase domains and a low plastic deformation for the resulting TPE. And since the Tm of the crystalline peptide phase can be adjusted, these new TPEs may be tailored to fit the intended service temperature and are melt-processable.

Abstract translation: 本发明一般涉及由肽封端的低Tg聚合物制成的新一类TPE及其制备方法。 这些TPE的中间嵌段是Tg值低于TPE预期使用温度的遥爪聚合物。 这些TPE的末端肽段是短的（约1至约10个氨基酸长），并且倾向于通过分子间氢键从片状二级结构产生，从而在聚合物链之间产生物理交联。 肽硬组分和弹性体软组分的不相似性导致微相区域之间非常强的偏析和所得TPE的低塑性变形。 并且由于可以调节结晶肽相的Tm，所以这些新的TPE可以被调整以适应预期的使用温度并且是可熔融加工的。

公开(公告)号：US09527964B2

公开(公告)日：2016-12-27

申请号：US14396951

申请日：2013-04-24

Applicant: Li Jia ,  Joseph P. Kennedy ,  Joseph Scavuzzo

Inventor： Li Jia ,  Joseph P. Kennedy ,  Joseph Scavuzzo

IPC: C08G77/42 ,  C08F10/06 ,  C08F10/10 ,  C08F12/08 ,  C08F22/10 ,  C08F36/06 ,  C08F36/08 ,  C08G77/388 ,  C08G81/02 ,  C08G69/08 ,  C08G69/10

CPC classification number: C08G77/42 ,  C08F10/06 ,  C08F10/10 ,  C08F12/08 ,  C08F22/10 ,  C08F36/06 ,  C08F36/08 ,  C08G69/08 ,  C08G69/10 ,  C08G77/388 ,  C08G81/024

Abstract: The present invention is generally directed to a new class of TPEs made from peptide terminated low Tg polymers and methods for making them. The middle block of these TPE is a telechelic polymer with a Tg that is below the intended service temperature of the TPE. The terminal peptide segments of these TPEs are short (from about 1 to about 10 amino acids long) and tend to from sheet type secondary structures through intermolecular hydrogen bonds, creating physical crosslinks between polymer chains. The dissimilarity of the peptide hard component and the elastomeric soft component results in very strong segregation between the microphase domains and a low plastic deformation for the resulting TPE. And since the Tm of the crystalline peptide phase can be adjusted, these new TPEs may be tailored to fit the intended service temperature and are melt-processable.

Abstract translation: 本发明一般涉及由肽封端的低Tg聚合物制成的新一类TPE及其制备方法。 这些TPE的中间嵌段是Tg值低于TPE预期使用温度的遥爪聚合物。 这些TPE的末端肽段是短的（约1至约10个氨基酸长），并且倾向于通过分子间氢键从片状二级结构产生，从而在聚合物链之间产生物理交联。 肽硬组分和弹性体软组分的不相似性导致微相区域之间非常强的偏析和所得TPE的低塑性变形。 并且由于可以调节结晶肽相的Tm，所以这些新的TPE可以被调整以适应预期的使用温度并且是可熔融加工的。