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公开(公告)号：US09486763B2
公开(公告)日：2016-11-08
申请号：US13880586
申请日：2011-10-20
CPC分类号： B01J7/00 , F24D2220/10 , F24H1/185 , F25B17/08 , F25B35/04 , F25D5/00 , F28D20/003 , Y02A30/277 , Y02B30/62 , Y02E60/142
摘要： The present invention relates to a thermochemical system comprising a reactor, or an enclosure for storing a solid reactive material capable of absorbing a gas, the reactive material and the gas being such that, when placed together, a chemical reaction occurs which results in the gas being absorbed by the reactive material, and a reverse chemical reaction occurs, wherein the gas absorbed by the reactive material is desorbed when heating means are applied to said reactive material when the latter has absorbed the gas. Said thermochemical system is characterized in that the reactor consists of an outer housing which is made of a composite material and which contains a sealed inner housing containing the reactive material, the heating means being arranged between the two enclosures.
摘要翻译： 本发明涉及一种热化学系统，其包括反应器或用于储存能够吸收气体的固体反应性材料的外壳，反应性材料和气体使得当放置在一起时，发生化学反应，导致气体 被反应性材料吸收，并发生反向化学反应，其中当反应性材料吸收气体时，当反应性材料被加热时，由反应性材料吸收的气体被解吸。 所述热化学系统的特征在于，所述反应器由外壳构成，所述外壳由复合材料制成并且包含容纳所述反应性材料的密封内壳，所述加热装置设置在所述两个外壳之间。
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公开(公告)号：US20130269369A1
公开(公告)日：2013-10-17
申请号：US13880586
申请日：2011-10-20
IPC分类号： F25D5/00
CPC分类号： B01J7/00 , F24D2220/10 , F24H1/185 , F25B17/08 , F25B35/04 , F25D5/00 , F28D20/003 , Y02A30/277 , Y02B30/62 , Y02E60/142
摘要： The present invention relates to a thermochemical system comprising a reactor, or an enclosure for storing a solid reactive material capable of absorbing a gas, the reactive material and the gas being such that, when placed together, a chemical reaction occurs which results in the gas being absorbed by the reactive material, and a reverse chemical reaction occurs, wherein the gas absorbed by the reactive material is desorbed when heating means are applied to said reactive material when the latter has absorbed the gas. Said thermochemical system is characterized in that the reactor consists of an outer housing which is made of a composite material and which contains a sealed inner housing containing the reactive material, the heating means being arranged between the two enclosures.
摘要翻译： 本发明涉及一种热化学系统，其包括反应器或用于储存能够吸收气体的固体反应性材料的外壳，反应性材料和气体使得当放置在一起时，发生化学反应，导致气体 被反应性材料吸收，并发生反向化学反应，其中当反应性材料吸收气体时，当反应性材料被加热时，由反应性材料吸收的气体被解吸。 所述热化学系统的特征在于，所述反应器由外壳构成，所述外壳由复合材料制成并且包含容纳所述反应性材料的密封内壳，所述加热装置设置在所述两个外壳之间。
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公开(公告)号：US09050575B2
公开(公告)日：2015-06-09
申请号：US13880560
申请日：2011-10-20
CPC分类号： B01J10/00 , B01D2259/40096 , F25B17/08 , F25B35/04 , F25B2333/002 , Y02A30/277 , Y02B30/62
摘要： A thermochemical system having a reactor or a chamber for storing a reactive material capable of absorbing a gas that is taken into the reactor by a diffuser placed along the longitudinal axis of the latter. The reactive material and the gas are such that, when placed in the presence of each other, same are subjected to a reaction causing the reactive material to absorb the gas, and conversely, same are subjected to a reaction for desorbing the gas, absorbed by the reactive material, by heating applied to the latter when it has absorbed gas. The diffuser includes a gas supply mechanism, a mechanism for dispensing the gas into the reactive material, a filtration mechanism, and a heating mechanism. The various mechanisms form a sub-assembly that is attached onto the housing of the reactor by a sealing element.
