AMINE-BASED CARBON DIOXIDE ADSORBENT RESISTANT TO OXYGEN AND SULFUR DIOXIDE AND METHOD OF PREPARING THE SAME

    公开(公告)号:US20200206719A1

    公开(公告)日:2020-07-02

    申请号:US16811155

    申请日:2020-03-06

    Abstract: A core-shell type amine-based carbon dioxide adsorbent is described, including a chelating agent resistant to oxygen and sulfur dioxide, to inhibit oxidative decomposition of amine. As a core, a porous support is employed on which an amine compound is immobilized, and, as a shell, an amine layer resistant to inactivity by sulfur dioxide is utilized. Such adsorbent exhibits high oxidation resistance because the chelating agent functions to remove a variety of transition metal impurities catalytically acting on amine oxidation. In addition, the sulfur dioxide-resistant amine layer of the shell selectively adsorbs sulfur dioxide to protect the amine compound of the core and, at the same time, the amine compound of the core selectively adsorbs only carbon dioxide. Sulfur dioxide adsorbed on the shell is readily desorbable therefrom at about 110° C. and thus remarkably improved regeneration stability is obtained during temperature-swing adsorption (TSA) processes in which sulfur dioxide is present.

    SYNTHESIS OF ORDERED MICROPOROUS ACTIVATED CARBONS BY CHEMICAL VAPOR DEPOSITION

    公开(公告)号:US20170225147A1

    公开(公告)日:2017-08-10

    申请号:US15433477

    申请日:2017-02-15

    Abstract: Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 μm to 20 μm.

    SYNTHESIS OF ORDERED MICROPOROUS ACTIVATED CARBONS BY CHEMICAL VAPOR DEPOSITION

    公开(公告)号:US20170225146A1

    公开(公告)日:2017-08-10

    申请号:US15433409

    申请日:2017-02-15

    Abstract: Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent.

    METAL-SUPPORTED ANION EXCHANGE RESINS AND METHOD OF REMEDIATING TOXIC ANIONS USING THE SAME
    8.
    发明申请
    METAL-SUPPORTED ANION EXCHANGE RESINS AND METHOD OF REMEDIATING TOXIC ANIONS USING THE SAME 有权
    金属支持的阴离子交换树脂和使用该金属负载的阴离子交换树脂的方法

    公开(公告)号:US20150266015A1

    公开(公告)日:2015-09-24

    申请号:US14664640

    申请日:2015-03-20

    Abstract: Provided are a method of removing a perchlorate ion (ClO4−) and a nitrate ion (NO3−) which are toxic anions in wastewater using an anion-exchange resin on which a metal is supported, and more particularly an anion-exchange resin on which a hydrogen activating metal is supported or a hydrogen activating metal and a secondary metal are supported together and a method of removing toxic anions using the same. The toxic anions may be efficiently ion-exchanged and removed using an anion-exchange resin supporting a reduction catalyst, the regeneration of the anion-exchange resin may be facilitated, and the consumption of energy and the reducing agent may be reduced, thereby being usable in removal of toxic anions from an actual water purification system.

    Abstract translation: 提供了使用负载有金属的阴离子交换树脂除去作为废水中的有毒阴离子的高氯酸根离子(ClO4-)和硝酸根离子(NO3-)的方法,更具体地说,其中阴离子交换树脂 负载氢活化金属或氢活化金属和二次金属一起被支撑,以及使用其除去有毒阴离子的方法。 有毒阴离子可以使用负载还原催化剂的阴离子交换树脂进行有效的离子交换和除去,可以促进阴离子交换树脂的再生,并且可以减少能量和还原剂的消耗,从而可以使用 从实际的水净化系统中去除有毒阴离子。

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