摘要翻译： 一种具有反应器或室的热化学系统，该反应器或室用于储存能够吸收通过沿其纵向轴线放置的扩散器而被吸入反应器的气体的反应性材料。 反应性材料和气体是这样的，当彼此相互放置时，相同的反应物进行反应，使反应性材料吸收气体，相反地，反应物经过用于解吸气体的反应，被 反应性材料通过在吸收气体时施加到后者上的加热。 扩散器包括气体供给机构，用于将气体分配到反应性材料中的机构，过滤机构和加热机构。 各种机构形成通过密封元件附接到反应器的壳体上的子组件。
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公开(公告)号：US20130280140A1
公开(公告)日：2013-10-24
申请号：US13880560
申请日：2011-10-20
IPC分类号： B01J10/00
CPC分类号： B01J10/00 , B01D2259/40096 , F25B17/08 , F25B35/04 , F25B2333/002 , Y02A30/277 , Y02B30/62
摘要： A thermochemical system having a reactor or a chamber for storing a reactive material capable of absorbing a gas that is taken into the reactor by a diffuser placed along the longitudinal axis of the latter. The reactive material and the gas are such that, when placed in the presence of each other, same are subjected to a reaction causing the reactive material to absorb the gas, and conversely, same are subjected to a reaction for desorbing the gas, absorbed by the reactive material, by heating applied to the latter when it has absorbed gas. The diffuser includes a gas supply mechanism, a mechanism for dispensing the gas into the reactive material, a filtration mechanism, and a heating mechanism. The various mechanisms form a sub-assembly that is attached onto the housing of the reactor by a sealing element.
摘要翻译： 一种具有反应器或室的热化学系统，该反应器或室用于储存能够吸收通过沿其纵向轴线放置的扩散器而被吸入反应器的气体的反应性材料。 反应性材料和气体是这样的，当彼此相互放置时，相同的反应物进行反应，使反应性材料吸收气体，相反地，反应物经过用于解吸气体的反应，被 反应性材料通过在吸收气体时施加到后者上的加热。 扩散器包括气体供给机构，用于将气体分配到反应性材料中的机构，过滤机构和加热机构。 各种机构形成通过密封元件附接到反应器的壳体上的子组件。
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公开(公告)号：US20080199372A1
公开(公告)日：2008-08-21
申请号：US12065139
申请日：2005-08-31
申请人： Laurent Rigaud , Francis Kindbeiter
发明人： Laurent Rigaud , Francis Kindbeiter
IPC分类号： B01J19/00
CPC分类号： F28D20/003 , F25B17/08 , F25B35/04 , F25D2331/804 , Y02A30/277 , Y02A30/278 , Y02B30/62 , Y02B30/64 , Y02E60/142
摘要： The invention relates to a thermochemical reactor (1) for a cooling and/or heating apparatus, comprising at least one reagent unit (2) which, by means of chemical combination, can absorb, a gas stream originating from a tank and which, by means of the reverse chemical reaction, cab desorb said gas stream due to a rise in temperature. The reagent unit (2) is disposed in a container (3) comprising walls, of which at least some are equipped with diffuser means (7) for distributing the gas stream. In addition, the reagent unit (2) is of the type that can expand during absorption of the gas stream and retract during desorption of the gas stream, said unit being connected to heating means. Moreover, at least some of the above-mentioned walls consist of mobile walls, which can accompany the longitudinal movement performed by the reagent unit (2), such as to enable successive deformation phenomena.
摘要翻译： 本发明涉及一种用于冷却和/或加热装置的热化学反应器（1），包括至少一个试剂单元（2），其通过化学组合可吸收来自罐的气流，并通过 反向化学反应的手段，由于温度升高，驾驶室解吸所述气流。 试剂单元（2）设置在包括壁的容器（3）中，其中至少一些装备有用于分配气流的扩散器装置（7）。 此外，试剂单元（2）是在气流的吸收期间可以膨胀的类型，并且在气流解吸期间缩回，所述单元连接到加热装置。 此外，上述壁中的至少一些由移动壁组成，其可以伴随由试剂单元（2）执行的纵向移动，从而能够实现连续的变形现象。
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公开(公告)号：US08459044B2
公开(公告)日：2013-06-11
申请号：US12065139
申请日：2005-08-31
申请人： Laurent Rigaud , Francis Kindbeiter
发明人： Laurent Rigaud , Francis Kindbeiter
CPC分类号： F28D20/003 , F25B17/08 , F25B35/04 , F25D2331/804 , Y02A30/277 , Y02A30/278 , Y02B30/62 , Y02B30/64 , Y02E60/142
摘要： A thermochemical reactor (1) for a cooling and/or heating includes at least one reagent unit (2) which, using chemical combination, can absorb a gas stream originating from a tank and which, using the reverse chemical reaction, can desorb the gas stream due to a rise in temperature. The reagent unit (2) is disposed in a container (3) that has walls, at least some of which are equipped with diffusers (7) for distributing the gas stream. In addition, the reagent unit (2), which can be heated, is of the type that can expand during absorption of the gas stream and retract during desorption of the gas stream. Moreover, at least some of the walls are mobile walls, which can accompany the longitudinal movement of the reagent unit (2), to enable successive deformation phenomena.
摘要翻译： 用于冷却和/或加热的热化学反应器（1）包括至少一个试剂单元（2），其使用化学组合可以吸收源自罐的气流，并且其使用反向化学反应可以解吸气体 由于温度上升导致的流量。 试剂单元（2）设置在具有墙壁的容器（3）中，其中至少一些装有用于分配气流的扩散器（7）。 此外，可以加热的试剂单元（2）是在气流的吸收期间可以膨胀的类型，并且在气流的解吸期间缩回。 此外，至少一些壁是可伴随试剂单元（2）的纵向移动的移动壁，以使得能够连续变形现象。
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公开(公告)号：US09625096B2
公开(公告)日：2017-04-18
申请号：US14233428
申请日：2012-08-02
申请人： Francis Kindbeiter , Laurent Rigaud
发明人： Francis Kindbeiter , Laurent Rigaud
CPC分类号： F17C5/06 , C01B3/001 , C01C1/006 , F17C11/00 , F17C11/005 , Y02E60/324
摘要： The invention relates to a method for filling a tank (1) with a gas in gaseous phase in order to store said gas in solid phase, in which the gas is introduced into the tank (1) at either: a filling pressure (Pr) equal to the equilibrium pressure of a reactant product at a filling temperature plus α times the difference between the saturation vapor pressure (PS) of the gas at the filling temperature (Tr) and the equilibrium pressure of the reactant product, α being between 0.1 and 0.9; or a filling temperature (Tr) equal to the vaporization temperature of the gas at the filling pressure (Pr) plus β times the difference between the equilibrium temperature (Te) of the reactant product at the filling pressure (Pr) and the vaporization temperature of the gas, β being between 0.1 and 0.9.
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8.发明申请METHOD FOR STORING A GAS BY CHEMISORPTION ON A POROUS MATERIAL COMPRISING EXPANDED GRAPHITE 审中-公开通过在含有膨胀石墨的多孔材料上进行化学存储气体的方法公开(公告)号：US20140205529A1
公开(公告)日：2014-07-24
申请号：US14232809
申请日：2012-08-02
申请人： Francis Kindbeiter , Laurent Rigaud
发明人： Francis Kindbeiter , Laurent Rigaud
CPC分类号： C01C1/006 , C01B3/001 , F17C11/00 , F17C11/005 , Y02E60/321 , Y02E60/324
摘要： Method for storing a gas in solid phase so that it can be distributed in gaseous phase, that consists in introducing the gas in gaseous phase into a storage tank (1) containing a reactive mixture the apparent density of which is between 40 kg/m3 and 60 kg/m3 and preferably of the order of 50 kg/m3, and which is made up of a reactive product and of expanded natural graphite, this reactive mixture and the gas being such that, when brought into the presence of one another, the reactive product and the gas undergo a thermochemical reaction the effect of which is that the gas is absorbed by the reactive product and a solid product of reaction is produced and, conversely, undergo a reverse thermochemical reaction in which the gas absorbed by the reactive product is desorbed when this product is heated after it has absorbed the gas.
摘要翻译： 用于将气体储存在固相中以使其可以分布在气相中的方法，其包括将气相中的气体引入到储存罐（1）中，所述储罐（1）含有表观密度为40kg / m 3和 60kg / m 3，优选约50kg / m 3，由反应产物和膨胀天然石墨组成，该反应性混合物和气体使得当彼此存在时， 反应产物和气体经受热化学反应，其作用是气体被反应产物吸收并产生固体反应产物，相反地，经历反应热化学反应，其中反应产物吸收的气体为 当该产品在吸收气体后被加热时解吸。
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公开(公告)号：US20140202587A1
公开(公告)日：2014-07-24
申请号：US14233428
申请日：2012-08-02
申请人： Francis Kindbeiter , Laurent Rigaud
发明人： Francis Kindbeiter , Laurent Rigaud
CPC分类号： F17C5/06 , C01B3/001 , C01C1/006 , F17C11/00 , F17C11/005 , Y02E60/324
摘要： The invention relates to a method for filling a tank (1) with a gas in gaseous phase in order to store said gas in solid phase, in which the gas is introduced into the tank (1) at either: a filling pressure (Pr) equal to the equilibrium pressure of a reactant product at a filling temperature plus a times the difference between the saturation vapour pressure (PS) of the gas at the filling temperature (Tr) and the equilibrium pressure of the reactant product, a being between 0.1 and 0.9; or a filling temperature (Tr) equal to the vaporisation temperature of the gas at the filling pressure (Pr) plus β times the difference between the equilibrium temperature (Te) of the reactant product at the filling pressure (Pr) and the vaporisation temperature of the gas, β being between 0.1 and 0.9.
摘要翻译： 本发明涉及一种用气体填充罐（1）以便将气体储存在固相中的方法，其中气体在以下两者中被引入到罐（1）中：填充压力（Pr） 等于反应物产物在填充温度下的平衡压力加上填充温度（Tr）下气体的饱和蒸气压（PS）与反应物产物的平衡压力之间的差异之间的差值，其中介于0.1和 0.9; 或填充温度（Tr）等于填充压力（Pr）+ bgr处气体的蒸发温度; 乘以在填充压力（Pr）下的反应物产物的平衡温度（Te）与气体的蒸发温度之差， 在0.1和0.9之间。
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10.发明授权Process of management of a thermochemical reaction or of a solid-gas adsorption 有权热化学反应或固体气体吸附的管理过程公开(公告)号：US06305186B1
公开(公告)日：2001-10-23
申请号：US09601410
申请日：2000-08-29
申请人： Xavier Py , Francis Kindbeiter
发明人： Xavier Py , Francis Kindbeiter
IPC分类号： F25B1708
CPC分类号： F25B17/08 , F25B49/046 , Y02A30/277 , Y02A30/278 , Y02B30/62 , Y02B30/64
摘要： The invention concerns a method for controlling a thermochemical reaction or a solid-gas adsorption being carried out in a reactor (10) containing an active agent capable of reversibly reacting with a gas, the reactor (10) being connected to an evaporator/condenser assembly (14) for the gas by a connection (12) without control valve, the reactor (10) and the evaporator/condenser assembly (14) each provided with means for selectively exchanging calories with their surroundings. The control method consists in: thermally insulating the reactor (10) and the evaporator/condenser assembly (14) from the surroundings; thermally communicating the reactor (10) with its surroundings so that the active agent reacts with the gas, thereby providing cold to the evaporator (14); thermally communicating the evaporator (14) with its surroundings so as to cool it selectively; and selectively insulating the reactor (10) or the evaporator/condenser assembly (14) from their surroundings so as to stop the reaction at one point of the reversible cycle.
摘要翻译： 本发明涉及一种控制热化学反应或固体气体吸附的方法，该反应器在包含能够与气体可逆地反应的活性剂的反应器（10）中进行，反应器（10）连接到蒸发器/冷凝器组件 （14），通过没有控制阀的连接（12），反应器（10）和蒸发器/冷凝器组件（14）各自设置有用于与其周围环境选择性地交换热量的装置。 控制方法包括：将反应器（10）和蒸发器/冷凝器组件（14）与周围环境隔热; 使反应器（10）与其周围环境热连通，使得活性剂与气体反应，从而向蒸发器（14）提供冷气。 使蒸发器（14）与其周围环境热连通，以便选择性地冷却它; 并且将反应器（10）或蒸发器/冷凝器组件（14）从其周围选择性地绝缘，以便在可逆循环的一个点处停止反应。
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